ChemicalBook >> CAS DataBase List >>Trifluoromethanesulfonyl chloride
Trifluoromethanesulfonyl chloride
- CAS No.
- 421-83-0
- Chemical Name:
- Trifluoromethanesulfonyl chloride
- Synonyms
- TRIFLYL CHLORIDE;PFC-MSC;Trifluoromethane chloride;TRIFLUOROMETHANESULFONYLCLORIDE;trifluoromethylsulfonyl chloride;Trifluoromethanesufonyl chloride;RIFLUOROMETHANESULFONYL CHLORIDE;Trifluoromathanesulfonyl chloride;TRIFLUOROMETHANESULFONYL CHLORIDE;Trifluoromethylsulphonyl chloride
- CBNumber:
- CB4253800
- Molecular Formula:
- CClF3O2S
- Molecular Weight:
- 168.52
- MDL Number:
- MFCD00007451
- MOL File:
- 421-83-0.mol
- MSDS File:
- SDS
Last updated:2024-04-23 16:18:34
| Melting point | -26 °C |
|---|---|
| Boiling point | 29-32 °C (lit.) |
| Density | 1.583 g/mL at 25 °C (lit.) |
| vapor pressure | 10.36 psi ( 20 °C) |
| refractive index |
n |
| Flash point | 32°C |
| storage temp. | 2-8°C |
| solubility | Chloroform |
| form | Liquid |
| color | Clear colorless to faintly colored |
| Specific Gravity | 1.583 |
| Water Solubility | Hydrolyzes with water. |
| Sensitive | Lachrymatory |
| BRN | 1812016 |
| InChIKey | GRGCWBWNLSTIEN-UHFFFAOYSA-N |
| CAS DataBase Reference | 421-83-0(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 14-34 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3265 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| Hazard Note | Corrosive/Lachrymatory | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29049090 | |||||||||
| NFPA 704 |
|
Trifluoromethanesulfonyl chloride price More Price(22)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 164798 | Trifluoromethanesulfonyl chloride ≥99% | 421-83-0 | 5g | $79.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | 164798 | Trifluoromethanesulfonyl chloride ≥99% | 421-83-0 | 25g | $263 | 2024-03-01 | Buy |
| TCI Chemical | T1027 | Trifluoromethanesulfonyl Chloride >98.0%(GC) | 421-83-0 | 5g | $65 | 2024-03-01 | Buy |
| TCI Chemical | T1027 | Trifluoromethanesulfonyl Chloride >98.0%(GC) | 421-83-0 | 25g | $204 | 2024-03-01 | Buy |
| Alfa Aesar | B21774 | Trifluoromethanesulfonyl chloride 98% | 421-83-0 | 5g | $72.9 | 2024-03-01 | Buy |
Trifluoromethanesulfonyl chloride Chemical Properties,Uses,Production
Chemical Properties
Clear colorless to faintly colored liquid
Uses
Ru(II) complex-catalyzed trifluoromethylating agent for aromatics and alkenes.
Application
Trifluoromethanesulfonyl chloride can be used as:
A trifluoromethylating agent for the fluoroalkylation of heterocycles, arenes, and heteroarenes.
A sulfonating agent for alcohols.
A chlorinating agent for carbanions.
Synthesis
Add 150g (1mol) of trifluoromethanesulfonic acid to the reactor equipped with thermometer, distillation device and mechanical stirrer, slowly add 435mL (6mol) of thionyl chloride under ice bath, and then add the catalyst N,N-dimethyl Formamide 7.36 (0.1 mol), slowly raise the temperature to room temperature, stir for half an hour, continue to heat up to 40°C, continue to stir, react for 12 hours, and then drop to room temperature after the reaction is complete.Subsequently, vacuum distillation was carried out at 110° C. and -0.1 to -0.08 MPa, and at the same time, the temperature was slowly raised to 50° C. to obtain 147 g of trifluoromethanesulfonyl chloride, with a yield of 87.5%.
Trifluoromethanesulfonyl chloride Preparation Products And Raw materials
Global( 271)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 | sales@fluoropharm.com | China | 1290 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| LEAPCHEM CO., LTD. | +86-852-30606658 | market18@leapchem.com | China | 43348 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12457 | 58 |
| Henan Bao Enluo International TradeCo.，LTD | +86-17331933971 +86-17331933971 | deasea125996@gmail.com | China | 2503 | 58 |
| airuikechemical co., ltd. | +undefined86-15315557071 | sales02@airuikechemical.com | China | 994 | 58 |
| Ouhuang Engineering Materials (Hubei) Co., Ltd | +8617702722807 | admin@hbouhuang.com | China | 1175 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
View Lastest Price from Trifluoromethanesulfonyl chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-23 | trifluoromethanesulfonyl chloride
421-83-0
|
US $100.00-30.00 / kg | 1kg | 99.93% | 1000kg per week | Ouhuang Engineering Materials (Hubei) Co., Ltd | |
 |
2024-04-09 | trifluoromethanesulfonyl chloride
421-83-0
|
US $0.00-0.00 / Kg | 1Kg | 99.9% | 200tons | airuikechemical co., ltd. | |
 |
2023-08-08 | TRIFLUOROMETHANESULFONYL CHLORIDE
421-83-0
|
US $50.00 / kg | 1kg | 99.9% | 10000MT | Henan Bao Enluo International TradeCo.，LTD |
-
- trifluoromethanesulfonyl chloride
421-83-0
- US $100.00-30.00 / kg
- 99.93%
- Ouhuang Engineering Materials (Hubei) Co., Ltd
-
- trifluoromethanesulfonyl chloride
421-83-0
- US $0.00-0.00 / Kg
- 99.9%
- airuikechemical co., ltd.
-
- TRIFLUOROMETHANESULFONYL CHLORIDE
421-83-0
- US $50.00 / kg
- 99.9%
- Henan Bao Enluo International TradeCo.，LTD
421-83-0(Trifluoromethanesulfonyl chloride )Related Search:
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1of4
TRIFLUOROMETHANESULFONYL CHLORIDE
TRIFLUOROMETHANESULPHONYL CHLORIDE
Methanesulfonyl chloride, trifluoro-
PFC-MSC
Trifluoromathanesulfonyl chloride
Trifluoromethanesulphonylchloride,99%
trifluoromethylsulfonyl chloride
Trifluoromethanesulphonyl chloride 99%
TRIFLUOROMETHANESULFONYLCLORIDE
TRIFLUOROMETHANESULFONYL CHLORIDE, 99+%
Trifluoromethanesulfonylchloride,98%
Trifluoromethylsulphonyl chloride
Trifluoromethanesulfonic acid chloride
Trifluoromethanesufonyl chloride
Trifluoromethylsulphonyl chloride 99%
TriMethylsilyltrilfluoroMethanesulfonate
TrifluoroMethanesulfonyl chloride, 99% 25GR
TRIFLUOROMETHANESULFONYL CHLORIDE FOR SY
Three fluorineMethane sulfonyl chloride
Trifluoromethanesulfonyl chloride, 99.5%
trifluoromethanesulfonyl chloride CClF3O2S
Trifluoromethane chloride
Trifluoromethanesulfonyl chloride, 98%, for synthesis
TRIFLYL CHLORIDE
RIFLUOROMETHANESULFONYL CHLORIDE
Trifluoromethanesulfonyl Chloride, ≥ 98.0%
421-83-0
421-86-0
CClF3O2S
CF3SO2Cl
C3F4l2
CF3ClO2S
CClF3SO2
Protection and Derivatization
Protecting and Derivatizing Reagents
Others
Synthetic Reagents
Piperazine derivates
organofluorine compounds
Others
Protecting and Derivatizing Reagents
Protection and Derivatization