ChemicalBook >> CAS DataBase List >>Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate

CAS No.
57834-33-0
Chemical Name:
Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate
Synonyms
UV Absorbers;UV Stabilizer UV-1;milestab 1;YISTAB UV-1;Runsorb UV-1;LOTSORB UV 1;Sinosorb? UV-1;Absorbent UV-1;UV absorber UV-1;UvAbsorberUv-1>98.5%
CBNumber:
CB4295255
Molecular Formula:
C17H18N2O2
Molecular Weight:
282.34
MDL Number:
MFCD04972556
MOL File:
57834-33-0.mol
Last updated:2024-04-25 17:59:01

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Properties

Boiling point 188 °C(Press: 0.1 Torr)
Density 1.05±0.1 g/cm3(Predicted)
vapor pressure 78Pa at 25℃
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Light Yellow to Yellow Semi-Solid
pka 6.94±0.50(Predicted)
Water Solubility 34.7mg/L at 20℃
LogP 4.46 at 25℃
CAS DataBase Reference 57834-33-0(CAS DataBase Reference)
EPA Substance Registry System Benzoic acid, 4-[[(methylphenylamino)methylene]amino]-, ethyl ester (57834-33-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS09
Signal word  Warning
Hazard statements  H373-H411
Precautionary statements  P260-P314-P501

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC E925558 Ethyl4-[[(methylphenylamino)methylene]amino]benzoate 57834-33-0 250mg $155 2021-12-16 Buy
AK Scientific P954 N-(Ethoxycarbonylphenyl)-N'-methyl-N'-phenylformamidine 57834-33-0 500g $150 2021-12-16 Buy
American Custom Chemicals Corporation CHM0079109 ETHYL 4-[[(METHYLPHENYLAMINO)METHYLENE]AMINO]BENZOATE 95.00% 57834-33-0 1G $903.5 2021-12-16 Buy
Ambeed A344403 Ethyl4-(((methyl(phenyl)amino)methylene)amino)benzoate 97% 57834-33-0 500g $150 2021-12-16 Buy
Ambeed A344403 Ethyl4-(((methyl(phenyl)amino)methylene)amino)benzoate 97% 57834-33-0 10g $9 2021-12-16 Buy
Product number Packaging Price Buy
E925558 250mg $155 Buy
P954 500g $150 Buy
CHM0079109 1G $903.5 Buy
A344403 500g $150 Buy
A344403 10g $9 Buy

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Chemical Properties,Uses,Production

Description

UV-1 is highly effective for the light stabilization of PUR in a wide range of applications, including microellular foams and integral skin foams for footwear, conventional rigid and flexible foams, fabric coatings for artificial leather, adhesives, sealants, and elastomers (spray, RIM, etc.). lItis conveniently added to PUR systems as a solution in the polyol component (polyether- or polyester-based).

Physical properties

UV-1(Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate) is a high efficient anti-ultraviolet additive. It is widely used in adhesives, polyurethane, foam and other materials. Because of its excellent absorption property, the ultraviolet radiation in 240-340nm is effectively absorbed and the ultraviolet radiation in the 300-330nm is nearly absorbed completely. Its anti-ultraviolet effect is 1.1-1.4 times as efficient as the UV absorbers of benzophenone or benzotriazole types.

Uses

UV-1(Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate) has good effect on the polymer system and it has good compatibility with the resin. The anti-yellowing effect is excellent. Its effect is superior to the other UV agent for PU. It is widely used in PU foaming, PU coating, PU leather, PU board and resins etc.

Industrial uses

UV absorber UV-1 is a liquid formamidine type ultraviolet absorber, it has a very strong UV absorption spectrum peak between 300-330nm, in this region polyurethane is susceptible to radiation degradation. So it has excellent light stability to microporous polyurethane products such as foam, integral skin foam, traditional foam, semi-rigid, soft foam, fabric coating, some adhesives, sealants and elastomers.It is convenient to use and miscible with polyester polyol and polyether polyols, has high solubility in many solvents, and has good compatibility with isocyanates and other polyurethane additives(such as light stabilizer 292).In polyurethane,normal usage level range is 0.2-1.0%.In adhesives and sealant,concentration level normally range is 0.5-1.0%.

Synthesis

Synthesis_57834-33-0
165 g (1 mol) of ethyl p-aminobenzoate, 117.7 g (1.1 mol) of N-methylaniline, 10 g of p-toluenesulfonic acid,200mL with toluene toluene added to the 1000mL reaction flask, stirred and warmed to 50-60 ?? C, 2h dropwise 59.53g (1.1mol) formic acid(Content of 85%),Heating to reflux reaction, continue to separate the generated water, the reaction of about 5h to stop water when there is no water. The reaction solution was distilled off with atmospheric toluene recovery agent, toluene was recovered, the remaining vacuum distillation reaction solution,A pale yellow viscous liquid N- (4-ethoxycarbonylphenyl) -N'-methyl-N'-phenyl formamidine 262g, yield 93%, purity 99.4%.

94-09-7
100-61-8
149-73-5
57834-33-0
Synthesis of Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate from Benzocaine and N-Methylaniline and Trimethoxymethane

Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Preparation Products And Raw materials

Global( 242)Suppliers
Supplier Tel Email Country ProdList Advantage
QINGDAO JADE NEW MATERIAL TECNOLOGY CO.,LTD
+86 13658692156 zandrew@jadenmtc.com China 221 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5993 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
Jiangsu Qingquan Chemical Co., Ltd.
+86-571-86589381,86589382,86589383 sales1@qqpharm.com CHINA 154 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Jinan Finer Chemical Co., Ltd
+86-531-88989536 +86-15508631887 sales@finerchem.com China 2967 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58

View Lastest Price from Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Absorbent UV-1  pictures 2024-04-25 Absorbent UV-1
57834-33-0
US $200.00-95.00 / kg 1kg 99% 20ton Hebei Zhuanglai Chemical Trading Co.,Ltd
Ultraviolet Absorbent UV-1 pictures 2024-04-25 Ultraviolet Absorbent UV-1
US $120.00 / kg 1kg 99% 20ton Hebei Zhuanglai Chemical Trading Co.,Ltd
UV Stabilizer UV-1 pictures 2024-04-25 UV Stabilizer UV-1
57834-33-0
US $2.00 / kg 1kg 99% 500mt Jinan Finer Chemical Co., Ltd
  • Absorbent UV-1  pictures
  • Absorbent UV-1
    57834-33-0
  • US $200.00-95.00 / kg
  • 99%
  • Hebei Zhuanglai Chemical Trading Co.,Ltd
N-(Ethoxycarbonylphenyl)-N'-methyl-N'-phenyl formamidine 4-[[(METHYLPHENYLAMINO)METHYLENE]AMINO]-BENZOIC ACID ethyl 4-[[(methylphenylamino)methylene]amino]benzoate 4-[[(methylphenylamino)methylene]amino]-benzoicaciethylester Benzoicacid,4-[[(methylphenylamino)methylene]amino]-,ethylester N-(Ethoxycabonylphenyl)-N'-methyl-N'-phenyl formamidine 4-[[(METHYLPHENYLAMINO)MEHTYLENE]AMINO]-BENZOIC ACID UvAbsorberUv-1>98.5% UV absorber UV-1 Ethyl-4-[[(methylphenylamino)methylen]amino]benzoat Ultraviolet absorbent UV-1 4-[[(Methylphenylamino)methylene]amino]benzoic acid ethyl ester Ethyl 4-[[(methylphe Runsorb UV-1 4-[[(MethylphenylaMino)Methylene]aMino]benzoate N-(P-Ethoxycarbonylphenyl)-N'-Methyl-N'-phenyl for N-(P-Ethoxycarbonylphenyl)-N'-methyl-N'-phenyl formamidine (E)-Ethyl 4-[[(Methylphenylamino)Methylene]Amino]Benzoate Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate(UV-1) Ethy14-[[(methylphenylamino)methylene]amino] benzoate 4-[(N-methylanilino)methylideneamino]benzoic acid milestab 1 LOTSORB UV 1 UV-1 Ethyl 4-[[(methylphenylamino)methylene]amino]benzoate Light Stablizer UV-1 Ultraviolet absorber UV-1 ETHYL 4-[[(METHYLPHENYLAMINO)METHYLENE]AMINO]BENZOATE 57834-33-0 UV ABSORBER TRUELICHT UV1 UV absorber Sunsorb 1 YISTAB UV-1 UV Absorbers UV Stabilizer UV-1 Sinosorb? UV-1 Absorbent UV-1 57834-33-0 57843-33-0 1104810-48-2 C17H18N2O2 C15H14N2O2 57834-33-0