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METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE

CAS No.
70264-94-7
Chemical Name:
METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE
Synonyms
METHYL 3-METHOXY-4-BROMOMETHYLBENZOATE;)-3-methoxybenzoate;Methyl 4-(Bromomethyl)-m-anisate;4-(bromomethyl)-3-methoxybenzoate;METHYL4-BROMOETHYL-3-METHOXYBENZOATE;METHYL3-METHOXY-4-(BROMOMETHYL)BENZONATE;METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE;Methyl 4-(bromomethyl)-3-methoxybenzonate;Methyl4-(Bromomethyl)-3-methoxybenzoate>4-(Bromomethyl)-m-anisic Acid Methyl Ester
CBNumber:
CB4342137
Molecular Formula:
C10H11BrO3
Molecular Weight:
259.1
MDL Number:
MFCD00270115
MOL File:
70264-94-7.mol
MSDS File:
SDS
Last updated:2023-05-15 10:43:25

METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE Properties

Melting point 92-94°C
Boiling point 324.2±32.0 °C(Predicted)
Density 1.432
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
solubility Chloroform (Sparingly), Methanol (Slightly)
form powder to crystal
color White to Light yellow
CAS DataBase Reference 70264-94-7(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H315-H317-H318-H410
Precautionary statements  P261-P264-P273-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,N
Risk Statements  36/37/38-50/53-43-41-38
Safety Statements  26-36/37/39-61-60
RIDADR  UN 2811 6.1/PG 3
WGK Germany  3
HazardClass  IRRITANT
PackingGroup 
HS Code  2918999090

METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 681180 Methyl 4-(bromomethyl)-3-methoxybenzoate 97% 70264-94-7 5g $82.4 2024-03-01 Buy
Sigma-Aldrich 681180 Methyl 4-(bromomethyl)-3-methoxybenzoate 97% 70264-94-7 1g $69.8 2023-06-20 Buy
TCI Chemical M2356 Methyl 4-(Bromomethyl)-3-methoxybenzoate >97.0%(GC) 70264-94-7 5g $106 2024-03-01 Buy
TCI Chemical M2356 Methyl 4-(Bromomethyl)-3-methoxybenzoate >97.0%(GC) 70264-94-7 25g $425 2024-03-01 Buy
TRC M258700 Methyl 4-(bromomethyl)-3-methoxybenzoate 70264-94-7 5g $70 2021-12-16 Buy
Product number Packaging Price Buy
681180 5g $82.4 Buy
681180 1g $69.8 Buy
M2356 5g $106 Buy
M2356 25g $425 Buy
M258700 5g $70 Buy

METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE Chemical Properties,Uses,Production

Preparation

Methyl 4-(bromomethyl)-3-methoxybenzoate is prepared by the following steps:A mixture of methyl 3-methoxy-4-methylbenzoate 37 (5 g, 27.8 mmol),  NBS (4.94 g, 27.8 mmol), and benoyl peroxide (0.0008 g, 0.003 mmol)  was refluxed in CCl4 (25 ml) for 10 hours. The reaction mixture was  allowed to cool and filtered. The residue was washed with CCl4 and the  combined filtrate concentrated in vacuo. Purification by column  chromatography over silica gel (5-10% EtOAc-pet ether) furnished a colourless solid (7.19  g).Yield : 100%

Uses

Methyl 4-(Bromomethyl)-3-methoxybenzoate is an intermediate used to prepare heteroarylphenyloxoacetyl and heteroarylphenylsulfonyl benzoylpiperazine analogs of BMS 378806 as HIV entry inhibitors. It is also used to synthesize steroid 5α-reductase inhibiting acylpiperidines.

METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE Preparation Products And Raw materials

Global( 184)Suppliers
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Shanghai Daken Advanced Materials Co.,Ltd
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ATK CHEMICAL COMPANY LIMITED
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Alchem Pharmtech,Inc.
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Wuhan Chemwish Technology Co., Ltd
027-67849912 sales@chemwish.com CHINA 10828 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58

View Lastest Price from METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE pictures 2019-07-06 METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE
70264-94-7
US $1.00 / KG 1G 98% 100KG Career Henan Chemical Co
Methyl 4-(bromomethyl)-3-methoxybenzonate 4-BROMOMETHYL-3-METHOXY-BENZOIC ACID METHYL ESTER METHYL3-METHOXY-4-(BROMOMETHYL)BENZONATE METHYL4-BROMOETHYL-3-METHOXYBENZOATE 4-Brommethyl-3-methoxybenzoesuremethylester Methyl 4-brome methyl-3-methoxy benzoate Methyl 4-(bromomethyl)-3-(methyloxy)benzoate Benzoic acid, 4-(bromomethyl)-3-methoxy-, methyl ester METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE 3-METHOXY-4-(BROMOMETHYL)BENZOIC ACID METHYL ESTER Methyl 4-(bromomethyl)-3-methoxybenzoate 98% Methyl4-(Bromomethyl)-3-methoxybenzoate> )-3-methoxybenzoate 4-(Bromomethyl)-m-anisic Acid Methyl Ester Methyl 4-(Bromomethyl)-m-anisate CAS No.70264-94-7 METHYL 4-(BROMOMETHYL)-3-METHOXYBENZOATE METHYL 3-METHOXY-4-BROMOMETHYLBENZOATE 4-(bromomethyl)-3-methoxybenzoate 3-Methoxy-4-bromomethylbenzoate methyl ester 70264-94-7 C10H11O3Br BENZYL HALIDE C10 to C11 Carbonyl Compounds Building Blocks Esters Organic Building Blocks Building Blocks C10 to C11 Carbonyl Compounds Chemical Synthesis Organic Building Blocks Aromatic Esters Benzoic acid C10 to C11 Carbonyl Compounds Esters