Methyl trioctyl ammonium chloride
- CAS No.
- 5137-55-3
- Chemical Name:
- Methyl trioctyl ammonium chloride
- Synonyms
- ALIQUAT 336;aliquat;ADOGEN 464;METHYLTRIOCTYLAMMONIUM CHLORIDE;TRICAPRYLYLMETHYLAMMONIUM CHLORIDE;TOMAC;TRIOCTYLMETHYLAMMONIUM CHLORIDE;TRICAPRYLMETHYLAMMONIUM CHLORIDE;METHYLTRI-N-OCTYLAMMONIUM CHLORIDE;trioctylmethylammonium
- CBNumber:
- CB4412612
- Molecular Formula:
- C25H54ClN
- Molecular Weight:
- 404.16
- MDL Number:
- MFCD00011862
- MOL File:
- 5137-55-3.mol
- MSDS File:
- SDS
| Melting point | -20°C |
|---|---|
| Boiling point | 240°C |
| Density | 0.884 g/mL at 25 °C(lit.) |
| vapor pressure | 0Pa at 25℃ |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | under inert gas (nitrogen or Argon) at 2-8°C |
| solubility | soluble in Chloroform, Hexanes |
| form | Viscous Liquid |
| color | Colourless to pale orange |
| Odor | Ammonical |
| Viscosity | 230.945mm2/s |
| Water Solubility | Partially insoluble |
| Sensitive | Hygroscopic |
| BRN | 4039255 |
| Stability | Stable. Incompatible wth strong oxidizing agents. Hygroscopic. |
| InChIKey | XKBGEWXEAPTVCK-UHFFFAOYSA-M |
| LogP | 4.5 at 25℃ |
| CAS DataBase Reference | 5137-55-3(CAS DataBase Reference) |
| FDA UNII | 07Q8S2MJ6A |
| EPA Substance Registry System | Methyltrioctylammonium chloride (5137-55-3) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS05,GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H314-H360FD-H373-H410 | |||||||||
| Precautionary statements | P202-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | Xn,N,C | |||||||||
| Risk Statements | 22-38-41-50/53-36/37/38-20/21/22-34 | |||||||||
| Safety Statements | 26-39-60-61-36-45-36/37/39 | |||||||||
| RIDADR | UN 2810 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | UZ2997500 | |||||||||
| F | 3-10 | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29239000 | |||||||||
| NFPA 704 |
|
Methyl trioctyl ammonium chloride price More Price(29)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 69485 | Methyltrioctylammonium chloride ≥97.0% (AT) | 5137-55-3 | 10g | $109 | 2024-03-01 | Buy |
| Sigma-Aldrich | 69485 | Methyltrioctylammonium chloride ≥97.0% (AT) | 5137-55-3 | 50g | $385 | 2024-03-01 | Buy |
| TCI Chemical | T1365 | Methyltri-n-octylammonium Chloride >95.0%(T) | 5137-55-3 | 25g | $106 | 2024-03-01 | Buy |
| TCI Chemical | T1365 | Methyltri-n-octylammonium Chloride >95.0%(T) | 5137-55-3 | 500g | $1189 | 2024-03-01 | Buy |
| Usbiological | 261427 | Tricaprylylmethylammonium chloride | 5137-55-3 | 100g | $333 | 2021-12-16 | Buy |
Methyl trioctyl ammonium chloride Chemical Properties,Uses,Production
Description
Methyltrioctylammonium chloride is a water insoluble quaternary ammonium salt, which is widely used as a counter ion in solvent extraction of anionic metal complexes. It is widely used as a phase transfer catalyst for the catalytic oxidation of cyclohexene to 1,6-hexanedioic acid. In comparison to traditional method of oxidizing cyclohexanol or cyclohexanone with nitric acid or potassium permanganate, the usage of methyltrioctylammonium chloride is a more environmentally friendly reaction.
Reference
N. Pourreza, H. Zavvar Mousavi, Determination of cadmium by flame atomic absorption spectrometry after preconcentration on naphthalene– methyltrioctylammonium chloride adsorbent as tetraiodocadmate (II) ions, Analytica Chimica Acta, 2004, vol. 503, pp. 279-282
Chemical Properties
viscous colourless to pale orange liquid
Uses
Mixture of C8 and C10 chains with C8 predominating. Used as a metal extraction reagent and a phase-transfer catalyst.
Uses
Methyltrioctylammonium chloride can be used:
- As a catalyst in the synthesis of acridine dione derivatives from aromatic aldehyde, dimedone and amines under ultrasonic irradiations.
- As a catalyst in the synthesis of extended π-systems using aromatic aldehydes and methyldiazines.
- As a component of a catalytic system used in the Suzuki-Miyaura cross-coupling reaction of a variety of aryl and heteroaryl chlorides in H2O.
Definition
ChEBI: An organic chloride salt having methyltrioctylammonium as the cation.
Flammability and Explosibility
Not classified
Safety Profile
Poison by ingestion and intraperitoneal routes. When heated to decomposition it emits very toxic fumes of NOx, NH3, and Cl-.
Purification Methods
A 30% (v/v) of Aliquat 336 solution in *benzene is washed twice with an equal volume of 1.5M HBr. [Petrow & Allen, Anal Chem 33 1303 1961.] It is purified by dissolving 50g in CHCl3 (100mL) and shaking with 20% NaOH solution (200mL) for 10minutes, and followed by 20% NaCl (200mL) for 10minutes. It is then washed with a small volume of H2O and filtered through a dry filter paper [Adam & Pribil Talanta 18 733 1971]. n-Alkylammonium chloride n=2,4,6. Recrystallise them from EtOH or an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985, Chu & Thomas J Am Chem Soc 108 6270 1986.] n-Alkyltrimethylammonium bromide n=10,12,16. Recrystallise them from an EtOH/Et2O mixture. [Hashimoto & Thomas J Am Chem Soc 107 4655 1985.]
Methyl trioctyl ammonium chloride Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12453 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7377 | 58 |
| Hebei Saisier Technology Co., LTD | +86-18400010335 +86-13102810335 | admin@hbsaisier.cn | China | 424 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9352 | 55 |
| JingJiang Connect Chemical manufacturing Co., Ltd. | 0523-80501690 15252623102 | andy@katchemical.com | CHINA | 59 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
View Lastest Price from Methyl trioctyl ammonium chloride manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-12 | Methyl trioctyl ammonium chloride
5137-55-3
|
US $6.00-3.00 / KG | 1KG | More than 99% | 20000kg | Hebei Saisier Technology Co., LTD | |
 |
2024-01-14 | Methyl Trioctyl Ammonium Chloride
5137-55-3
|
US $5.00-0.50 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2024-01-06 | Methyl trioctyl ammonium chloride
5137-55-3
|
US $0.00 / kg | 1kg | 99% | 1000000 | Hebei Jingbo New Material Technology Co., Ltd |
-
- Methyl trioctyl ammonium chloride
5137-55-3
- US $6.00-3.00 / KG
- More than 99%
- Hebei Saisier Technology Co., LTD
-
- Methyl Trioctyl Ammonium Chloride
5137-55-3
- US $5.00-0.50 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- Methyl trioctyl ammonium chloride
5137-55-3
- US $0.00 / kg
- 99%
- Hebei Jingbo New Material Technology Co., Ltd