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2-Hydroxyethyl methacrylate

CAS No.
868-77-9
Chemical Name:
2-Hydroxyethyl methacrylate
Synonyms
HEMA;GMA;HYDROXYETHYL METHACRYLATE;GLYCOL METHACRYLATE;ETHYLENE GLYCOL METHACRYLATE;BisoMer HEMA;N5-Methyl-L-glutamine;Hydroxyethyl Methacrylat;2-(Methacryloyloxy)ethanol;Hydroxyethyl methacrylate (HEMA)
CBNumber:
CB4690827
Molecular Formula:
C6H10O3
Molecular Weight:
130.14
MDL Number:
MFCD00002863
MOL File:
868-77-9.mol
MSDS File:
SDS
Last updated:2024-04-23 13:02:50

2-Hydroxyethyl methacrylate Properties

Melting point -12 °C
Boiling point 67 °C3.5 mm Hg(lit.)
Density 1.073 g/mL at 25 °C(lit.)
vapor density 5 (vs air)
vapor pressure 0.01 mm Hg ( 25 °C)
refractive index n20/D 1.453(lit.)
Flash point 207 °F
storage temp. 2-8°C
solubility Chloroform, Methanol (Slightly)
pka 13.83±0.10(Predicted)
form Liquid
color Clear
Odor Ester like
Viscosity 6.36mm2/s
Water Solubility soluble
Sensitive Air Sensitive
BRN 1071583
Stability Unstable - may polymerize in the absence of stabilizer. May be stabilized with, or contain small amounts of, diethylene glycol monomethacrylate, di(ethylene glycol)dimethacrylate, methacrylic acid. Incompatible with strong oxidizing agents, free radical initiators, peroxides, steel. Closed containers may explode if heated due to runaway polymer
InChIKey WOBHKFSMXKNTIM-UHFFFAOYSA-N
LogP 0.42 at 25℃
Indirect Additives used in Food Contact Substances 2-HYDROXYETHYL METHACRYLATE
FDA 21 CFR 175.105; 177.1010
CAS DataBase Reference 868-77-9(CAS DataBase Reference)
EWG's Food Scores 3-6
FDA UNII 6E1I4IV47V
NIST Chemistry Reference 2-Hydroxyethyl methacrylate(868-77-9)
EPA Substance Registry System 2-Hydroxyethyl methacrylate (868-77-9)
Cosmetics Info HEMA

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H317-H319
Precautionary statements  P261-P264-P272-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/38-43-36/37/38
Safety Statements  26-36/37-28A-28
WGK Germany  1
RTECS  OZ4725000
TSCA  Yes
HS Code  29161490
Toxicity LD50 orally in Rabbit: 5050 mg/kg LD50 dermal Rabbit > 3000 mg/kg
NFPA 704
1
2 1

2-Hydroxyethyl methacrylate price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.00588 2-Hydroxyethyl methacrylate (stabilised with hydroquinone monomethyl ether) for synthesis 868-77-9 250ML $60.3 2024-03-01 Buy
Sigma-Aldrich 8.00588 2-Hydroxyethyl methacrylate (stabilised with hydroquinone monomethyl ether) for synthesis 868-77-9 2.5L $132 2024-03-01 Buy
Sigma-Aldrich 17348 2-Hydroxyethyl methacrylate embedding medium (for microscopy) 868-77-9 250ML $115 2024-03-01 Buy
Sigma-Aldrich 128635 2-Hydroxyethyl methacrylate contains ≤250 ppm monomethyl ether hydroquinone as inhibitor, 97% 868-77-9 1kg $52 2024-03-01 Buy
Sigma-Aldrich 128635 2-Hydroxyethyl methacrylate contains ≤250 ppm monomethyl ether hydroquinone as inhibitor, 97% 868-77-9 18kg $547 2024-03-01 Buy
Product number Packaging Price Buy
8.00588 250ML $60.3 Buy
8.00588 2.5L $132 Buy
17348 250ML $115 Buy
128635 1kg $52 Buy
128635 18kg $547 Buy

2-Hydroxyethyl methacrylate Chemical Properties,Uses,Production

Chemical Properties

colourless liquid

Uses

2-Hydroxyethyl methacrylate is used for preparation of hydrophilic polymers for biomedical devices.

Uses

2-Hydroxyethyl methacrylate is used in UV-curable inks and coatings. It is also used in adhesives, artificial nails, dental materials and lacquers. In dentistry, it is one of the main volatile acrylates along with methyl methacrylate. Further, it is used as a monomer in the synthesis of polymers for dental prosthetics and for geotechnical grouting in construction work.

Uses

2-Hydroxyethyl methacrylate is the methacrylic monomer for use in UV inks, adhesives, lacquers, dental materials, artificial nails, etc.

Definition

2-Hydroxyethyl methacrylate is an enoate ester that is the monomethacryloyl derivative of ethylene glycol.

General Description

2-Hydroxyethyl methacrylate (HEMA) is biocompatible in nature. Polymeric hydrogel scaffold can be produced by polymerizing HEMA in water.

Hazard

30% grade (with xylene): Flammable, moderate fire risk.

Purification Methods

Dissolve the ester in water and extract with n-heptane to remove ethylene glycol dimethacrylate (checked by gas-liquid chromatography and by NMR) and distil it twice under reduced pressure [Strop et al. J Phys Chem 80 694 1976]. [Beilstein 2 IV 1530.]

107-21-1
80-62-6
868-77-9
97-90-5
Synthesis of 2-Hydroxyethyl methacrylate from Ethylene glycol and Methyl methacrylate
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View Lastest Price from 2-Hydroxyethyl methacrylate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Hydroxyethyl methacrylate pictures 2024-04-23 2-Hydroxyethyl methacrylate
868-77-9
US $15.00 / kg 1kg 99.912% 10ton Ouhuang Engineering Materials (Hubei) Co., Ltd
2-Hydroxyethyl methacrylate (HEMA) pictures 2024-04-23 2-Hydroxyethyl methacrylate (HEMA)
868-77-9
US $0.00 / Kg/Drum 1KG 99% 2000mt/year Jinan Finer Chemical Co., Ltd
2-Hydroxyethyl methacrylate pictures 2024-04-23 2-Hydroxyethyl methacrylate
868-77-9
US $2375.00 / Tons 1Tons 99% 100Tons Hebei Dangtong Import and export Co LTD
2-Hydroxyethyl=2-methylpropenoate 2-Propenoicacid,2-methyl-,2-hydroxyethylester 2-Hydroxyethyl methacrylate,98%,stabilized 2-Hydroxyethyl Methacrylate  2-Hydroxyethyl Methacrylate contains <=250 ppM MonoMethyl ether hydroquinone as inhibitor, 97% 2-Hydroxyethyl Methacrylate, 99%, stabilized with 100 ppM MEHQ 2-Hydroxyethyl methacrylate ,99% [stabilized with MEHQ, 200 - 300 ppm] 2-Hydroxyethyl methacrylate ,99% [stabilized with MEHQ,<100 ppm] 2-Hydroxyethyl methacrylate ,99% [stabilized with MEHQ, 180 - 220 ppm] 2-Hydroxyethyl metha HEMA, Direct Casting Grade HEMA, High Purity Grade, High Stability, Optical Hydroxyethyl Methacrylate 95% min 2-HYDROXYETHYL METHACRYLATE, FOR MIC 2-Hydroxyethyl methacrylate, stabilized with &ap:500ppm 4-methoxyphenol HEMA GLYCOL METHACRYLATE 2-hydroxyethyl methacrglate FILTER AGENT CELPURE (R) P65 USP-NF & 2-HYDROXYETHYL METHACRYLATE, 99+% 2-HYDROXYETHYL METHACRYLATE, FOR MICROSCOPY* 2-HYDROXYETHYL METHACRYLATE, STAB. 2-HydroxyethylMethacrylate(Hema) 2-Hydroxyethyl methacrylate, stabilised, 98% Acryester HISS Acryester HO BisoMer SR BleMMer E EB 109 GE 610 HEMA 90 Light Ester HO Light Ester HO 250 MhoroMer BM 903 MhoroMer BM 905 NSC 24180 Rocryl 400 Ethylene Glycol Methacrylate Methacrylic Acid 2-Hydroxyethyl Ester 2-Hydroxyethyl Methacrylate, stabilized, 97% 1KG 2-Hydroxyethyl Methacrylate, stabilized, 97% 25GR 2-Hydroxyethyl Methacrylate, stabilized, 97% 500GR 2-Hydroxyethyl methacrylate, stabilized, 96% METHANESULFOMIC ACID 2-Hydroxyethyl Methacrylate, Stabilized with 250 ppM MEHQ 2-Hydroxyethyl Methacrylate, stabilized with 200 ppM MEHQ 2-Hydroxyethyl Methacrylate, stabilized with 200 - 300 ppM MEHQ 2-Hydroxyethyl Methacrylate, stabilized with 100 ppM MEHQ HEMA HISS 2-Hydroxyethyl Methacrylate >=99%, contains <=50 ppM MonoMethyl ether hydroquinone as inhibitor beta-Hydroxyethyl methacrylate beta-hydroxyethylmethacrylate Bisomer 2HEMA Glycol monomethacrylate glycolmonomethacrylate Heme-a Mhoromer Monomer MG-1 monomermg-1 monomethacrylicetherofethyleneglycol