ChemicalBook >> CAS DataBase List >>Acryloyl chloride

Acryloyl chloride

Acryloyl chloride structure

CAS No.: 814-68-6

Chemical Name:: Acryloyl chloride

Synonyms: prop-2-enoyl chloride;oyL;2-PROPENOYL CHLORIDE;acrylyl chloride;ACRYLIC ACID CHLORIDE;Propenoyl chloride;chloridkyselinyakrylove;Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole;ACRYLOYL CHLORIDE;propenoylchloride

CBNumber:: CB4854427

Molecular Formula:: C3H3ClO

Molecular Weight:: 90.51

MDL Number:: MFCD00000731

MOL File:: 814-68-6.mol

Last updated:2023-12-26 11:30:52

Request For Quotation

Acryloyl chloride Properties

Melting point	76 °C(Solv: isopropyl ether (108-20-3))
Boiling point	72-76 °C (lit.)
Density	1.114 g/mL at 25 °C (lit.)
vapor density	>1 (vs air)
vapor pressure	1.93 psi ( 20 °C)
refractive index	n20/D 1.435(lit.)
Flash point	61 °F
storage temp.	2-8°C
solubility	Chloroform (Soluble), Methanol (Slightly)
form	Oil
color	Colourless to Pale Yellow
Water Solubility	Miscible with water.
Sensitive	Moisture & Light Sensitive
BRN	635744
Exposure limits	ACGIH: TWA 5 mg/m3 (Skin) NIOSH: TWA 5 mg/m3
Stability	Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.
InChIKey	HFBMWMNUJJDEQZ-UHFFFAOYSA-N
CAS DataBase Reference	814-68-6(CAS DataBase Reference)
EWG's Food Scores	1
FDA UNII	8K23O56TG5
NIST Chemistry Reference	2-Propenoyl chloride(814-68-6)
EPA Substance Registry System	Acrylyl chloride (814-68-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS02,GHS05,GHS06

Signal word

Danger

Hazard statements

H225-H290-H302-H314-H330

Precautionary statements

P210-P280-P301+P312-P303+P361+P353-P304+P340+P310-P305+P351+P338

Hazard Codes

F,T+

Risk Statements

11-14-26-34

Safety Statements

16-26-28-36/37/39-45-7/9

RIDADR

UN 3383 6.1/PG 1

WGK Germany

RTECS

AT7350000

8-10

TSCA

Yes

HazardClass

PackingGroup

HS Code

29161980

NFPA 704

	3
4		2
	W

Acryloyl chloride price More Price(14)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	549797	Acryloyl chloride 97.0%, contains <210ppm MEHQ as stabilizer	814-68-6	5g	$76.2	2024-03-01	Buy
Sigma-Aldrich	549797	Acryloyl chloride 97.0%, contains <210ppm MEHQ as stabilizer	814-68-6	500g	$646	2024-03-01	Buy
Alfa Aesar	L10363	Acryloyl chloride, 96%, stab. with 400ppm phenothiazine	814-68-6	10g	$40.5	2021-12-16	Buy
Alfa Aesar	L10363	Acryloyl chloride, 96%, stab. with 400ppm phenothiazine	814-68-6	50g	$60.6	2021-12-16	Buy
Sigma-Aldrich	A24109	Acryloyl chloride ≥97%, contains ~400ppm phenothiazine as stabilizer	814-68-6	5g	$66.7	2024-03-01	Buy

Product number	Packaging	Price	Buy
549797	5g	$76.2	Buy
549797	500g	$646	Buy
L10363	10g	$40.5	Buy
L10363	50g	$60.6	Buy
A24109	5g	$66.7	Buy

Acryloyl chloride Chemical Properties,Uses,Production

Chemical Properties

Acryloyl chloride is a highly flammable, polymerizable, and toxic (inhalation), light yellow liquid. A lacrimator.

Uses

Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

Synthesis Reference(s)

Journal of the American Chemical Society, 72, p. 72, 1950 DOI: 10.1021/ja01157a020

General Description

A liquid. Boiling point 75°C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture.

Air & Water Reactions

Polymerizes readily upon exposure to oxygen in the air. Reacts exothermically with water to give hydrochloric acid and acrylic acid.

Reactivity Profile

Acrylyl chloride is incompatible with strong oxidizing agents, alcohols, amines, alkali. Polymerizes readily upon exposure to oxygen. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Fire Hazard

When heated to decomposition, Acrylyl chloride emits toxic fumes of chlorides. Decomposes in water.

Potential Exposure

May be used as a monomer in preparation of specialty polymers or as a chemical intermediate

Shipping

UN3383 Poisonous Toxic by inhalation liquid, flammable, n.o.s. with an LC50 # 200 mL/m3 and saturated vapor concentration ≥500 LC50, Hazard class: 6.1; Labels: 6.1-Poisonous materials, 3-Flammable liquid, Technical Name Required, Inhalation Hazard Zone A. UN2924 Flammable liquids, corrosive, n.o.s., Hazard Class: 3; Labels: 3-Flammable liquid, 8-Corrosive material, Technical Name Required

Incompatibilities

Use MEHQ (monomethyl ether of hydroquinone) as an inhibitor. Incompatible with oxidizers, polymerizes on contact with oxygen; alcohols, amines, alkalis. Reacts violently with water, releasing hydrochloric acid and acrylic acid. Attacks some metals.

Acryloyl chloride Preparation Products And Raw materials

Raw materials

Copper(I) chloride Acrylic acid Phosphorus trichloride

Preparation Products

N-Isopropylacrylamide N-ACRYLOXYSUCCINIMIDE N-NONYL ACRYLATE 1,4-Diacryloylpiperazine 1,4-BUTANEDIOL DIACRYLATE

Atracurium besylate Dodecyl acrylate Poziotinib (HM781-36B) CO-1686 DECYL ACRYLATE

N-PROPYL ACRYLATE PROPARGYL ACRYLATE 2-Propenoic acid (3-methoxyphenyl)methyl ester 1-(2,3-dihydro-1H-indol-1-yl)-2-Propen-1-one Ibrutinib D5

6-(4-Cyano-biphenyl-4'-yloxy)hexyl acrylate 1-Adamantylacrylate Triethylene glycol diacrylate 5-METHYLINDOLE-3-CARBOXYLIC ACID METHYL ESTER

1of4

Acryloyl chloride Suppliers

Global( 431)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Henan Fengda Chemical Co., Ltd	+86-371-86557731 +86-13613820652	info@fdachem.com	China	7378	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1807	55
Zjartschem	+86-571-8723 8903 jocelynpan@zjarts.com	jocelynpan@zjarts.com	CHINA	993	58
Tianjin Zhongxin Chemtech Co., Ltd.	+86-022-66880623 +8618622897568	sales@tjzxchem.com	China	559	58
Shanxi Naipu Import and Export Co.,Ltd	+86-13734021967 +8613734021967	kaia@neputrading.com	China	1011	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	China	2931	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58

Supplier	Advantage
Henan Fengda Chemical Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
Zjartschem	58
Tianjin Zhongxin Chemtech Co., Ltd.	58
Shanxi Naipu Import and Export Co.,Ltd	58
career henan chemical co	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58
Hubei Jusheng Technology Co.,Ltd.	58

View Lastest Price from Acryloyl chloride manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-12-26	Acryloyl chloride 814-68-6	US $100.00-1.00 / KG	1KG	99%	g-kg-tons, free sample is available	Henan Fengda Chemical Co., Ltd
2023-08-04	Acryloyl chloride 814-68-6	US $0.00-0.00 / kg	1kg	0.99	500000kg	Hebei Yibangte Import and Export Co. , Ltd.
2023-08-04	Acryloyl chloride 814-68-6	US $0.00-0.00 / kg	1kg	0.99	500000kg	Hebei Yibangte Import and Export Co. , Ltd.

Acryloyl chloride
814-68-6
US $100.00-1.00 / KG
99%
Henan Fengda Chemical Co., Ltd

Acryloyl chloride
814-68-6
US $0.00-0.00 / kg
0.99
Hebei Yibangte Import and Export Co. , Ltd.

Acryloyl chloride
814-68-6
US $0.00-0.00 / kg
0.99
Hebei Yibangte Import and Export Co. , Ltd.

Acryloyl chloride Spectrum

Acryloyl chloride(814-68-6)MS Acryloyl chloride(814-68-6)¹HNMR Acryloyl chloride(814-68-6)¹³CNMR Acryloyl chloride(814-68-6)IR1 Acryloyl chloride(814-68-6)Raman

814-68-6(Acryloyl chloride)Related Search:

Choline chloride Ammonium chloride Benzyl chloride Acrylamide Calcium chloride

Mepiquat chloride Sodium chloride Polyvinyl chloride Tetramethyl Ibandronate methyl N-(3-methoxy-3-oxopropyl)-N-methyl-beta-alaninate

Ibandronate sodium monohydrate Trisodium phosphate N-Methylpentylamine b-Alanine, N-methyl-N-pentyl- Phosphonic acid, disodium salt

N-Methyl-N-pentyl-beta-alanine methyl ester Ibandronate Impurity 1(Ibandronate EP Impurity B) Pamidronic acid Acrylic Acid Chloride Propenoyl Chloride

1of4

ACRYLOYL CHLORIDE STAB. WITH 2 6-DI-TER ACRYLOYL CHLORIDE, STAB. Acryloylchloride,96% Acryloyl chloride, 96%, stab. with 400ppm phenothiazine Acryloyl Chloride (stabilized with MEHQ) Acryloyl Chloride (stabilized with Phenothiazine) Acryloyl Chloride, Stab. With 400Ppm Phenothiazine ACRYLOYL CHLORIDE, 97.0% Acryloyl chloride,2-Propenoyl chloride ACRYLOYL CHLORIDE ACRYLOYL CHLORIDE (STABILISED WITH PHENO Chlorid kyseliny akrylove propenoylchloride Acryloyl chloride, stabilized with 400 ppM phenothiazine ACRYLOYL CHLORIDE, 96%, STABILIZED Acryloyl Chloride (stabilized with Phenothiazine)> Ibandronate Sodium Impurity J Ibandronate Impurity 17 Acryloyl chloride ISO 9001：2015 REACH Acryloyl chloride, 97%, stabilized with p-Hydroxyanisole Acryloyl chloride, 97%, stabilized with 400 ppm phenothiazine Acryloyl chloride, 97%, stabilized with 400 ppm p-Hydroxyanisole Acrylyl chloride manufacturer kf-wang(at)kf-chem.com acrylyl chloride ACRYLIC ACID CHLORIDE 2-PROPENOYL CHLORIDE chloridkyselinyakrylove Propenoyl chloride Acryloyl chloride, 97%, for synthesis, stabilized with p-Hydroxyanisole prop-2-enoyl chloride oyL Acrylonyl chloride, HYPERICUM PERFORATUM OIL 68917-49-7 Acryloyl chloride (6CI, 8CI) Acryloyl chloride,99.5% Acryloyl Chloride, stabilized with Phenothiazine), ≥ 95.0% 814-68-6 CH2CHCOCl C3H3OCl Building Blocks Carbonyl Compounds Acid Halides Organic Building Blocks ACID CHLORIDES Industrial/Fine Chemicals Halogen compounds 814-68-6