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Acrylyl chloride

Acrylyl chloride
Acrylyl chloride
CAS No.
814-68-6
Chemical Name:
Acrylyl chloride
Synonyms
acrylyl chloride;propenoylchloride;ACRYLOYL CHLORIDE;Propenoyl chloride;Acryloylchloride,96%;2-PROPENOYL CHLORIDE;ACRYLIC ACID CHLORIDE;chloridkyselinyakrylove;ACRYLOYL CHLORIDE, STAB.;ACRYLOYL CHLORIDE, 97.0%
CBNumber:
CB4854427
Molecular Formula:
C3H3ClO
Formula Weight:
90.51
MOL File:
814-68-6.mol

Acrylyl chloride Properties

Boiling point:
72-76 °C(lit.)
Density 
1.119 g/mL at 20 °C
vapor density 
>1 (vs air)
vapor pressure 
1.93 psi ( 20 °C)
refractive index 
n20/D 1.435(lit.)
Flash point:
61 °F
storage temp. 
2-8°C
Water Solubility 
Miscible with water.
Sensitive 
Moisture & Light Sensitive
BRN 
635744
Stability:
Stable, but reacts violently with water. Incompatible with alcohols, oxidizing agents, strong bases. Light-sensitive. Highly flammable.
CAS DataBase Reference
814-68-6(CAS DataBase Reference)
NIST Chemistry Reference
2-Propenoyl chloride(814-68-6)
EPA Substance Registry System
2-Propenoyl chloride(814-68-6)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  F,T+
Risk Statements  11-14-26-34
Safety Statements  16-26-28-36/37/39-45-7/9
RIDADR  UN 3383 6.1/PG 1
WGK Germany  3
RTECS  AT7350000
8-10
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29161980
Hazardous Substances Data 814-68-6(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H225 Highly Flammable liquid and vapour Flammable liquids Category 2 Danger P210,P233, P240, P241, P242, P243,P280, P303+ P361+P353, P370+P378,P403+P235, P501
H290 May be corrosive to metals Corrosive to Metals Category 1 Warning P234, P390, P404
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
Precautionary statements:
P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P320 Specific treatment is urgent (see … on this label).
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P403+P235 Store in a well-ventilated place. Keep cool.

Acrylyl chloride price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 549797 Acryloyl chloride 97.0%, contains <210ppm MEHQ as stabilizer 814-68-6 5g $54.8 2017-11-08 Buy
Sigma-Aldrich 549797 Acryloyl chloride 97.0%, contains <210ppm MEHQ as stabilizer 814-68-6 500g $467 2017-11-08 Buy
Alfa Aesar L10363 Acryloyl chloride, 96%, stab. with 400ppm phenothiazine 814-68-6 50g $67.5 2017-11-08 Buy
Alfa Aesar L10363 Acryloyl chloride, 96%, stab. with 400ppm phenothiazine 814-68-6 10g $36 2017-11-08 Buy
Sigma-Aldrich A24109 Acryloyl chloride ≥97%, contains ~400ppm phenothiazine as stabilizer 814-68-6 5g $50.5 2017-11-08 Buy

Acrylyl chloride Chemical Properties,Uses,Production

Chemical Properties

Liquid

General Description

A liquid. Boiling point 75°C. Used to make plastics. Polymerization in a closed container can cause pressurization and explosive rupture.

Air & Water Reactions

Polymerizes readily upon exposure to oxygen in the air. Reacts exothermically with water to give hydrochloric acid and acrylic acid.

Reactivity Profile

Acrylyl chloride is incompatible with strong oxidizing agents, alcohols, amines, alkali. Polymerizes readily upon exposure to oxygen. May react vigorously or explosively if mixed with diisopropyl ether or other ethers in the presence of trace amounts of metal salts [J. Haz. Mat., 1981, 4, 291].

Fire Hazard

When heated to decomposition, Acrylyl chloride emits toxic fumes of chlorides. Decomposes in water.

Acrylyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products


Acrylyl chloride Suppliers

Global( 213)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555
+86-021-57951555 jack.li@time-chemicals.com CHINA 1372 55
GuangTuo Chemical (Shanghai) Co., Ltd. 021-60899189-8001 18918189673
021-60899304 gtchem@126.com China 2715 58
Chengdu Research Accelerators Technology Co., Ltd. 028-64353063
028-64353063 QQ:784253935 reacchemical@163.com China 5353 58
HENAN WANXIANG TECHNOLOGY&TRADE CO.,LTD. 0371-56669008;13526697008
0371-56669008 58chem@163.com China 290 55
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800 info@energy-chemical.com China 44192 61
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701 sale@aladdin-e.com China 25121 65
Henan Wanxiang Chemical Industry Co., Ltd. 0371-56669001、56669008
0371-56669008 Sales@wanxiangchem.com China 36 62
Tianjin Zhongxin Chemtech Co., Ltd. 86(0)22-89880739
86(0)22-89880739 ext 8030 / 86-22-66880086 sales@tjzxchem.com China 553 60
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96820 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40398 62

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