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Hydrazine hydrate

CAS No.7803-57-8
Chemical Name:Hydrazine hydrate
Synonyms:DiamineHydrate;DiamideHydrate;Diamid hydrate;idrazinaidrata;Hydrazine hydrate;hydrazinehydroxide;HYDRAZINE1-HYDRATE;Diamide monohydrate;HydrazineHydrate80%;Hydrazinehydrate,50%
CBNumber:CB5110461
Molecular Formula:H6N2O
Formula Weight:50.06
MOL File:7803-57-8.mol
Hydrazine hydrate Property
Melting point : −51.7 °C(lit.)
Boiling point : 120.1 °C(lit.)
density : 1.03 g/mL at 20 °C
vapor density : >1 (vs air)
vapor pressure : 5 mm Hg ( 25 °C)
refractive index : n20/D 1.428(lit.)
Fp : 204 °F
storage temp. : 0-6°C
Merck : 14,4771
Stability:: Stability Incompatible with a wide variety of materials, including oxidizing agents, heavy metal oxides, dehydrating agents, alkali metals, rust, silver salts. Combustible. Contact with many materials may cause fire or explosive decomposition. May react explosively with a variety of materials, including dehydrating agents, heavy metal ox
CAS DataBase Reference: 7803-57-8(CAS DataBase Reference)
EPA Substance Registry System: Hydrazine, monohydrate(7803-57-8)
Safety
Hazard Codes : T,N
Risk Statements : 45-20/21/22-34-43-51/53-50/53-23/24/25-10
Safety Statements : 53-45-60-61-36/37/39-26
RIDADR : UN 3293 6.1/PG 3
WGK Germany : 3
RTECS : MV8050000
F : 23
HazardClass : 8
PackingGroup : II
HS Code : 28251000

Hydrazine hydrate Chemical Properties,Usage,Production

Chemical Properties
colourless fuming liquid
General Description
A colorless fuming liquid with a faint ammonia-like odor. Corresponds to a 64% aqueous solution of hydrazine in water. Combustible but may require some effort to ignite. Contact with oxidizing materials may cause spontaneous ignition. Toxic by inhalation and by skin absorption. Corrosive to tissue. Produces toxics oxides of nitrogen during combustion.
Air & Water Reactions
Fumes in air. Water soluble.
Reactivity Profile
Hydrazine hydrate is a base and a very powerful reducing agent. Very corrosive. Violent reaction on contact with alkali metals (sodium, potassium), 2,4-dinitrochlorobenzene, tin dichloride, mercury oxide. Vigorous neutralization reaction with acids. Emits toxic fumes of nitrogen oxides when heated to decomposition [Lewis, 3rd ed., 1993, p. 680]. Reacts with tin(II) chloride to give tin(II) dihydrazine chloride, which decomposes explosively when heated [Mellor 7:430(1946-1947)]. Reacts exothermically and violently with 2,4-dinitrochlorobenzene [Wischmeyer (1967)].
Health Hazard
TOXIC; inhalation, ingestion or skin contact with material may cause severe injury or death. Contact with molten substance may cause severe burns to skin and eyes. Avoid any skin contact. Effects of contact or inhalation may be delayed. Fire may produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
Combustible material: may burn but does not ignite readily. When heated, vapors may form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated. Runoff may pollute waterways. Substance may be transported in a molten form.
Hydrazine hydrate Preparation Products And Raw materials
Raw materials
CHLORIC ACID Sodium hypochlorite Hydrogen peroxide Chlorine Urea Water Bone glue Chloramine-T Potassium permanganate Sodium hydroxide
Preparation Products
6-Fluoro-4-(trifluoromethyl)quinolin-2-amine ,97% 1H-INDAZOL-3-YLAMINE 3-Bromopropylamine hydrobromide 3-Hydrazinyl-N-methylpropanamide (1,3-DIMETHYL-BUTYL)-HYDRAZINE ETHYL 5-(2-FURYL)-1H-PYRAZOLE-3-CARBOXYLATE Methyl 4-amino-3-methylbenzoate 4,5-Dichloro-3(2H)-pyridazinone 3-AMINO-2-METHYLTHIENO[2,3-D]PYRIMIDIN-4(3H)-ONE (1,1-DIMETHYL-PROPYL)-HYDRAZINE 3-Hydrazinylpropanamide (2,2-DIMETHYL-PROPYL)-HYDRAZINE BENZYLHYDRAZINE DIHYDROCHLORIDE 9-PHENANTHROL 5-(2-FURYL)-4H-PYRAZOLE-3-CARBOXYLIC ACID 2,6-DIAMINO-4-CHLOROPYRIDINE 2-Hydrazinyl-N,N-dimethylacetamide 4-CHLOROPYRIDINE-2,6-DICARBOHYDRAZIDE 2-Hydrazinylacetamide 1-(2-Methoxyethyl)hydrazine 4-CHLORO-6-HYDRAZINO-PYRIMIDIN-5-YLAMINE 3-(Furan-2-yl)-1H-pyrazole-5-carbohydrazide ,97% 2,5-BIS(4-AMINOPHENYL)-1,3,4-OXADIAZOLE (1,2-DIMETHYL-PROPYL)-HYDRAZINE 4-Hydrazino-6-methylpyrimidin-2-amine Pyridazine 3,6-Dihydroxypyridazine 5-Bromothiophene-2-carbohydrazide 3-Hydrazinyl-N,N-dimethylpropanamide 3,3'-Dichlorobenzidine dihydrochloride 2-Hydrazinyl-N-methylacetamide 1-(3-Methoxypropyl)hydrazine 4-AMINO-N,N-DIMETHYLBENZYLAMINE 6-chloro-1H-indazol-3-amine 2-Chlorobenzhydrazide 4-tert-Butylbenzhydrazide 6-BOC-HYDRAZINONICOTINIC ACID 6-(AMINOMETHYL)-2-PYRIDINE CARBOXYLIC ACID 4,6-DIMETHYL-1H-PYRAZOLO[3,4-B]PYRIDIN-3-AMINE
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