ChemicalBook >> CAS DataBase List >>N-Phenyl-bis(trifluoromethanesulfonimide)
N-Phenyl-bis(trifluoromethanesulfonimide)
- CAS No.
- 37595-74-7
- Chemical Name:
- N-Phenyl-bis(trifluoromethanesulfonimide)
- Synonyms
- PHENYL TRIFLIMIDE;N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE;N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE);1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide;N-PHENYLTRIFLUOROMETHANESULFONIMIDE;phenyltrifluoromethanesulfonimide;N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE);trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide;N-PHENYLT;NSC 240874
- CBNumber:
- CB5289550
- Molecular Formula:
- C8H5F6NO4S2
- Molecular Weight:
- 357.25
- MDL Number:
- MFCD00000404
- MOL File:
- 37595-74-7.mol
- MSDS File:
- SDS
Last updated:2024-04-25 09:47:11
| Melting point | 100-102 °C(lit.) |
|---|---|
| Boiling point | 305.3±52.0 °C(Predicted) |
| Density | 1.766±0.06 g/cm3(Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | Soluble in methanol. Slightly soluble in chloroform and ethyl acetate. |
| pka | -13.12±0.50(Predicted) |
| form | Crystals or Crystalline Powder |
| color | White or colorless |
| Sensitive | Moisture Sensitive |
| BRN | 1269141 |
| Stability | Moisture Sensitive |
| InChI | InChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H |
| InChIKey | DIOHEXPTUTVCNX-UHFFFAOYSA-N |
| SMILES | C(F)(F)(F)S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(=O)=O |
| CAS DataBase Reference | 37595-74-7(CAS DataBase Reference) |
| FDA UNII | TIC0LRR43X |
| NIST Chemistry Reference | N-phenyltrifluoromethanesulfonimide(37595-74-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P264-P271-P280-P302+P352-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 26-36 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 21 | |||||||||
| TSCA | No | |||||||||
| HazardClass | IRRITANT | |||||||||
| HS Code | 29242100 | |||||||||
| NFPA 704 |
|
N-Phenyl-bis(trifluoromethanesulfonimide) price More Price(57)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 295973 | N-Phenyl-bis(trifluoromethanesulfonimide) 99% | 37595-74-7 | 5g | $82.1 | 2024-03-01 | Buy |
| Sigma-Aldrich | 295973 | N-Phenyl-bis(trifluoromethanesulfonimide) 99% | 37595-74-7 | 25g | $201 | 2024-03-01 | Buy |
| TCI Chemical | P1257 | N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent] >98.0%(GC) | 37595-74-7 | 5g | $23 | 2024-03-01 | Buy |
| TCI Chemical | P1257 | N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent] >98.0%(GC) | 37595-74-7 | 25g | $80 | 2024-03-01 | Buy |
| Alfa Aesar | L12531 | N-Phenylbis(trifluoromethanesulfonimide), 99% | 37595-74-7 | 5g | $72.1 | 2024-03-01 | Buy |
N-Phenyl-bis(trifluoromethanesulfonimide) Chemical Properties,Uses,Production
Description
N-Phenylbis(trifluoromethanesulfonimide) acts as a mild triflating reagent as well as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes. It is also employed as a reactant for the preparation of amphoteric alfa-boryl aldehydes. It plays an important role in the enantioselective synthesis of the core ring skeleton of leucosceptroids A-D and in steroselective sulfoxidation.
Chemical Properties
white to off-white crystalline powder
Uses
Acts as a transparent strong electron-withdrawing p-type dopant in carbon nanotubes
Reactant for:
Synthesis of amphoteric alpha-boryl aldehydes
Enantioselective synthesis of core ring skeleton of leucosceptroids A-D
Stereoselective synthesis of monoamine reuptake inhibitor NS9544 acetate
Stereoselective sulfoxidation
Uses
N-Phenylbis(trifluoromethanesulfonamide) is used in the enantioselective synthesis of β-amino acids via the Mannich reaction. Used in the synthesis of sphingosine 1-phosphate-1 receptor agonists useful in pharmaceutical application.
Synthesis
Add methylene chloride, aniline, 4-dimethylaminopyridine (DMAP), and triethylamine to a reactor equipped with a thermometer, distillation device, and mechanical stirring. When the vacuum of the reactor is evacuated to -0.095MPa and cooled to -40°C, trifluoromethanesulfonyl fluoride gas is introduced and then stirred at -20°C ~ 0°C and 0.02MPa ~ 0.1MPa reaction pressure, and react for 6 hours Finally, the excess trifluoromethanesulfonyl fluoride gas in the reactor is released and collected by cooling. After the inside of the reactor is brought to normal pressure, 500 mL of water is added, and the liquid is separated. A light yellow solid is obtained after the organic phase is heated to 40°C and methylene chloride is distilled. The light yellow solid is recrystallized with toluene to obtain 650g of white crystal N-Phenyl-bis(trifluoromethanesulfonimide).
Synthesis of N-Phenyl-bis(trifluoromethanesulfonimide) from Trifluoromethanesulfonic anhydride and Aniline
N-Phenyl-bis(trifluoromethanesulfonimide) Preparation Products And Raw materials
Raw materials
1of3
Preparation Products
Global( 493)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Jiangxi Time Chemical CO Ltd | +86-0794-7183888 +86-13155888520 | sales@groupchem.com | China | 27 | 58 |
| Fluoropharm Co., Ltd. | +86-0571-85586753; +8613336034509 | sales@fluoropharm.com | China | 1290 | 60 |
| SHANGHAI T&W PHARMACEUTICAL CO., LTD. | +86-021-61551413 +8618813727289 | contact@trustwe.com | China | 5738 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Zibo Hangyu Biotechnology Development Co., Ltd | +86-0533-2185556 +8617865335152 | Mandy@hangyubiotech.com | China | 11013 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Beijing Cooperate Pharmaceutical Co.,Ltd | 010-60279497 | sales01@cooperate-pharm.com | CHINA | 1811 | 55 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
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View Lastest Price from N-Phenyl-bis(trifluoromethanesulfonimide) manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-25 | N,N-Bis(trifluoromethylsulfonyl)aniline
37595-74-7
|
US $0.00 / KG | 1KG | ≥99% | 200mt/year | Jinan Finer Chemical Co., Ltd | |
 |
2024-01-02 | N-Phenyl-bis(trifluoromethanesulfonimide)
37595-74-7
|
US $65.00-650.00 / kg | 10kg | 0.99 | 20tons | Zibo Hangyu Biotechnology Development Co., Ltd | |
 |
2023-10-21 | N-Phenyl-bis(trifluoromethanesulfonimide)
37595-74-7
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd |
-
- N,N-Bis(trifluoromethylsulfonyl)aniline
37595-74-7
- US $0.00 / KG
- ≥99%
- Jinan Finer Chemical Co., Ltd
-
- N-Phenyl-bis(trifluoromethanesulfonimide)
37595-74-7
- US $65.00-650.00 / kg
- 0.99
- Zibo Hangyu Biotechnology Development Co., Ltd
-
- N-Phenyl-bis(trifluoromethanesulfonimide)
37595-74-7
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
37595-74-7(N-Phenyl-bis(trifluoromethanesulfonimide))Related Search:
Triphenylmethyl Chloride
O-Phthalimide
Lithium bis(trifluoromethanesulphonyl)imide
Aniline
Succinimide
Bismaleimide
Trifluoromethanesulfonyl chloride
Trifluoromethanesulfonimide
Dimethyl sulfone
N-Phenylmethanesulfonamide
1of4
1,1,1-TRIFLUORO-N-PHENYL-N-[(TRIFLUOROMETHYL)SULFONYL]METHANESULFONAMIDE
N-Phenylbis(trifluoromethanesulphonimide), Phenyl triflimide
N-Phenyl bis trifluorosulphonamide
N-Bis(trifluoromethylsulfonyl)aniline
1,1,1-trifluoro-N-(methylsulfonyl)methanesulfonamide
N- phenyl-bis (trifluoromethanesulfonyl) imide
N-Phenylbis(trifluoroMethanesulfoniMide), 97% 5GR
N,N-Bis(trifluoromethylsulfonyl)aniline
Phenyl Triflimide
N-Phenyltrifluoromethanesulfonimide
N,N-Bis(trifluoroMethylsufonyl)aniline
N,N-Bis(trifluoroMethylsulfonyl)aniline SynonyMs N-Phenylbis(trifluoroMethanesulfon)iMide
N-phenyldouble(threefluoro Methanesulfonic acidiMide
N-Phenyl-bis(trifluoroMethanesulfoniMide) >=98.0% (HPLC)
N,N-Bis(trifluoromethanesulphonyl)aniline~Phenyl triflimide~N-Phenyltrifluoromethanesulphonimide
Phenyl triflimide~N-Phenyltrifluoromethanesulphonimide
N-PHENYL-BIS-(TRIFLUORMETHANSULFONIMID)
N,N-BIS-(TRIFLUOROMETHANESULFONYL)ANILINE
1,1,1-Trifluoro-N-phenyl-N-(trifluoromethyl)sulphonylmethanesulphonamide
n-phenylbis(trifluorometanesulfonimide)
N-Phenyl-bis(trifluoromethyl)sulfonimide
N-Phenylbis(trifluoromethanesulfonimide) [Triflating Reagent]
N-phenyl-bis(trifluoromethanesulfonamide)
N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, Phenyl triflimide, 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide
N-Phenyltrifluoromethanesulfonimide ,98%
N-Phenyl-bis(trifluoromethanesulfonimide),1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide, N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide, Pheny
N,N-Bis(trifluoromethylsulphonyl)aniline 98%
N-Phenylbis(trifluoromethanesulfonyl)amine
N-Phenylbis(trifluoromethylsulfonyl)amine
N-Phenyl-N,N-bis(trifluoromethylsulfonyl)amine
N-Phenylbis(trifluoromethanesulphonimide)97%
N-Phenylbis(trifluoromethanesulfonimide),97%
N-Phenylbis(trifluromethanesulphonimide)99%
N-phenyl bis(trifluoromethanesulfonyl)amide
N-Phenyl-bis(trifluoromethanesulfonimide) 37595-74-7
N,N-Bis(trifluoromethylsulfonyl)aniline 37595-74-7
-bis(trifL
fonimide)
N-Phenylbis(trifluoromethanesulfonimide)[TriflatingReagent]>
Methanesulfonamide, 1,1,1-trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]-
1,1,1-trifluoro-N-phenyl-N
TIANFUCHEM--37595-74-7--N-Phenyl-bis(trifluoromethanesulfonimide) factory price
phenyltrifluoromethanesulfonimide
N-PHENYLBIS(TRIFLUOROMETHANESULFONIMIDE)
N-PHENYLBIS(TRIFLUOROMETHANESULPHONIMIDE)
N-PHENYLTRIFLUOROMETHANESULFONIMIDE
N-PHENYLTRIFLUOROMETHANESULPHONIMIDE
N,N-BIS(TRIFLUOROMETHYLSULFONYL)ANILINE
NSC 240874
1,1,1-trifluoro-N-phenyl-N-trifluoromethanesulfonylmethanesulfonamide
PHENYL TRIFLIMIDE
trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide
N-PHENYLT
Bis(trifluoromethylsulfonyl)aniline
N- phenylbis (trifluoromethanesulfonyl) imine
N-PHENYL-BIS(TRIFLUROMETHANSULPHONIMIDE)
N-phenylbis (trifluoromesulfonimide)
37595-74-7
7595-74-7
37595-74-4