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4-PHENYLETHYNYLPHTHALIC ANHYDRIDE

CAS No.
119389-05-8
Chemical Name:
4-PHENYLETHYNYLPHTHALIC ANHYDRIDE
Synonyms
4-PEPA;4-(Phenylethynyl)phthalic;4-phenylethylphthalic anhydride;Phenylethynylphthalic Anhydride;4-PHENYLETHYNYLPHTALIC ANHYDRIDE;4-PHENYLETHYNYLPHTHALIC ANHYDRIDE;3-Phenylethynylphthalic anhydride;5-Phenylethynyl-phthalic anhydride;4-Pheneylethynylphthalic anhydride;4-PhenylethynylphthalicAnhydride>
CBNumber:
CB5334539
Molecular Formula:
C16H8O3
Molecular Weight:
248.23
MDL Number:
MFCD10574892
MOL File:
119389-05-8.mol
MSDS File:
SDS
Last updated:2024-01-08 21:00:42

4-PHENYLETHYNYLPHTHALIC ANHYDRIDE Properties

Melting point 152 °C
Boiling point 466.9±28.0 °C(Predicted)
Density 1.38±0.1 g/cm3(Predicted)
storage temp. Inert atmosphere,Room Temperature
Water Solubility Practically insoluble in water
form powder to crystal
color White to Yellow to Green
EPA Substance Registry System 1,3-Isobenzofurandione, 5-(phenylethynyl)- (119389-05-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Risk Statements  36/37/38
Safety Statements  26-36/37/39
HS Code  29173990
NFPA 704
0
1 0

4-PHENYLETHYNYLPHTHALIC ANHYDRIDE price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical P1437 4-Phenylethynylphthalic Anhydride >98.0%(GC)(T) 119389-05-8 5g $128 2024-03-01 Buy
TCI Chemical P1437 4-Phenylethynylphthalic Anhydride >98.0%(GC)(T) 119389-05-8 25g $384 2024-03-01 Buy
GFS CHEMICALS 18232 PHENYLETHYNYLPHTHALICANH 119389-05-8 25g $291.46 2021-12-16 Buy
TRC P399525 4-Phenylethynylphthalic Anhydride 119389-05-8 500mg $75 2021-12-16 Buy
TRC P399525 4-Phenylethynylphthalic Anhydride 119389-05-8 50mg $45 2021-12-16 Buy
Product number Packaging Price Buy
P1437 5g $128 Buy
P1437 25g $384 Buy
18232 25g $291.46 Buy
P399525 500mg $75 Buy
P399525 50mg $45 Buy

4-PHENYLETHYNYLPHTHALIC ANHYDRIDE Chemical Properties,Uses,Production

Uses

4-Phenylethynylphthalic Anhydride is a useful research chemical.

Chemical Properties

Light yellow to light yellow-green crystal or powder

Preparation

The preparation of 4-phenylethynylphthalic anhydride is as follows:4-phenyl ethynyl dimethyl phthalate (33.6 g) was suspended in a mixed medium comprising water and methanol and a 25% by mass aqueous solution of sodium hydroxide (40 g) was dropwise added thereto with stirring. The resultant reaction mixture was stirred at 60° C. for 3 hours and, then, after confirming the completion of the reaction, cooled to the inside temperature of 30° C. Thereafter, 1 g of active carbon was added thereto, and, then, stirred for 30 minutes maintaining the same temperature. The resultant mixture was filtered to remove the active carbon, and rinsed with water. The filtrate and a rinsing solution were combined and, then, toluene and ethyl acetate were added to the resultant mixture. Concentrated hydrochloric acid (28 g) was dropwise added to the resultant 2-layered reaction mixture. The mixture was stirred for 30 minutes at room temperature and was allowed to stand, so that an organic layer containing 4-phenyl ethynyl phthalic acid was separated. After partially concentrating the organic layer, acetic anhydride (17 g) was added thereto, and the reaction mixture was refluxed with heating for 4 hours. After the reaction was completed, the resultant reaction mixture was cooled, so that 4-phenyl ethynyl phthalic anhydride was precipitated as a crystal. The crystal was filtered, rinsed and dried, to thereby obtain 26.6 g of 4-phenyl ethynyl phthalic anhydride as a pale yellow crystal. The yield was 94% on the basis of 4-phenyl ethynyl dimethyl phthalate.

119389-05-8.png

865354-04-7
119389-05-8
Synthesis of 4-PHENYLETHYNYLPHTHALIC ANHYDRIDE from 4-PHENYLETHYNYLPHTHALIC DIMETHYL ESTER
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View Lastest Price from 4-PHENYLETHYNYLPHTHALIC ANHYDRIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-(Phenylethynyl)phthalic anhydride pictures 2024-04-17 4-(Phenylethynyl)phthalic anhydride
119389-05-8
US $5.00 / kg 1kg ≥99% 200mt/year Jinan Finer Chemical Co., Ltd
4-Phenylethynylphthalic Anhydride pictures 2024-01-08 4-Phenylethynylphthalic Anhydride
119389-05-8
US $111.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
4-PHENYLETHYNYLPHTHALIC ANHYDRIDE pictures 2023-07-25 4-PHENYLETHYNYLPHTHALIC ANHYDRIDE
119389-05-8
US $0.00 / kg 1kg 99% 20 tons Hebei Yanxi Chemical Co., Ltd.
4-PEPA 4-PHENYLETHYNYLPHTHALIC ANHYDRIDE 4-(2-PHENYLETHYNYL)PHTHALIC ANHYDRIDE 3-Phenylethynylphthalic anhydride 5-Phenylethynyl-phthalic anhydride 4-PHENYLETHYNYLPHTALIC ANHYDRIDE 4-Phenylethynylphthalic anhydride ,98% 4-(Phenylethynyl)-1,2-benzenedicarboxylic anhydride 5-(Phenylethynyl)-1,3-isobenzofurandione 4-phenylethylphthalic anhydride 1,3-Isobenzofurandione, 5-(2-phenylethynyl)- 1,3-Isobenzofurandione, 5-(phenylethynyl)- Phenylethynylphthalic Anhydride 4-phenylethynylphthalic anhydride(4-PEPA) 4-(Phenylethynyl)phthalic 5-(phenylethynyl)-2-benzofuran-1,3-dione 5-(2-Phenylethynyl)-1,3-isobenzofurandione 4-Pheneylethynylphthalic anhydride 5-(Phenylethynyl)isobenzofuran-1,3-dione 4-(PHENYLETHYNYL)PHTHALIC ANHYDRIDE, 98%4-(PHENYLETHYNYL)PHTHALIC ANHYDRIDE, 98%4-(PHENYLETHYNYL)PHTHALIC ANHYDRIDE, 98%4-(PHENYLETHYNYL)PHTHALIC ANHYDRIDE, 98% 4-PhenylethynylphthalicAnhydride> 4-PHENYLETHYNYL PHTHALIC ANHYDRIDE(4-PEPA) 119389-05-8 4-Phenylethynylphthalic anhydride (PEPA) (4-PEPA) 4-PHENYLETHYNYLPHTHALIC ANHYDRIDE 119389-05-8 Functionalized Acetylenes Acetylenes strong recommend Acetylenes Functionalized Acetylenes 119389-05-8