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Diethylene Glycol Monoethyl Ether

CAS No.
111-90-0
Chemical Name:
Diethylene Glycol Monoethyl Ether
Synonyms
Transcutol;CARBITOL;2-(2-ETHOXYETHOXY)ETHANOL;Dowanol;ETHYL CARBITOL;ETHYL DIGLYCOL;Dowanol DE;ETHYL DIGOL;ETHOXYETHOXYETHANOL;ethyldiethyleneglycol
CBNumber:
CB5376207
Molecular Formula:
C6H14O3
Molecular Weight:
134.17
MDL Number:
MFCD00002872
MOL File:
111-90-0.mol
MSDS File:
SDS
Last updated:2023-12-22 17:53:22

Diethylene Glycol Monoethyl Ether Properties

Melting point -80 °C
Boiling point 202 °C(lit.)
Density 0.999 g/mL at 25 °C(lit.)
vapor density 4.63 (vs air)
vapor pressure 0.12 mm Hg ( 20 °C)
refractive index n20/D 1.427(lit.)
Flash point 205 °F
storage temp. Store below +30°C.
solubility water: soluble
form Liquid
pka 14.37±0.10(Predicted)
color Clear colorless
Odor Weakly fruity; mild and characteristic.
Evaporation Rate 0.02
explosive limit 1.8-12.2%(V)
Water Solubility Miscible
Sensitive Hygroscopic
Merck 14,1800
BRN 1736441
Stability Stable. Combustible. Note wide explosion limits. Incompatible with strong oxidizing agents, strong acids, acid chlorides, acid anhydrides. Hygroscopic.
InChIKey XXJWXESWEXIICW-UHFFFAOYSA-N
LogP -0.54 at 20℃
Indirect Additives used in Food Contact Substances DIETHYLENE GLYCOL MONOETHYL ETHER
FDA 21 CFR 175.105; 176.180
CAS DataBase Reference 111-90-0(CAS DataBase Reference)
FDA UNII A1A1I8X02B
NIST Chemistry Reference Ethanol, 2-(2-ethoxyethoxy)-(111-90-0)
EPA Substance Registry System Diethylene glycol monoethyl ether (111-90-0)
Cosmetics Info Ethoxydiglycol

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H332
Precautionary statements  P261-P271-P304+P340+P312
Hazard Codes  Xn,Xi
Risk Statements  36-20-36/37/38
Safety Statements  23-24/25-39-26-36
WGK Germany  1
RTECS  KK8750000
Autoignition Temperature 204 °C
TSCA  Yes
HS Code  29094400
Toxicity LD50 orally in rats: 8.69 g/kg (Smyth, Carpenter)
NFPA 704
2
2 0

Diethylene Glycol Monoethyl Ether price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.03127 Diethylene glycol monoethyl ether for synthesis 111-90-0 1L $38.5 2024-03-01 Buy
Sigma-Aldrich 8.03127 Diethylene glycol monoethyl ether for synthesis 111-90-0 2.5L $64.4 2024-03-01 Buy
Sigma-Aldrich 8.03127 Diethylene glycol monoethyl ether for synthesis 111-90-0 25L $382 2024-03-01 Buy
Sigma-Aldrich 537616 Diethylene glycol monoethyl ether ReagentPlus , 99% 111-90-0 1l $76 2024-03-01 Buy
Sigma-Aldrich 537616 Diethylene glycol monoethyl ether ReagentPlus , 99% 111-90-0 4l $256 2024-03-01 Buy
Product number Packaging Price Buy
8.03127 1L $38.5 Buy
8.03127 2.5L $64.4 Buy
8.03127 25L $382 Buy
537616 1l $76 Buy
537616 4l $256 Buy

Diethylene Glycol Monoethyl Ether Chemical Properties,Uses,Production

Chemical Properties

Diethylene glycol monoethyl ether is a colorless, stable, hygroscopic liquid of a mild, pleasant odor. It is completely miscible with water, alcohols, ethers, ketones, aromatic and aliphatic hydrocarbons, and halogenated hydrocarbons. Owing to the fact that it contains an ether-alcohol-hydrocarbon group in the molecule, it has the power to dissolve a wide variety of substances such as oils, fats, waxes, dyes, camphor and natural resins like copal resin, kauri, mastic, rosin, sandarac, shellac, as well as several types of synthetic resins. It is used as a solvent in synthetic resin coating compositions, and in lacquers, where high-boiling solvents are desired.

Occurrence

Has apparently not been reported to occur in nature.

Uses

Usually used as solvent for the polymer electrospinning.

Uses

Diethylene glycol monoethyl ether has low setting point and low viscocity at low temperature so it is used in manufacturing brake fluid. It is used as a flow and gloss promoter in paint industries, in production of printing ink and as a cleaner in offset printing. Also used in textile as a solvent for dyestuff in the printing and dying of fiber & fabrics, in the production & wood preservaties.

Uses

Di(ethylene glycol) ethyl ether is suitable for use as solvent for the polymer electrospinning.

Definition

ChEBI: A primary alcohol that is ethanol substituted by a 2-ethoxyethoxy group at position 2.

Preparation

From ethyl alcohol plus ethylene oxide (Arctander, 1969).

General Description

A colorless, slightly viscous liquid with a mild pleasant odor. Flash point near 190°F. Used to make soaps, dyes, and other chemicals.

Air & Water Reactions

Slightly denser than water and soluble in water. Oxidizes readily in air to form unstable peroxides that may explode spontaneously [Bretherick, 1979 p.151-154, 164].

Reactivity Profile

Mixing 2(2-Ethoxyethoxy)ethanol in equal molar portions with any of the following substances in a closed container caused the temperature and pressure to increase: chlorosulfonic acid and oleum, NFPA 1991.

Health Hazard

None expected.

Fire Hazard

2(2-Ethoxyethoxy)ethanol is combustible.

Chemical Reactivity

Reactivity with Water : No reaction; Reactivity with Common Materials: No reaction; Stability During Transport: Stable; Neutralizing Agents for Acids and Caustics: Not pertinent; Polymerization: V; Inhibitor of Polymerization: Not pertinent.

Safety Profile

irritation, and unspecified eye effects, cough,

Metabolism

The major part of an administered dose of diethylene glycol monoethyl ether is oxidized in the body or excreted as the glucuronate, administration to rabbits orally or by sc injection being followed by a marked increase in the urinary content of glucuronic acid (Fellows, Luduena & Hanzlik, 1947).

Purification Methods

Ethylene glycol can be removed by extracting 250g in 750mL of *benzene with 5mL portions of water, allowing for phase separation, until successive aqueous portions show the same volume increase. Dry, and free from peroxides, as described for diethylene glycol mono-n-butyl ether. [Beilstein 1 IV 2393.]

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View Lastest Price from Diethylene Glycol Monoethyl Ether manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
ETHOXY DIGLYCOL pictures 2024-03-28 ETHOXY DIGLYCOL
111-90-0
US $30.00 / KG 200KG 99% 1000kg/day Hebei Yime New Material Technology Co., Ltd.
Diethylene Glycol Monoethyl Ether pictures 2024-03-28 Diethylene Glycol Monoethyl Ether
111-90-0
US $5.00 / KG 200KG 99% 1000kg/day Hebei Yime New Material Technology Co., Ltd.
Diethylene Glycol Monoethyl Ether pictures 2023-12-23 Diethylene Glycol Monoethyl Ether
111-90-0
US $50.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
  • ETHOXY DIGLYCOL pictures
  • ETHOXY DIGLYCOL
    111-90-0
  • US $30.00 / KG
  • 99%
  • Hebei Yime New Material Technology Co., Ltd.
monoethyletherofdiethyleneglycol O-Ethyldigol pm1799 Poly-Solv DE Poly-solv DE ethanol, 2,2'-oxybis-, monoethyl ether poly-solvde Solvent APV Spec Solvolsol Carbitol 2-(2-Ethoxyethoxy)ethanol DIETHYLENE GLYCOL MONOETHYL ETHER FOR SY Diethylene glycol monoethyl ether ,99% Diethylene glycol monoethyl ether,2-(2-Ethoxyethoxy)ethanol, CARBITOL, Diethylene glycol ethyl ether, Ethyldiglycol Diethylene glycol monoethyl ether, synthesis grade Di(ethylene glycol) ethyl ether,2-(2-Ethoxyethoxy)ethanol, CARBITOL, Diethylene glycol ethyl ether, Diethylene glycol monoethyl ether, Ethyldiglycol 2(2-Ethoxyethoxy)ethanol, pure, 98+% 2(2-Ethoxyethoxy)ethanol, 98+%, pure 2(2-Ethoxyethoxy)ethanol, 98+% 1LT DE Solvent ETHOXY DIGLYCOL DIETHYLENE GLYCOL MONOETHYL ETHER DI(ETHYLENE GLYCOL)ETHYL ETHER DIGLYCOL MONOETHYL ETHER CARBITOL(R) CARBITOL SOLUTION CARBITOL(TM) Carbit0l DECS DIETHYLENE GLYCOL MONOETHYL ETHER(DE) Diethylene glycol Monoethyl ether, 99.5% Diethylene glycol Monoethyl ether, 99.5%, 99.5% Diethylene glycol Monoethyl et Diethylene glycol monoethyl ether ReagentPlus(R), 99% Diethylene glycol monoethyl ether Vetec(TM) reagent grade, 99% Diethylene glycol momoethyl ether Diethylene Glycol Monoethyl Ether 〔2-(2-Ethoxyethoxy)ethanol〕 Carbitol (Union Carbide) Diethylene glycol monoethyl ether (diethylene glycol diethyl ether) Diethyleneglycolmonoethyleth Dioxitol Dioxitol-low gravity 1-Hydroxy-3,6-dioxaoctane 2-(2-ethoxyethoxy)-ethano 2-(beta-Ethoxyethoxy)ethanol 2-(beta-Ethoxyethoxy)ethanol diglycol 2-(Ethoxyethoxy)ethanol dowanol17 dowanolde Eastman DE Ektasolve DE Ektasolve DE, DE-HG ektasolvede Ethanol, 2,2'-oxybis-, monoethyl ether Ethanol,2-(2-ethoxyethoxy)- DI(ETHYLENE GLYCOL) ETHYL ETHER 99+% DIETHYLENE GLYCOL MONOETHYL ETHERGC STANDARD DiethyleneGlycolMonoethylEther(EthylCarbitol) 2-(2-ETHOXYETHOXY)ETHANOL,REAGENT 2(2-Ethoxyethoxy)ethanol, 98+%