ChemicalBook >> CAS DataBase List >>1-Butyl-3-methylimidazolium hexafluorophosphate

1-Butyl-3-methylimidazolium hexafluorophosphate

1-Butyl-3-methylimidazolium hexafluorophosphate structure

CAS No.: 174501-64-5

Chemical Name:: 1-Butyl-3-methylimidazolium hexafluorophosphate

Synonyms: BMIMPF6;1-butyl-3-methylimidazolium hexafluorophsphate;1-N-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE;SKL1399;-3-methyL;ium hexafL;JACS-174501-64-5;1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPH;1-BUTYL-3-METHYL-IMIDAZOLIUM HEXAFLUOROP;Butylmethylimidazolium Hexafluorophosphate

CBNumber:: CB6203652

Molecular Formula:: C8H15F6N2P

Molecular Weight:: 284.18

MDL Number:: MFCD03093295

MOL File:: 174501-64-5.mol

MSDS File:: SDS

Last updated:2024-04-01 18:08:31

Request For Quotation

1-Butyl-3-methylimidazolium hexafluorophosphate Properties

Melting point	6.5 °C
Boiling point	>340°C
Density	1.38 g/mL at 20 °C (lit.)
refractive index	n20/D 1.41
Flash point	>350°C
storage temp.	Store below +30°C.
solubility	Acetone, Methanol
form	Viscous Liquid
Specific Gravity	1.396
color	Clear colorless to pale yellow
PH	5 (H2O, 20℃)
Viscosity	267 cP
Water Solubility	Miscible with dichloromethane, chloroform, ethyl acetate. Immiscible with water, diethyl ether and hexane.
Hydrolytic Sensitivity	4: no reaction with water under neutral conditions
Merck	14,1581
InChIKey	IXQYBUDWDLYNMA-UHFFFAOYSA-N
CAS DataBase Reference	174501-64-5(CAS DataBase Reference)
FDA UNII	ZGE3N4O8Q9
ECW	4.2 V

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H315-H319

Precautionary statements

P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313

Hazard Codes

Risk Statements

Safety Statements

WGK Germany

TSCA

HazardClass

IRRITANT

HS Code

29339900

NFPA 704

	1
2		1

1-Butyl-3-methylimidazolium hexafluorophosphate price More Price(44)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	18122	1-Butyl-3-methylimidazolium hexafluorophosphate for catalysis, ≥98.5% (T)	174501-64-5	5G	$150	2024-03-01	Buy
Sigma-Aldrich	18122	1-Butyl-3-methylimidazolium hexafluorophosphate for catalysis, ≥98.5% (T)	174501-64-5	50g	$1440	2024-03-01	Buy
TCI Chemical	B2320	1-Butyl-3-methylimidazolium Hexafluorophosphate >98.0%(HPLC)(N)	174501-64-5	5g	$32	2024-03-01	Buy
TCI Chemical	B2320	1-Butyl-3-methylimidazolium Hexafluorophosphate >98.0%(HPLC)(N)	174501-64-5	25g	$86	2024-03-01	Buy
Alfa Aesar	L19086	1-n-Butyl-3-methylimidazolium hexafluorophosphate, 98+%	174501-64-5	5g	$38.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
18122	5G	$150	Buy
18122	50g	$1440	Buy
B2320	5g	$32	Buy
B2320	25g	$86	Buy
L19086	5g	$38.65	Buy

1-Butyl-3-methylimidazolium hexafluorophosphate Chemical Properties,Uses,Production

Conductivity

1.92 mS/cm

Chemical Properties

Clear pale yellow oil

Uses

1-Butyl-3-methylimidazolium hexafluorophosphate is an ionic liquid employed in many environmentally friendly reactions.

It can also be used as a medium for reactions such as:

Ring-closing metathesis of diene and enyne substrates in the presence of a novel recyclable ruthenium carbene complex.
Nickel(II)acetylacetonate catalyzed oxidation of aromatic aldehydes to the corresponding acids using dioxygen as the oxidant.
Lipase-catalyzed enantioselective acylation of allylic alcohols.
Allylation of aldehydes using tetraallylstannane to yield homoallylic alcohols.

Uses

those consisting of tetrafluoroborate, alkylsulfate, alkylsulfonate, carboxylate, or phosphate anions are hydrophilic and are completely dissolved in water. Dupont and coworkers first reported stable hydrophobic imidazolium salt, 1-butyl-3-methylimidazolium hexafluorophosphate ([C4mim][PF6]) in 1996. Since then, this salt has been used as a typical hydrophobic IL in many chemical reactions because its mixture with water forms a biphasic layer. Furthermore, this IL shows poor solubility in hexane or ether, which allows realization of an easy work-up process. However, [C4mim][PF6] was reported to be sensitive to the moisture at high temperature and produced hazardous hydrogen fluoride as it decomposed. Therefore, bis(trifluoromethanesulfonyl)amide (NTf2) salts are now recommended as the anion for preparing hydrophobic ILs.

General Description

1-Butyl-3-methylimidazolium hexafluorophosphate is an imidazolium-based, hydrophobic, room temperature ionic liquid (RTIL). It can be prepared by reacting 1-methylimidazole with chlorobutane. Gaseous hydrofluorocarbons (HFCs) such as fluoromethane, fluoroethane and 1,1,2,2-tetrafluoroethane are soluble in BMIMPF₆.

1-Butyl-3-methylimidazolium hexafluorophosphate synthesis

Synthesis of 1-Butyl-3-methylimidazolium hexafluorophosphate from 1-Methylimidazole and 1-Chlorobutane

1-Butyl-3-methylimidazolium hexafluorophosphate Preparation Products And Raw materials

Raw materials

Sodium hexafluorophosphate 1-Methylimidazole 1-Bromobutane Toluene Hexafluorophosphoric acid

Potassium hexafluorophosphate Dichloromethane Methanol 1-Butylimidazole 1-Butyl-3-methylimidazolium chloride

1-Butyl-3-methylimidazolium bromide 1-BUTYL-3-METHYLIMIDAZOLIUM IODIDE 1-Chlorobutane

1of3

Preparation Products

3-Iodo-4,5-dimethoxybenzaldehyde

1-Butyl-3-methylimidazolium hexafluorophosphate Suppliers

Global( 446)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Henan Allgreen Chemical Co.,LTD	+86-37155567971 +86-13633837469	info@allgreenchem.com	China	5986	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15371	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
Nanjing MSN chemical Co., Ltd	25-57015632 +8618913029712	export@msnchem.com	China	25	34
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	+86 18953170293	sales@sdzschem.com	China	2931	58
Changzhou Ansciep Chemical Co., Ltd.	+86 519 86305871	sales@ansciepchem.com	CHINA	4242	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58

Supplier	Advantage
Henan Allgreen Chemical Co.,LTD	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Nanjing MSN chemical Co., Ltd	34
career henan chemical co	58
SHANDONG ZHI SHANG CHEMICAL CO.LTD	58
Changzhou Ansciep Chemical Co., Ltd.	58
Hubei Jusheng Technology Co.,Ltd.	58
Accela ChemBio Inc.	58

View Lastest Price from 1-Butyl-3-methylimidazolium hexafluorophosphate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-02	1-Butyl-3-methylimidazolium hexafluorophosphate 174501-64-5	US $0.00-0.00 / kg	1kg	99%	50000kg	Hebei Yibangte Import and Export Co. , Ltd.
2023-06-07	1-Butyl-3-methylimidazolium hexafluorophosphate 174501-64-5	US $5.00-2.00 / KG	1KG	99%	10000kg	Hebei Guanlang Biotechnology Co,.LTD
2023-03-20	1-Butyl-3-methylimidazolium hexafluorophosphate 174501-64-5	US $0.00 / kg	1kg	98.0%min	100kg	LY Global chemicals co.,ltd .

1-Butyl-3-methylimidazolium hexafluorophosphate
174501-64-5
US $0.00-0.00 / kg
99%
Hebei Yibangte Import and Export Co. , Ltd.

1-Butyl-3-methylimidazolium hexafluorophosphate
174501-64-5
US $5.00-2.00 / KG
99%
Hebei Guanlang Biotechnology Co,.LTD

1-Butyl-3-methylimidazolium hexafluorophosphate
174501-64-5
US $0.00 / kg
98.0%min
LY Global chemicals co.,ltd .

174501-64-5(1-Butyl-3-methylimidazolium hexafluorophosphate)Related Search:

1-Butylimidazole Pinacolone tert-Butyl methyl ether 2-Butoxyethanol Cyhalofop-butyl

Buprofezin tert-Butyl peroxyacetate Butyl acrylate 1-Methylimidazole tert-Butyldimethylsilyl chloride

BUTYL OLEATE Diethylene glycol monobutyl ether Butyl acetate Lithium hexafluorophosphate Hexafluorophosphate

3-METHYL-1-OCTYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE 1-BUTYL-2,3-DIMETHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE 1-Hexyl-3-methylimidazolium hexafluorophosphate

1of4

1-Butyl-3-methylimidazolium hexafluorophosphate≥ 98.5%(HPLC) 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE 1-BUTYL-3-METHYLIMIDAZOLIUM HEXFLUOROPHOSPHATE 1-Butyl-3-MethyliMidazoliuM hexafluorophosphate >=97.0% (HPLC) 1-butyl-3-methylimmidazolium hexafluorophosphate 1-Butyl-3-methylimidazolium hexafluorophosphate for catalysis, >=98.5% (T) 1-Butyl-3-Methyl-1h-Imidazolium Hexafluorophosphate 1-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPH 1-Butyl-3-methylimidazolium hexafluorophosphate 97% 1-Butyl-3-methylimidazoliumhexafluorophosphate97% 1-N-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE 99% 1-n-Butyl-3-methylimidazolium hexafluorophosphate, 98+% 1-Butyl-3-methylimidazolium hexafluorophosphate ,99% Butylmethylimidazolium Hexafluorophosphate 1-Butyl-3-methylimidazolium hexafluorophosphate, 98+% 1-Butyl-3-methylimidazol-3-ium hexafluorophosphate 97% 1-Butyl-3-MethyliMidazoliuM hexafluorophosphate 25GR 1-Butyl-3-Methyl-1H-iMidazol-3-iuM hexafluorophosphate(V) 1-(But-1-yl)-3-methyl-1H-imidazol-3-ium hexafluorophosphate 97% JACS-174501-64-5 1-butyl-3-methyl-1H-imidazole-1,3-diium hexafluorophosphate 1-Butyl-3-methylimidazolium hexafluorophosphate in stock Factory 1-Butyl-3-methylimidazolium Hexafluorophosphate > 1-Butyl-3-methylimidazolium hexafluorophosphate, 99%, for synthesis 1-BUTYL-3-METHYL-IMIDAZOLIUM HEXAFLUOROP ium hexafL -3-methyL SKL1399 1-Butyl-3-methyl-imidazol-3-ium hexafluorophosphate 1-Butyl-3-methylimidazolium hexafluorophosphate, ≥98.5% 1-Butyl-3-methylimidazolium hexafluorophosphate, 97% (HPLC) 1-Butyl-3-Methylimidazolium Hexafluorophosphate (BMIM PF6) extrapure, 98% 1-Butyl-3-methylimidazolium hexafluorophosphate (HPLC) 1-N-BUTYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE BMIMPF6 1-butyl-3-methylimidazolium hexafluorophsphate 1-Butyl-3-methylimidazolium hexafluorophosphate [BMIm]PF6 1-Butyl-3-methylimidazole hexafluorophosphate 174501-64-5 C8H17F6N2P C8H15N2.F6P C8H15F6N2P C8H15N2PF6 C8H16F6N2P Imidazolium Imidazolium Compounds Ionic Liquids Imidazolium Salts (Ionic Liquids) Ionic liquid Imidazolium Compounds Imidazolium Salts (Ionic Liquids) Ionic Liquids Synthetic Organic Chemistry 174501-64-5