Tetrabutyl titanate
- CAS No.
- 5593-70-4
- Chemical Name:
- Tetrabutyl titanate
- Synonyms
- TITANIUM BUTOXIDE;TNBT;TETRA-N-BUTYL TITANATE;tetrabutoxytitanium;BUTYL TITANATE;TITANIUM(IV) BUTOXIDE;TITANIUM TETRABUTOXIDE;TETRABUTYL ORTHOTITANATE;Tyzor TBT;titaniuM salt
- CBNumber:
- CB6222404
- Molecular Formula:
- C16H36O4Ti
- Molecular Weight:
- 340.32
- MDL Number:
- MFCD00009433
- MOL File:
- 5593-70-4.mol
- MSDS File:
- SDS
| Melting point | -55°C |
|---|---|
| Boiling point | 206 °C/10 mmHg (lit.) |
| Density | 1.00 g/mL at 20 °C (lit.) |
| vapor pressure | 5.6 hPa (20 °C) |
| refractive index |
n |
| Flash point | 55 °F |
| storage temp. | Store at +2°C to +8°C. |
| solubility | Miscible with aliphatic, aromatic, chlorinated and oxygenated solvents. |
| form | Liquid |
| Specific Gravity | 0.998 |
| color | Pale yellow |
| explosive limit | 2.0-12.0%(V) |
| Water Solubility | RAPIDLY HYDROLIZED |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| BRN | 4148236 |
| Stability | Stable, but moisture sensitive. Flammable. Incompatible with water, moisture, strong oxidizing agents, strong acids. |
| InChIKey | YHWCPXVTRSHPNY-UHFFFAOYSA-N |
| LogP | 0.84 at 25℃ |
| Indirect Additives used in Food Contact Substances | TETRABUTYL TITANATE |
| FDA 21 CFR | 175.300; 177.1590 |
| CAS DataBase Reference | 5593-70-4(CAS DataBase Reference) |
| FDA UNII | FJS8Q2MX9I |
| NIST Chemistry Reference | Tetrabutoxytitanium(5593-70-4) |
| EPA Substance Registry System | Tetrabutyl titanate (5593-70-4) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS02,GHS05,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H315-H318-H335-H336 | |||||||||
| Precautionary statements | P210-P233-P240-P280-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | Xi,T | |||||||||
| Risk Statements | 10-36/37/38-67-41-37/38-45 | |||||||||
| Safety Statements | 16-26-39-24/25-53 | |||||||||
| RIDADR | UN 1993 3/PG 3 | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | XR1585000 | |||||||||
| F | 21 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29051900 | |||||||||
| Toxicity | LD50 orally in Rabbit: 3122 mg/kg | |||||||||
| NFPA 704 |
|
Tetrabutyl titanate price More Price(27)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 8.21084 | Tetra-n-butyl orthotitanate forsynthesis | 5593-70-4 | 100mL | $40.9 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.21084 | Tetra-n-butyl orthotitanate forsynthesis | 5593-70-4 | 500mL | $136 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.21084 | Tetra-n-butyl orthotitanate forsynthesis | 5593-70-4 | 10Kg | $640 | 2024-03-01 | Buy |
| Sigma-Aldrich | 244112 | Titanium(IV) butoxide reagent grade, 97% | 5593-70-4 | 5g | $42.1 | 2024-03-01 | Buy |
| Sigma-Aldrich | 244112 | Titanium(IV) butoxide reagent grade, 97% | 5593-70-4 | 2kg | $282 | 2024-03-01 | Buy |
Tetrabutyl titanate Chemical Properties,Uses,Production
Chemical Properties
colourless to light yellow viscous liquid
Uses
Titanium(IV) butoxide is a sourcing material for the preparation of titanium oxide (TiO2) which can further be used in a variety of applications such as dye sensitized solar cells (DSSCs), photo-catalytic and self-cleaning based coatings.
Uses
Titanium(IV) n-butoxide is used in the preparation of nanosized titania powders in the anatase form and ferroelectric bismuth titanate thin films. It is also used as intermediates, paint additives, coating additives, processing aids and as process regulators. It is involved in the preparation of nanocrystalline titanium dioxide powders at room temperature.
Uses
Ester exchange reactions; heat-resistant paints (up to 500C); improving adhesion of paints, rubber, and plastics to metal surfaces; cross-linking agent; condensation catalyst.
General Description
A water-white to pale-yellow liquid with an alcohol-like odor. About the same density as water. Flash point 170°F. Contact may irritate or cause burns.
Air & Water Reactions
Soluble in water. Reacts with water to form butanol and titanium dioxide, the reaction is not generally thought to be hazardous.
Reactivity Profile
Organometallics are strongly reactive with many other groups. Incompatible with acids and bases. Organometallics are good reducing agents and therefore incompatible with oxidizing agents. Often reactive with water to generate toxic or flammable gases. Generally highly toxic. Often react on contact with tissues to give toxic products.
Health Hazard
LIQUID: Irritating to skin and eyes. If swallowed will cause nausea and vomiting.
Fire Hazard
Combustible. Containers may explode in fire. May give off dense white smoke. Containers may explode.
Flammability and Explosibility
Flammable
Safety Profile
Suspected carcinogen. A poison by intravenous route. Moderately toxic by ingestion. See n-BUTYL ALCOHOL and TITANIUM COMPOUNDS. Flammable when exposed to heat or flame. To fight fire, use water, spray, foam, dry chemical. Incompatible with oxidizing materials. When heated to decomposition it emits acrid and irritating fumes.
Purification Methods
Dissolve it in *C6H6, filter if solid is present, evaporate and vacuum fractionate through a Widmer 24inch column (p 11). The ester hydrolyses when exposed to air to give hydrated ortho-titanic acid. The titanium content can be determined thus: weigh a sample (ca 0.25g) into a weighed crucible and cover it with 10mL of H2O and a few drops of conc HNO3. Heat (hot plate) carefully till most of the H2O has evaporated. Cool and add more H2O (10mL) and conc HNO3 (2mL), and evaporate carefully (no spillage) to dryness and ignite the residue at 600-650o/1hour. Weigh the residual TiO2. [Bradley et al. J Chem Soc 2773 1952, Speer J Org Chem 14 655 1949, Beilstein 1 II 398, 1 III 1515, 1 IV 1415.]
Tetrabutyl titanate Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Huzhou Haipu Chemical Co.,Ltd | +86-0572-+86-0572-2526078 +8613757061525 | xatyang@acetylacetone.net | China | 16 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Dalian Richfortune Chemicals Co., Ltd | 0411-84820922 8613904096939 | sales@richfortunechem.com | China | 303 | 57 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| Shanghai Time Chemicals CO., Ltd. | +86-021-57951555 +8617317452075 | jack.li@time-chemicals.com | China | 1807 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
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View Lastest Price from Tetrabutyl titanate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-09 | Tetrabutyl orthotitanate
5593-70-4
|
US $4500.00 / T | 1T | 99% | 600T | Shandong Luning Pharmaceutical Co., Ltd. | |
 |
2023-10-17 | Tetrabutyl titanate
5593-70-4
|
US $0.00 / kg | 1kg | 99% | 20tons | Hebei Yanxi Chemical Co., Ltd. | |
 |
2023-09-14 | Tetrabutyl orthotitanate
5593-70-4
|
US $10.00 / bottle | 1bottle | 99% | 100MT | Wuhan Han Sheng New Material Technology Co.，Ltd |
-
- Tetrabutyl orthotitanate
5593-70-4
- US $4500.00 / T
- 99%
- Shandong Luning Pharmaceutical Co., Ltd.
-
- Tetrabutyl titanate
5593-70-4
- US $0.00 / kg
- 99%
- Hebei Yanxi Chemical Co., Ltd.
-
- Tetrabutyl orthotitanate
5593-70-4
- US $10.00 / bottle
- 99%
- Wuhan Han Sheng New Material Technology Co.，Ltd