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2-Bromo-9-fluorenone

2-Bromo-9-fluorenone Structure
2-Bromo-9-fluorenone structure
CAS No.
3096-56-8
Chemical Name:
2-Bromo-9-fluorenone
Synonyms
2-Bromo-9H-fluoren-9-one;2-Bromo-9-fL;2-Bromofluorenone;2-BROMO-9-FLUORENONE;2-Bromo –fluororenone;2-BroMo-9H-fluorenone;2-BROMOFLUOREN-9-ONE;2-Bromo-9-Fluorenone98%;2-Bromo-9-fluorenone >2-Bromo-9-Fluorenone 98%
CBNumber:
CB6682655
Molecular Formula:
C13H7BrO
Molecular Weight:
259.1
MDL Number:
MFCD00010789
MOL File:
3096-56-8.mol
Last updated:2023-12-24 21:24:35
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2-Bromo-9-fluorenone Properties

Melting point 146-148 °C (lit.)
Boiling point 392.8±21.0 °C(Predicted)
Density 1.4633 (rough estimate)
refractive index 1.5130 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility Solubility in other solvents, soluble in acetone.
form powder to crystal
color Light yellow to Yellow to Orange
CAS DataBase Reference 3096-56-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-37/39
WGK Germany  3
Hazard Note  Irritant
HS Code  29143990
NFPA 704
1
2 0

2-Bromo-9-fluorenone price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 300128 2-Bromo-9-fluorenone 96% 3096-56-8 100mg $108 2023-06-20 Buy
TCI Chemical B3109 2-Bromo-9-fluorenone >98.0%(GC) 3096-56-8 5g $24 2024-03-01 Buy
TCI Chemical B3109 2-Bromo-9-fluorenone >98.0%(GC) 3096-56-8 25g $64 2024-03-01 Buy
Alfa Aesar H55962 2-Bromo-9-fluorenone, 96% 3096-56-8 1g $47 2023-06-20 Buy
Alfa Aesar H55962 2-Bromo-9-fluorenone, 96% 3096-56-8 5g $184 2023-06-20 Buy
Product number Packaging Price Buy
300128 100mg $108 Buy
B3109 5g $24 Buy
B3109 25g $64 Buy
H55962 1g $47 Buy
H55962 5g $184 Buy

2-Bromo-9-fluorenone Chemical Properties,Uses,Production

Description

2-Bromo-9-fluorenone is a brominated derivative of 9-Fluorenone which is used in the preparation of antimalarial drugs. It is used as organic intermediates functional materials. It is mainly used as best liquid crystal material. It is used as an OLED intermediate. the maximum and minimum solubility of 2-bromo-9-fluorenone was 0.0526 (mole fraction) in 1,4-dioxane at 323.15 K and 0.0002 (mole fraction) in methanol at 278.15 K, respectively, and the solubility increased with the increase in temperature in all solvents[1].

Chemical Properties

yellow powder

Uses

2-Bromo-9-fluorenone, a functional material as an organic intermediate. It is the best liquid crystal material and is used as an intermediate for OLED.

Application

2-Bromo-9-fluorenone was used:
as end-capping agent for poly(9,9-dialkylfluorene-2,7-diyl) derivatives
in synthesis of 2-bromo-9-hydroxy-9-(2-biphenyl)fluorene
in preparation of spirobifluorene ligands
in synthesis of altitudinal molecular motors which contain functional groups in their rotor part
in synthesis of FB

Synthesis

The synthesis of 2-Bromo-9-fluorenone is as follows：the 9-fluorenone (10mmol), the phase transfer catalyst (1.5mmol fourteen alkyl trimethyl ammonium chloride) and brominated aqueous ammonium solution (30 wt %, 25mmol ammonium bromide) mixing and heating system temperature to 75 °C, in 1h is divided into three time 11mmol potassium bromate, to three times the weight ratio of 1:3:1, to maintain the system temperature to continue reaction 3h, wherein the 9-fluorenone, ammonium bromide, the molar ratio of potassium bromate 1 : 2.5: 1.1 ; 9-fluorenone, and fourteen alkyl trimethyl ammonium chloride (phase-transfer catalyst) molar ratio of 1 : 0.15; 2) after the reaction, to room temperature, by adding 20% aqueous solution of sodium sulfite ( eliminates the bromine fluid ), is filtered, the filter cake washing water And dried to obtain yellow solid of 2-Bromo-9-fluorenone, the yield is 99.2%.
3096-56-8.png

Solubility in organics

2-Bromo-9-fluorenone was 0.0526 (mole fraction) in 1,4-dioxane at 323.15 K and 0.0002 (mole fraction) in methanol at 278.15 K, respectively, and the solubility increased with the increase in temperature in all solvents.

References

[1] Peng Y, et al. Determination and Analysis of Solubility of 2-Bromo-9-fluorenone in 10 Different Organic Solvents and Three Binary Solvent Mixtures at Different Temperatures (T = 278.15–323.15 K). Journal of Chemical & Engineering Data, 2022; 67: 2662–2674.

2-Bromo-9-fluorenone synthesis

486-25-9
3096-56-8
Synthesis of 2-Bromo-9-fluorenone from 9-Fluorenone

2-Bromo-9-fluorenone Preparation Products And Raw materials

Raw materials

Preparation Products

2-Bromo-9,9-diphenylfluorene 2-HYDROXY-9-FLUORENONE 2-bromo-spiro[fluorene-7,9'-benzofluorene] 2-Bromo-9,9'-spirobi[9H-fluorene] 4-[2-bromo-9-[4-(1,1-dimethylethyl)phenyl]-9H-fluoren-9-yl]-Phenol

2-Bromo-9-fluorenone Suppliers

Global( 401)Suppliers
Supplier Tel Email Country ProdList Advantage
Jiangsu Nata Opto-electronic Material Co.,Ltd. 		+86-0512-62520998 +86-15030927757 gaoym@natachem.com China 229 58
Zhengzhou HQ Material CO.,LTD.
+86-371-55919009 +8615225108189 sale1@hqmat.com China 633 58
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12457 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 7613 58
Springchem New Material Technology Co.,Limited 		+86-021-62885108 +8613917661608 info@spring-chem.com China 2068 57
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
Shanghai Time Chemicals CO., Ltd. 		+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32480 60
AB PharmaTech,LLC 		323-480-4688 United States 989 55
Supplier Advantage
Jiangsu Nata Opto-electronic Material Co.,Ltd. 		58
Zhengzhou HQ Material CO.,LTD.
58
Hebei Mojin Biotechnology Co., Ltd 		58
Henan Fengda Chemical Co., Ltd 		58
Springchem New Material Technology Co.,Limited 		57
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Shanghai Time Chemicals CO., Ltd. 		55
ATK CHEMICAL COMPANY LIMITED 		60
AB PharmaTech,LLC 		55

View Lastest Price from 2-Bromo-9-fluorenone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromo-9-fluorenone pictures 2024-03-28 2-Bromo-9-fluorenone
3096-56-8
 US $0.00 / kg 25kg 98%-99% Inquiry PNP Biotech Co. Ltd
2-Bromo-9-fluorenone pictures 2023-12-24 2-Bromo-9-fluorenone
3096-56-8
 US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
2-Bromo-9-fluorenone pictures 2023-10-16 2-Bromo-9-fluorenone
3096-56-8
 US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd

2-Bromo-9-fluorenone Spectrum

2-Bromo-9-fluorenone(3096-56-8)1HNMR2-Bromo-9-fluorenone(3096-56-8)Raman

3096-56-8(2-Bromo-9-fluorenone)Related Search:

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2-BROMOCARBAZOLE 2-Bromofluorene 2,7-Dibromo-9H-fluoren-9-one Bromine 2-AMINO-7-BROMO-9-FLUORENONE,7-AMINO-2-BROMO-9-FLUORENONE
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2,7-DIBROMO-4-CARBOXYL-9-FLUORENONE METHYL-2,7-DIBROMO-9-FLUORENONE-4-CARBOXYLATE METHYL-2-BROMO-9-FLUORENONE-5-CARBOXYLATE

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2-Bromo-9-fluorenone,95% 2-Bromofluorenone or 2-Bromo-9-fluorenone 9H-Fluoren-9-one,2-broMo- 2-Bromo –fluororenone 2-Bromofluorenone 2-broMo-9H-fluoren-9-one (2-BFone) 2-BroMo-9H-fluorenone 2-BROMO-9-FLUORENONE 2-Bromo-9-Fluorenone98% 2-Bromo-9-Fluorenone 98% 2-Bromo-9-fluorenone > 2-Bromo-9-fL 2-Bromo-9-fluorenone ISO 9001：2015 REACH 2-Bromo-9H-fluoren-9-one 2-BROMOFLUOREN-9-ONE 3096-56-8 C13H7BrO Ketones Organic Building Blocks Carbonyl Compounds C13 to C14 Building Blocks Fluorene Series organic chemicals and derivatives/others OLED OLED materials,pharm chemical,electronic Fluorenes, Flurenones Electronic Chemicals Fluorenes & Fluorenones Fluorenones Fluorene Derivatives C13 to C14 Carbonyl Compounds Ketones