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ChemicalBook >> CAS DataBase List >>(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Structure
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester structure
CAS No.
13811-71-7
Chemical Name:
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
Synonyms
DET;D-DET;D-tartrate;DIETHYL D-TARTRATE;(-)-Diethyl D-tartrate;D(-)diethyl tartarate;(2R,3R)-diethyl 2,3-dihydroxysuccinate;ETHYL TARTRATE;diethyl (2S,3S)-2,3-dihydroxybutanedioate;(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl
CBNumber:
CB7105982
Molecular Formula:
C8H14O6
Molecular Weight:
206.19
MDL Number:
MFCD00064451
MOL File:
13811-71-7.mol
MSDS File:
SDS
Last updated:2024-04-08 13:48:25
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(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Properties

Melting point 17 °C
Boiling point 162 °C/19 mmHg (lit.)
alpha -9 º (neat)
Density 1.205 g/mL at 20 °C (lit.)
refractive index n20/D 1.446(lit.)
Flash point 200 °F
storage temp. Store below +30°C.
solubility Chloroform (Slightly), Water (Slightly)
pka 11.61±0.20(Predicted)
form Viscous Liquid
color Clear colorless
Specific Gravity 1.21
optical activity [α]23/D 8.5°, neat
Water Solubility insoluble
Merck 14,3855
BRN 1727143
CAS DataBase Reference 13811-71-7(CAS DataBase Reference)
NIST Chemistry Reference Butanedioic acid, 2,3-dihydroxy-, diethyl ester, [S-(R*,R*)]-(13811-71-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H227
Precautionary statements  P210e-P280a-P370+P378a-P403+P235-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  24/25-36-26
WGK Germany  3
Hazard Note  Irritant
HS Code  29181300
NFPA 704
1
0 0

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 213969 (?)-Diethyl D-tartrate ≥99% 13811-71-7 5g $52.7 2024-03-01 Buy
Sigma-Aldrich 8.18685 (2S,3S)-(-)-Diethyl tartrate for synthesis 13811-71-7 25mL $87 2024-03-01 Buy
Sigma-Aldrich 213969 (?)-Diethyl D-tartrate ≥99% 13811-71-7 25g $90.7 2024-03-01 Buy
TCI Chemical T1195 Diethyl D-(-)-Tartrate >97.0%(GC) 13811-71-7 25g $16 2024-03-01 Buy
TCI Chemical T1195 Diethyl D-(-)-Tartrate >97.0%(GC) 13811-71-7 250g $115 2024-03-01 Buy
Product number Packaging Price Buy
213969 5g $52.7 Buy
8.18685 25mL $87 Buy
213969 25g $90.7 Buy
T1195 25g $16 Buy
T1195 250g $115 Buy

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Chemical Properties,Uses,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Diethyl D(-)-tartrate is mainly used in chiral pharmaceuticals, chiral intermediates and chiral catalysts. It can be used with titanium in enolic asymmetric epoxidization. The compound d-alpha-tocopherol is the principal compound present in natural vitamin E sources. At present, d-alpha-tocopherol and other tocopherol derivatives are used in pharmaceuticals, foods and animal feeds. It is used as a food additive.

Purification Methods

Distil the esters under high vacuum and store them under vacuum or in an inert atmosphere in a desiccator in round bottomed flasks equiped with a vacuum stopcock. They have also been distilled by Kügelrohr distillation and/or by 'wiped-film' molecular distillation. They are slightly soluble in H2O but miscible with EtOH and Et2O. [Gao et al. J Am Chem Soc 109 5770 (5771) 1987, IR: Pristera Anal Chem 25 844 1953, Beilstein 3 III 1025 for D-(-), 3 IV 1232 for L(+).]

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Preparation Products And Raw materials

Raw materials

DL-Tartaric acid

Preparation Products

(-)-DIOP (R)-(-)-2,2-Dimethyl-1,3-dioxolane-4-methanol

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Suppliers

Global( 565)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12456 58
Hebei Yanxi Chemical Co., Ltd. 		+8617531190177 peter@yan-xi.com China 5993 58
Zibo Hangyu Biotechnology Development Co., Ltd 		+86-0533-2185556 +8617865335152 Mandy@hangyubiotech.com China 11013 58
airuikechemical co., ltd. 		+undefined86-15315557071 sales02@airuikechemical.com China 994 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3012 60
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Accela ChemBio Inc. 		(+1)-858-699-3322 info@accelachem.com United States 19965 58
Supplier Advantage
Hebei Mojin Biotechnology Co., Ltd 		58
Hebei Yanxi Chemical Co., Ltd. 		58
Zibo Hangyu Biotechnology Development Co., Ltd 		58
airuikechemical co., ltd. 		58
Capot Chemical Co.,Ltd. 		60
Henan Tianfu Chemical Co.,Ltd. 		55
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
career henan chemical co 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Accela ChemBio Inc. 		58

View Lastest Price from (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(2s,3s)(-)-dihydroxybutane-1,4-dioic acid diethyl ester pictures 2024-04-08 (2s,3s)(-)-dihydroxybutane-1,4-dioic acid diethyl ester
13811-71-7
 US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester pictures 2024-01-02 (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
13811-71-7
 US $80.00-800.00 / kg 10kg 0.99 20tons Zibo Hangyu Biotechnology Development Co., Ltd
Diisopropyl D-tartrate pictures 2023-09-28 Diisopropyl D-tartrate
13811-71-7
 US $40.00-40.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Spectrum

(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester(13811-71-7)IR(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester(13811-71-7)Raman(2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester(13811-71-7)FT-IR

13811-71-7((2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester)Related Search:

2,3-Di-O-para-toluoyl-D-tartaric acid (-)-Dibenzoyl-L-tartaric acid monohydrate (+)-Dimethyl L-tartrate (-)-DIBUTYL-D-TARTRATE (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester
Bis(diethyl-D-tartrate glycolato)diboron Diethyl succinate Bis(diethyl-L-tartrate glycolato)diboron (2R,3R)(+)-DIHYDROXYBUTANE-1,4-DIOIC ACID DIETHYL ESTER Bis(diisopropyl-L-tartrate glycolato)diboron
Bis(diisopropyl-D-tartrate glycolato)diboron Diisopropyl D-tartrate (-)-DIBENZYL D-TARTRATE (-)-DI-TERT-BUTYL D-TARTRATE 3-PYRIDYLMETHYL D-TARTRATE
(2S,3S)-(+)-DIETHYL 2,3-O-BENZYLIDENETARTRATE

1of4

(-)-Diethyl D-tartrate, Made froM unnatural tartaric acid, 99% 25ML (R,R)-(+)-Weinsaeure-diethylester (-)-Diethyl (2S,3S)-2,3-dihydroxybutane-1,4-dioate, (-)-Diethyl (2S,3S)-2,3-dihydroxysuccinate D-(-)-TARTARIC ACID DIETHYL ESTER (2S,3S)-(-)-DIETHYL TARTRATE (2S,3S)(-)-DIHYDROXYBUTANE-1,4-DIOIC ACID DIETHYL ESTER diethyl [S-(R*,R*)]-tartrate MINUS-TARTARIC ACID DIETHYL ESTER DIETHYL D-TARTRATE, 99+% D (-)Diethy tartrate (-)-Diethyl D-tartrate, made from unnatural tartaric acid, 99% Butanedioic acid, 2,3-dihydroxy-, diethyl ester, S-(R*,R*)- Diethyl-L-(+)-Tartarte D-(-)-WEINSURE-DIETHYLESTER (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester Diethyl D- tartrate D-Tartaric acid diethyl ester D-ethyl tartrate Diethyl-D(-)-Tartrate99.0%Min (-)-Diethyl d-tartrate, 99%, made from unnatural tartaric acid (2S,3S)-2,3-Dihydroxysuccinic acid diethyl ester Diethyl dextro-tartrate (2S,3S)(-)-Dihydroxy EsoMeprazo interMediate C D- two ethyl acetate Dihydroxybutane-1,4-dioic acid diethyl ester D-Tartaric Acid Diethyl Ester,99%e.e. (2S,3S)-(-)-Diethyl tartrate for synthesis dlethyl-tartrate (-)-DIETHYL-2,3-DIHYDROXYSUCCINATE (-)-DIETHYL-D-TARTRATE DIETHYL D-(-)-TARTRATE [-]-TARTARIC ACID DIETHYL ESTER D(-)-DIETHYL TARTRATE D-(-)-Diethyl L-tartrate (-)-Diethyl D-tartrate >=99% Diethyl Tartrate D(-) (-)-Diethyl (2S,3S)-2,3-dihydroxybutane-1,4-dioate, (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester 13811-71-7 3S)(-)-Dihydroxybutane-1 4-dioic acid diethyl ester diethyl laevo-tartrate DI-ETHYL-D-TARTRATE (Pure) 13811-71-7 Diethyl-D-Tartarate (13811-71-7) (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl ester in stock Factory Butanedioic acid, 2,3-dihydroxy-, 1,4-diethyl ester, (2S,3S)- D-tartrate (2R,3R)-diethyl 2,3-dihydroxysuccinate (-)-Diethyl D-tartrate (2S,3S)(-)-Dihydroxybutane-1,4-dioic acid diethyl D(-)diethyl tartarate ETHYL TARTRATE DIETHYL D-TARTRATE DET D-DET diethyl (2S,3S)-2,3-dihydroxybutanedioate (-)-Diethyl tartrate D-(-)-Tartaric Acid Diethyl Ester Diethyl-D-tartrate ( - ) Di Ethyl D Tartrate