Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>1,2-Bis(diphenylphosphino)ethane

1,2-Bis(diphenylphosphino)ethane

1,2-Bis(diphenylphosphino)ethane Structure
1,2-Bis(diphenylphosphino)ethane structure
CAS No.
1663-45-2
Chemical Name:
1,2-Bis(diphenylphosphino)ethane
Synonyms
DIPHOS;BIS(DIPHENYLPHOSPHINO)ETHANE;1,2-Bis(diphenylphos;1,2-Bis(diphenylphosphono)ethane;1,2-BIS(DIPHENYLPHOSPHINE)ETHANE;98% DPPE;DIPHOS OR DPPE;1,2-()(DPPE) 98%;bis(diphenylphosphine)ethane;1,2-Bis(diphenylphosphino)etha
CBNumber:
CB7138139
Molecular Formula:
C26H24P2
Molecular Weight:
398.42
MDL Number:
MFCD00003047
MOL File:
1663-45-2.mol
MSDS File:
SDS
Last updated:2024-04-03 12:01:51
Request For Quotation

1,2-Bis(diphenylphosphino)ethane Properties

Melting point 137-142 °C (lit.)
Boiling point 514.8±33.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
solubility Soluble in acetone, methanol and alcoholic hydrochloric acid.
form Crystalline Powder or Crystals
color White to off-white
Sensitive Air Sensitive
BRN 761261
Stability Stable. Combustible. Incompatible with strong oxidizing agents. May be air-sensitive.
InChI InChI=1S/C26H24P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20H,21-22H2
InChIKey QFMZQPDHXULLKC-UHFFFAOYSA-N
SMILES C1C=CC=CC=1P(CCP(C1=CC=CC=C1)C1=CC=CC=C1)C1=CC=CC=C1
CAS DataBase Reference 1663-45-2(CAS DataBase Reference)
FDA UNII KL33QE52I4
NIST Chemistry Reference Phosphine, 1,2-ethanediylbis[diphenyl-(1663-45-2)
EPA Substance Registry System Phosphine, 1,2-ethanediylbis[diphenyl- (1663-45-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H335
Precautionary statements  P261-P271-P304+P340+P312-P403+P233-P405-P501
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25-37/39-26-36
WGK Germany  3
F  9
TSCA  Yes
HS Code  29310095
NFPA 704
1
2 0

1,2-Bis(diphenylphosphino)ethane price More Price(48)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 106496 Ethylenebis(diphenylphosphine) 97% 1663-45-2 10g $67.2 2024-03-01 Buy
Sigma-Aldrich 106496 Ethylenebis(diphenylphosphine) 97% 1663-45-2 50g $314 2024-03-01 Buy
TCI Chemical B1137 1,2-Bis(diphenylphosphino)ethane >97.0%(GC)(T) 1663-45-2 10g $40 2024-03-01 Buy
TCI Chemical B1137 1,2-Bis(diphenylphosphino)ethane >97.0%(GC)(T) 1663-45-2 25g $78 2024-03-01 Buy
Alfa Aesar A11419 1,2-Bis(diphenylphosphino)ethane, 97+% 1663-45-2 5g $48.7 2024-03-01 Buy
Product number Packaging Price Buy
106496 10g $67.2 Buy
106496 50g $314 Buy
B1137 10g $40 Buy
B1137 25g $78 Buy
A11419 5g $48.7 Buy

1,2-Bis(diphenylphosphino)ethane Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

suzuki reaction

Uses

1,2-Bis(diphenylphosphino)ethane is a bidendate ligand used in coordination chemistry to prepare metal complexes. It is involved in the metal-catalyzed allylic alkylation and decarboxylation of allylic esters. It is also used in 1,3-diene synthesis. Further, it is used in cycloaddition reactions and carbonylation reactions. In addition to this, it is used to prepare bis(dicyclohexylphosphino)ethane by hydrogenation.

Definition

ChEBI: 1,2-bis(diphenylphosphino)ethane is a tertiary phosphine and a member of diphosphanes. It has a role as an allergen.

Purification Methods

Recrystallise it from aqueous EtOH or *C6H6. The dimethiodide, when recrystallised from MeOH has m 305-307o, and the dioxide when recrystallised from toluene or DMF (needles), or *C6H6 (plates) has m 252-254o (276-278o) [Isslieb et al. Chem Ber 92 3175 1959, NMR: Aquiar et al. J Org Chem 29 1660 1964, B.ckvall et al. J Org Chem 52 5430 1987]. [Beilstein 16 IV 958.]

1,2-Bis(diphenylphosphino)ethane Preparation Products And Raw materials

Raw materials

Diphenylphosphine Ethanol Acetone Sodium 1,2-Dibromoethane
Tetrahydrofuran Ethyl acetate 1,2-Dichloroethane Hydrochloric acid Dichloromethane
Sodium hydroxide Triphenylphosphine Magnesium sulfate PETROLEUM ETHER Lithium
n-Butyllithium

1of4

Preparation Products

Bis(diphenylphosphino)methane (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl 1.1'-Binaphthyl-2.2'-diphemyl phosphine TETRACHLOROCATECHOL Dichloro(DPPE)digold(I) ,96%

1,2-Bis(diphenylphosphino)ethane Suppliers

Global( 473)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12456 58
Hebei Yanxi Chemical Co., Ltd. 		+8617531190177 peter@yan-xi.com China 5993 58
Shanghai UCHEM Inc. 		+862156762820 +86-13564624040 sales@myuchem.com China 6710 58
Henan Fengda Chemical Co., Ltd 		+86-371-86557731 +86-13613820652 info@fdachem.com China 7845 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32480 60
AB PharmaTech,LLC 		323-480-4688 United States 989 55
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Supplier Advantage
Hebei Mojin Biotechnology Co., Ltd 		58
Hebei Yanxi Chemical Co., Ltd. 		58
Shanghai UCHEM Inc. 		58
Henan Fengda Chemical Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
ATK CHEMICAL COMPANY LIMITED 		60
AB PharmaTech,LLC 		55
career henan chemical co 		58

View Lastest Price from 1,2-Bis(diphenylphosphino)ethane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,2-Bis(diphenylphosphino)ethane pictures 2024-04-05 1,2-Bis(diphenylphosphino)ethane
1663-45-2
 US $8.00-3.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
1,2-Bis(diphenylphosphino)ethane nickel(II) chloride pictures 2024-02-23 1,2-Bis(diphenylphosphino)ethane nickel(II) chloride
1663-45-2
 US $12.00-208.00 / g 25g 0.98 100kg Shanghai UCHEM Inc.
1,2-Bis(diphenylphosphino)ethane pictures 2023-10-19 1,2-Bis(diphenylphosphino)ethane
1663-45-2
 US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd

1,2-Bis(diphenylphosphino)ethane Spectrum

1,2-Bis(diphenylphosphino)ethane(1663-45-2)MS1,2-Bis(diphenylphosphino)ethane(1663-45-2)1HNMR1,2-Bis(diphenylphosphino)ethane(1663-45-2)IR11,2-Bis(diphenylphosphino)ethane(1663-45-2)IR21,2-Bis(diphenylphosphino)ethane(1663-45-2)Raman1,2-Bis(diphenylphosphino)ethane(1663-45-2)ESR

1663-45-2(1,2-Bis(diphenylphosphino)ethane)Related Search:

Hexafluoroethane ETHANE 3,4'-DIAMINODIPHENYLMETHANE 1,5-Diphenylcarbazide N-(Carboxymethyl)-N-(phosphonomethyl)-glycine
4,4'-DDT Chlorodiphenylphosphine 1,1'-Bis(diphenylphosphino)ferrocene 1,3-Bis(diphenylphosphino)propane Bis(diphenylphosphino)methane
[1,2-Bis(diphenyphosphino)ethane]dichlorocobalt(II) 1,2,3,4-DIEPOXYBUTANE [1,2-Bis(diphenyphosphino)ethane]dichloroiron(II) R-(+)-1,2-BIS(DIPHENYLPHOSPHINO)PROPANE (2R,3R)-(+)-BIS(DIPHENYLPHOSPHINO)BUTANE
(2S,3S)-(-)-BIS(DIPHENYLPHOSPHINO)BUTANE ETHYLENEBIS(TRIPHENYLPHOSPHONIUM BROMIDE) (2R,3R)-(-)-2,3-BIS(DIPHENYLPHOSPHINO)BICYCLO[2.2.1]HEPT-5-ENE

1of4

1,2-()(DPPE) 98% DIPHOS OR DPPE 1,2-Bis(diphenylphosphino)ethane, Diphos 2-Di(phenyl)phosphanylethyl-di(phenyl)phosphane 1,2-Bis(diphenylphosphino) ethane,99% Dipltos 1,2-Bis(diphenylphosphino)ethane, 98+% 10GR 1,2-Bis(diphenylphosphino)ethane, 98+% 50GR 98% DPPE Ethylenebis(diphenylphosphine) DPPE 1,2-Bis(diphenylphosphiNA)ethane 1,2-Bis(diphenylphosphino)etha 1,2- double(twophenylphosphine)ethane 1,2-Bis(diphenylphosphino)ethane,98% DPPE 1,2-Bis(diphenylphosphino)ethane Bis(1,2-diphenylphosphino)ethane 1,2-Bis(diphenylphosphino)ethane,96% 1,2-Bis(diphenylphosphino)-ethane for synthesis [2-(Diphenylphosphino)ethyl](diphenyl)phosphine 1,2-Ethanediylbis(diphenylphosphine) 1,2-ethanediylbis[diphenyl-phosphin bis(diphenylphosphine)ethane P,P'-Ethylenebis(diphenylphosphine) Phosphine, 1,2-ethanediylbis*diphenyl- Phosphine, ethylenebis*diphenyl- Phosphine, ethylenebis[diphenyl- 1,2-BIS(DIPHENYLPHOSPHINO)ETHANE ETHYLENEBIS(DIPHENYLPHOSPHINE) BIS(1,2-DIPHENYLPHOSPHINO)ETHANE 1,2-Bis(Diphenylphosphor) Ethane 1,2-Bis(diphenylphosphino)ethane(dppe) 1,2-Bis(diphenylphosphino)ethane, 98+% 1,2-bis(diphenyphosphino)ethane 1,2-Bis(diphenylphosphino)ethane,99%DIPHOS DPPE/ 1,2-BIS(DIPHENY PHOSPHINE)ETHANE DPPE/1,2-BIS- (DIPHENYLPHOSPHINO)ETHANE 1,2-Bis(dipheny phosphine)ethane 1,2-Bis(diphenylphosphino)ethane, 97+% 1,2-Bis(diphenylphosphino)ethane > 1,2-Bis(diphenylphosphino)ethane, 98%, for synthesis Phosphine, 1,1'-(1,2-ethanediyl)bis[1,1-diphenyl- TIANFUCHEM--1663-45-2--2-Aminobenzaldehyde factory price 1,2- bis(diphenylphosphaneyl)ethane (DPPE) DPPE (1,2-Bis(Diphenylphosphino)Ethane) extrapure, 98% 1,2-Bis(diphenylphos 1,2-Bis(diphenylphosphono)ethane 1,2-BIS(DIPHENYLPHOSPHINE)ETHANE DIPHOS BIS(DIPHENYLPHOSPHINO)ETHANE 1,2-Bis(diphenylphosphanyl)ethane 1663-45-2 C6H52PCH2CH2PC6H52 C26H24P2 Catalysis and Inorganic Chemistry Polydentate Phosphine Ligands Phosphorus Compounds Phosphine Ligands Ligand Phosphines Phosphine Ligands