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Aniline

CAS No.62-53-3
Chemical Name:Aniline
Synonyms:Anilin;Anyvim;Kyanol;Anilina;blueoil;ci76000;ANILINE;Benzidam;Blue Oil;ai3-03053
CBNumber:CB7169544
Molecular Formula:C6H7N
Formula Weight:93.13
MOL File:62-53-3.mol
Aniline Property
Melting point : -6.2 °C
Boiling point : 184 °C(lit.)
density : 1.022 g/mL at 25 °C(lit.)
vapor density : 3.22 (185 °C, vs air)
vapor pressure : 0.7 mm Hg ( 25 °C)
refractive index : n20/D 1.586(lit.)
Fp : 76 °C
storage temp. : 2-8°C
Water Solubility : 36 g/L (20 ºC)
Merck : 14,659
BRN : 605631
Stability:: Stable. Incompatible with oxidizing agents, bases, acids, iron and iron salts, zinc, aluminium. Light sensitive. Combustible.
CAS DataBase Reference: 62-53-3(CAS DataBase Reference)
NIST Chemistry Reference: Aniline(62-53-3)
EPA Substance Registry System: Benzenamine(62-53-3)
Safety
Hazard Codes : T,N,F
Risk Statements : 23/24/25-40-41-43-48/23/24/25-50-68-48/20/21/22-39/23/24/25-11
Safety Statements : 26-27-36/37/39-45-46-61-63-36/37-16
RIDADR : UN 1547 6.1/PG 2
WGK Germany : 2
RTECS : BW6650000
F : 8-9
TSCA : Yes
HazardClass : 6.1
PackingGroup : II
Hazardous Substances Data: 62-53-3(Hazardous Substances Data)

Aniline Chemical Properties,Usage,Production

Chemical Properties
colourless liquid
General Description
A yellowish to brownish oily liquid with a musty fishy odor. Melting point -6°C; boiling point 184°C; flash point 158°F. Denser than water (8.5 lb / gal) and slightly soluble in water. Vapors heavier than air. Toxic by skin absorption and inhalation. Produces toxic oxides of nitrogen during combustion. Used to manufacture other chemicals, especially dyes, photographic chemicals, agricultural chemicals and others.
Air & Water Reactions
Darkens on exposure to air and light. Polymerizes slowly to a resinous mass on exposure to air and light. Slightly soluble in water.
Reactivity Profile
Aniline is a heat sensitive base. Combines with acids to form salts. Dissolves alkali metals or alkaline earth metals with evolution of hydrogen. Incompatible with albumin, solutions of iron, zinc and aluminum, and acids. Couples readily with phenols and aromatic amines. Easily acylated and alkylated. Corrosive to copper and copper alloys. Can react vigorously with oxidizing materials (including perchloric acid, fuming nitric acid, sodium peroxide and ozone). Reacts violently with BCl3. Mixtures with toluene diisocyanate may ignite. Undergoes explosive reactions with benzenediazonium-2-carboxylate, dibenzoyl peroxide, fluorine nitrate, nitrosyl perchlorate, peroxodisulfuric acid and tetranitromethane. Violent reactions may occur with peroxyformic acid, diisopropyl peroxydicarbonate, fluorine, trichloronitromethane (293° F), acetic anhydride, chlorosulfonic acid, hexachloromelamine, (HNO3 + N2O4 + H2SO4), (nitrobenzene + glycerin), oleum, (HCHO + HClO4), perchromates, K2O2, beta-propiolactone, AgClO4, Na2O2, H2SO4, trichloromelamine, acids, FO3Cl, diisopropyl peroxy-dicarbonate, n-haloimides and trichloronitromethane. Ignites on contact with sodium peroxide + water. Forms heat or shock sensitive explosive mixtures with anilinium chloride (detonates at 464° F/7.6 bar), nitromethane, hydrogen peroxide, 1-chloro-2,3-epoxypropane and peroxomonosulfuric acid. Reacts with perchloryl fluoride form explosive products. .
Health Hazard
Aniline is classified as very toxic. Probable oral lethal dose in humans is 50-500 mg/kg for a 150 lb. person. Aniline poisoning is characterized by methemoglobin formation in the blood and resulting cyanosis or blue skin. The formation of methemoglobin interferes with the oxygen-carrying capacity of the blood. The approximate minimum lethal dose for a 150 lb. human is 10 grams. Serious poisoning may result from ingestion of 0.25 mL. People at special risk include individuals with glucose-6-phosphate-dehydrogenase deficiency and those with liver and kidney disorders, blood diseases, or a history of alcoholism.
Fire Hazard
Combustion can produce toxic fumes including nitrogen oxides and carbon monoxide. Aniline vapor forms explosive mixtures with air. Aniline is incompatible with strong oxidizers and strong acids and a number of other materials. Avoid heating. Hazardous polymerization may occur. Polymerizes to a resinous mass.
Aniline Preparation Products And Raw materials
Raw materials
Nitrogen Iron oxide Benzene Hydrogen Nitric acid Nitrobenzene
Preparation Products
N-PHENYLISONICOTINAMIDE Modified MDI 2-Anilinoethanol Butyl 2-[[3-[[(2,3-dihydro-2-oxo-1H-benzimidazol-5-yl)amino]carbonyl]-2-hydroxy-1-naphthyl]azo]benzoate Acid Black 234 Direct Dark Brown NM Direct Bordeaux NGB Aniline hydrochloride N,N'-Diphenylurea 2,4,6-Trichloroaniline Pigment Red 175 Poly(1,2-dihydro-2,2,4-trimethylquinoline) UREA, N-(2,6-DIMETHYLPHENYL)-N'-[IMINO(METHYLAMINO)METHYL]- N-Phenyl-1-naphthylamine REACTIVE VIOLET 5 2-CHLOROMALONALDEHYDE 3-Hydroxydiphenylamine Acid Black 26 4-N-DECYLANILINE N,N-Bis(cyanoethyl)aniline Direct Orange S LANASOLBLUE3R SOLVENT BLACK 5 3-BROMOPYRIDINE-2-CARBOXYLIC ACID DCHA Acid Yellow 79 Disperse Scarlet S-3GFL 4-HYDROXY-2-(TRIFLUOROMETHYL)QUINOLINE N,N-Diphenyl-p-phenylenediamine Reactive Blue 222 Direct Green 89 N-(2-Naphthyl)aniline 4-bromo-2-(trifluoromethyl)quinoline 8-Anilino-1-naphthalenesulfonic acid Phenylhydrazine sulfate FLUORESCENT BRIGHTENER 28 2 BASIC ORANGE 2 Bronze Red sodium dibenzyl amine enzene sulfonate Sudan I
Aniline Suppliers      Global( 227)Suppliers     
Supplier Tel Fax Email Country ProdList Advantage
Shanghai Macklin Biochemical Co.,Ltd. 15221275939
021-51821727shenlinxing@macklin.cn China 13254 55
Shanghai Aladdin Bio-Chem Technology Co.,LTD 021-20337333/400-620-6333
021-50323701sale@aladdin-e.com China 28587 65
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933jkinfo@jkchemical.com;market6@jkchemical.com China 96832 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing)sh@meryer.com China 40403 62
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05saleschina@alfa-asia.com China 30315 84
TCI (Shanghai) Development Co., Ltd. 800-988-0390
021-67121385sales@tcishanghai.com.cn China 22833 81
Beijing dtftchem Technology Co., Ltd. 13651141086; 86(10)60275028、60275820
86 (10) 60270825dtftchem@sina.com China 1443 62
Energy Chemical 021-58432009 / 400-005-6266
021-58436166-800info@energy-chemical.com China 44198 61
Beijing Ouhe Technology Co., Ltd +86-10-4006331231;+86-10-51280831;+86-10-82967028
+86-10-82967029sales@ouhechem.com China 10813 60
JinYan Chemicals(ShangHai) Co.,Ltd. 13817811078,021-50426030
86-021-50426522,50426273sales@jingyan-chemical.com China 10094 60
 
62-53-3(Aniline)Related Search:
Benzidine Diphenylamine 2-(3-METHOXYPROPOXY)-5-(TRIFLUOROMETHYL)ANILINE n,n-dimethyl-p-(3’-methylphenylazo)-anili 2-Anisidine-4-sulfonic acid 2,4-DIFLUORO-N-(2,2,-DIMETHYLPROPANOYL)ANILIN m-Aminobenzene arsonic acid 2-(3-METHYLPHENOXY)-5-(TRIFLUOROMETHYL)ANILINE 3-Ethoxyaniline 2-(2-MORPHOLIN-4-YLETHOXY)ANILIN n-dichloromethylene-anili 3,5-Di(trifluoromethyl)aniline N,N-Bis(trifluoromethylsulfonyl)aniline N-(4-CHLORO-PHENYL)-OXALAMIC ACID ETHYL ESTER 4-Bromo-N,N-dimethylaniline N-METHYL-N-PHENYLCARBAMOYL CHLORIDE Diphenylcarbamyl chloride 2-Chloro-N-[4-chloro-2-(2-chlorobenzoyl)phenyl]acetamide
ai3-03053 amino-benzen Aminophen Anilin anilin(czech) Anilina anilina(italian,polish) Aniline reagent aniline(andhomologs) Aniline(benzenamine) aniline15 anilineandhomologues Anyvim arylamine benzamine Benzene, amino- benzene,amino Benzidam Blue Oil blueoil C.I. 76000 C.I. Oxidation base 1 c.i.76000 c.i.oxidationbase1 caswellno051c ci76000 cioxidationbase1 epapesticidechemicalcode251400 Huile D'aniline huiled’aniline huiled’aniline(french) Krystallin Kyanol ncic03736 NCI-C03736 Rcra waste number U012 rcrawastenumberu012 BENZENEAMINE BENZENAMINE ANILINE OIL ANILINE 62-53-3 AKOS BBS-00003680 AMINOBENZENE C2 to C6 AM to AQ Analytical Standards Building Blocks Amines Analytical Chromatography Product Catalog Alphabetic Organic Building Blocks Nitrogen Compounds PHENYLAMINE Aniline;Aminobenzene; Phenylamine L-Aniline ANILINE EXTRA PURE ANILINE, STANDARD FOR GC
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