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Allylboronic acid pinacol ester

CAS No.
72824-04-5
Chemical Name:
Allylboronic acid pinacol ester
Synonyms
2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane;AKOS BRN-1082;PINACOL ALLYLBORONATE;Allyl pinacol boronate;Pinacolyl 2-propenylboronate;Allylboronic acid pinacolate;Allylboronic acid picol ester;ALLYLBORONIC ACID PINACOL ESTER;Allylboronic acid piracol ester
CBNumber:
CB7169827
Molecular Formula:
C9H17BO2
Molecular Weight:
168.04
MDL Number:
MFCD00013347
MOL File:
72824-04-5.mol
MSDS File:
SDS
Last updated:2024-04-08 16:27:35

Allylboronic acid pinacol ester Properties

Boiling point 50-53 °C/5 mmHg (lit.)
Density 0.896 g/mL at 25 °C (lit.)
refractive index n20/D 1.4268(lit.)
Flash point 115 °F
storage temp. 2-8°C
solubility Chloroform, Methanol (Slightly)
form Liquid
color Clear colorless
Water Solubility Not miscible or difficult to mix in water.
BRN 4244068
CAS DataBase Reference 72824-04-5(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Warning
Hazard statements  H226
Precautionary statements  P210-P233-P240-P241-P242-P243
Hazard Codes  Xi
Risk Statements  10-36/37/38
Safety Statements  26-36
RIDADR  UN 1993 3/PG 3
WGK Germany  3
Hazard Note  Irritant
HazardClass  3
PackingGroup  III
HS Code  29310095
NFPA 704
2
2 1

Allylboronic acid pinacol ester price More Price(47)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 324647 Allylboronic acid pinacol ester 97% 72824-04-5 1g $50.1 2024-03-01 Buy
Sigma-Aldrich 324647 Allylboronic acid pinacol ester 97% 72824-04-5 10g $308 2024-03-01 Buy
TCI Chemical A2157 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) >96.0%(GC) 72824-04-5 1g $41 2024-03-01 Buy
TCI Chemical A2157 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) >96.0%(GC) 72824-04-5 5g $115 2024-03-01 Buy
Alfa Aesar L16232 Allylboronic acid pinacol ester, 98+% 72824-04-5 1g $37.65 2024-03-01 Buy
Product number Packaging Price Buy
324647 1g $50.1 Buy
324647 10g $308 Buy
A2157 1g $41 Buy
A2157 5g $115 Buy
L16232 1g $37.65 Buy

Allylboronic acid pinacol ester Chemical Properties,Uses,Production

Chemical Properties

Clear corless liquid

Uses

Allylboronic acid pinacol ester can act as reagent used for Palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis; Intermolecular radical additions; Allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids and Cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes ; Nucleic acid-templated energy transfer leading to a photorelease reaction .

Uses

Allylboronic acid pinacol ester reacts with carboxylic acids, in the presence of tri-n-butyltin hydride, to give homoallylic alcohols in good yield. Homoallylic alcohols can also be formed by allylboration of aldehydes. It is a reagent used for palladium-catalyzed Suzuki-Miyaura cross-coupling reactions and olefin metathesis, intermolecular radical additions, allylboration of aldehydes catalyzed by chiral spirobiindane diol (SPINOL) based phosphoric acids, cobalt-catalyzed regioselective hydrovinylation of dienes with alkenes, nucleic acid-templated energy transfer leading to a photorelease reaction and stereoselective indium-catalyzed Hosomi-Sakurai reactions.

Global( 229)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 7377 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15371 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Shanghai Arbor Chemical Co., Ltd.
021-60451682 act@arborchemical.com CHINA 906 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Changzhou Ditong Chemical Co.,Ltd
+86-0519-88299272 info@edengenechem.com China 2169 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
Wuhan Chemwish Technology Co., Ltd
027-67849912 sales@chemwish.com CHINA 10828 58

View Lastest Price from Allylboronic acid pinacol ester manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Allylboronic acid pinacol ester pictures 2024-04-08 Allylboronic acid pinacol ester
72824-04-5
US $34.00-1.20 / kg 1kg 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Allylboronic acid pinacol ester pictures 2021-07-13 Allylboronic acid pinacol ester
72824-04-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
Allylboronic acid pinacol ester pictures 2021-07-10 Allylboronic acid pinacol ester
72824-04-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Allylboronic acid pinacol ester 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Allylboronic acid pinacol ester 97% 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine) 4,4,5,5-tetramethyl-2-(2-propen-1-yl)-1,3,2-dioxaborolane 4,4,5,5-tetramethyl-2-(2-propenyl)-1,3,2-dioxaborolane Allyl pinacol boronate Pinacolyl 2-propenylboronate 2-(Prop-2-en-1-yl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane Allylboronic acid pinacol ester, 98% 1GR Allylboronic acid pinacol ester(stabilized with Phenothiazine) 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXAB 1,3,2-Dioxaborolane, 4,4,5,5-tetramethyl-2-(2-propen-1-yl)- (2-Propen-1-yl)-boronic acid pinacol ester Allyl pinacol boronate Pinacolyl 2-propenylboronate 3-Hydroxy-2,3-dimethylbutan-2-yl hydrogen allylboronate Allylboronic acid picol ester 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane for synthesis PINACOL ALLYLBORONATE ALLYLBORONIC ACID, PINACOL CYCLIC ESTER ALLYLBORONIC ACID PINACOL ESTER AKOS BRN-1082 ALLBORONIC ACID,PINACOL CYCLIC ESTER Allylboronic acid piracol ester Allylboronic acid pinacolate Allylboronic acid pinacol ester, 98+% 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane, Pinacol allylboronate 4,4,5,5-tetramethyl-2-(prop-2-en-1-yl)-1,3,2-dioxaborolane 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane (stabilized with Phenothiazine)> 4,4,5,5-Tetramethyl-2-prop-2-enyl-1,3,2-dioxaborolane 2-ALLYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE 72824-04-5 CH34C2O2BCH2CHCH2 Boronate Esters Boronic Acids and Derivatives Alkyl Organometallic Reagents Alkyl Boronate Esters Boronate Esters Boronic Acids and Derivatives Chemical Synthesis Organometallic Reagents Olefin Organoborons B (Classes of Boron Compounds) Boronic Acids Esters CHIRAL CHEMICALS