Methyl bromoacetate
- CAS No.
- 96-32-2
- Chemical Name:
- Methyl bromoacetate
- Synonyms
- METHYL 2-BROMOACETATE;BAM;BROMO METHYLACETATE;BROMOACETIC ACID METHYL ESTER;Methyl bomoacetate;METHYL BROMOACETATE;2-BROMOMETHYL ACETATE;BroMine Methyl acetate;methylmonobromoacetate;Methyl broMoacetate 97%
- CBNumber:
- CB7171783
- Molecular Formula:
- C3H5BrO2
- Molecular Weight:
- 152.97
- MDL Number:
- MFCD00000189
- MOL File:
- 96-32-2.mol
- MSDS File:
- SDS
| Melting point | -50°C |
|---|---|
| Boiling point | 51-52 °C/15 mmHg (lit.) |
| Density | 1.616 g/mL at 25 °C (lit.) |
| vapor pressure | 18 hPa (50 °C) |
| refractive index |
n |
| Flash point | 145 °F |
| storage temp. | Store below +30°C. |
| form | Liquid |
| Specific Gravity | 1.416 |
| color | Clear colorless to slightly yellow |
| Water Solubility | Miscible with methanol, ether and acetone. Slightly miscible with water |
| FreezingPoint | <-50℃ |
| BRN | 506256 |
| LogP | 0.71 at 25℃ |
| CAS DataBase Reference | 96-32-2(CAS DataBase Reference) |
| FDA UNII | LI6481MCM6 |
| NIST Chemistry Reference | Acetic acid, bromo-, methyl ester(96-32-2) |
| EPA Substance Registry System | Acetic acid, bromo-, methyl ester (96-32-2) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS05,GHS06 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301-H314-H317-H335 | |||||||||
| Precautionary statements | P261-P270-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | T,Xi,F | |||||||||
| Risk Statements | 25-34-37-23/24/25-40-36/37/38-38 | |||||||||
| Safety Statements | 26-36/37/39-45-28A-36-16 | |||||||||
| RIDADR | UN 2643 6.1/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | AF6300000 | |||||||||
| F | 19 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29159080 | |||||||||
| NFPA 704 |
|
Methyl bromoacetate price More Price(27)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 157910 | Methyl bromoacetate 97% | 96-32-2 | 25g | $32.3 | 2024-03-01 | Buy |
| Sigma-Aldrich | 157910 | Methyl bromoacetate 97% | 96-32-2 | 100g | $95.6 | 2024-03-01 | Buy |
| TCI Chemical | B0533 | Methyl Bromoacetate >98.0%(GC) | 96-32-2 | 25g | $28 | 2024-03-01 | Buy |
| TCI Chemical | B0533 | Methyl Bromoacetate >98.0%(GC) | 96-32-2 | 100g | $73 | 2024-03-01 | Buy |
| Alfa Aesar | A10605 | Methyl bromoacetate, 98+% | 96-32-2 | 50g | $41.65 | 2024-03-01 | Buy |
Methyl bromoacetate Chemical Properties,Uses,Production
Chemical Properties
Colorless liquid
Uses
Methyl bromoacetate is used in the synthesis of coumarins and cis-cyclopropanes. It reacts with the conjugate base of (methylmethoxycarbene)pentacarbonylchromium(0) to prepare alkylated carbene complexes. Further, it is used to make vitamins and pharmaceuticals.
Uses
Methyl bromoacetate was used in the synthesis of novel coumarins. It was also employed in the synthesis of cis-cyclopropanes
Application
Methyl Bromoacetate is an organic building block that has been used as a reactant in the preparation of isoquinolinone indole acetic acid derivatives as antagonists of chemoattractant receptor homologous molecule expressed on Th2 cells (CRTH2) for the treatment of allergic inflammatory diseases.
General Description
A colorless to straw-colored liquid with a sharp penetrating odor. Denser than water and soluble in water. Severly irritates skin and eyes. Toxic by ingestion and inhalation. Used to make vitamins and pharmaceuticals.
Air & Water Reactions
Highly flammable. Soluble in water.
Reactivity Profile
Methyl bromoacetate is a halogenated ester. Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides.
Hazard
Vapor is strong irritant to eyes.
Health Hazard
TOXIC; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. Bromoacetates and chloroacetates are extremely irritating/lachrymators. Reaction with water or moist air will release toxic, corrosive or flammable gases. Reaction with water may generate much heat that will increase the concentration of fumes in the air. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control or dilution water may be corrosive and/or toxic and cause pollution.
Fire Hazard
HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors form explosive mixtures with air: indoors, outdoors and sewers explosion hazards. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapors may travel to source of ignition and flash back. Substance will react with water (some violently) releasing flammable, toxic or corrosive gases and runoff. Contact with metals may evolve flammable hydrogen gas. Containers may explode when heated or if contaminated with water.
Safety Profile
Poison by intravenous route. When heated to decomposition it emits toxic fumes of Br-. See also ESTERS.
Methyl bromoacetate Preparation Products And Raw materials
Raw materials
Preparation Products
1of4
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shaanxi Didu New Materials Co. Ltd | +86-89586680 +86-13289823923 | 1026@dideu.com | China | 9116 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
| Firsky International Trade (Wuhan) Co., Ltd | +8615387054039 | admin@firsky-cn.com | China | 436 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| Yancheng Longshen Chemical Co.,Ltd. | +86-0515-88706880; +8618352073383 | sales@longshenchem.com | China | 79 | 55 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
View Lastest Price from Methyl bromoacetate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-10-16 | Methyl bromoacetate
96-32-2
|
US $20.00-1.00 / kg | 1kg | 0.99 | 10 tons | Hebei Yanxi Chemical Co., Ltd. | |
 |
2023-10-08 | Methyl bromoacetate
96-32-2
|
US $30.00 / KG | 1KG | 99% | 20T | Firsky International Trade (Wuhan) Co., Ltd | |
 |
2023-09-06 | Methyl bromoacetate
96-32-2
|
US $100.00 / drum | 1drum | 99 | 5000 | Hebei Fengqiang Trading Co., LTD |
-
- Methyl bromoacetate
96-32-2
- US $20.00-1.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.
-
- Methyl bromoacetate
96-32-2
- US $30.00 / KG
- 99%
- Firsky International Trade (Wuhan) Co., Ltd
-
- Methyl bromoacetate
96-32-2
- US $100.00 / drum
- 99
- Hebei Fengqiang Trading Co., LTD