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ChemicalBook >> CAS DataBase List >>2,3,4,6-Tetra-O-benzyl-D-glucopyranose

2,3,4,6-Tetra-O-benzyl-D-glucopyranose

2,3,4,6-Tetra-O-benzyl-D-glucopyranose Structure
2,3,4,6-Tetra-O-benzyl-D-glucopyranose structure
CAS No.
4132-28-9
Chemical Name:
2,3,4,6-Tetra-O-benzyl-D-glucopyranose
Synonyms
(3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)Methyl)tetrahydro-2H-pyran-2-ol;2,3,4, 6-4-o-benzyl-d-pyranoglucose;ucopyranose;2,3,4,6-Tetra-O-benz;Voglibose Impurity 4;Garlic oil 8000-78-0;benzyl-D-glucopyranose;Voglibose Intermediates;2,3,4,6-TETRABENZYL-D-GLUCOSE;Tetra-O-benzyl-D-glucopyranose
CBNumber:
CB7194124
Molecular Formula:
C34H36O6
Molecular Weight:
540.65
MDL Number:
MFCD00023849
MOL File:
4132-28-9.mol
Last updated:2023-11-17 16:15:53
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2,3,4,6-Tetra-O-benzyl-D-glucopyranose Properties

Melting point 145-149 °C(lit.)
Boiling point 672.4±55.0 °C(Predicted)
Density 1.22±0.1 g/cm3(Predicted)
storage temp. Sealed in dry,Store in freezer, under -20°C
solubility Soluble in chloroform
pka 11.87±0.70(Predicted)
form Solid
color White to Off-White
optical activity [α]20/D +49±2°, c = 2% in dioxane
InChIKey OGOMAWHSXRDAKZ-BKJHVTENSA-N
SMILES OC1O[C@H](COCC2=CC=CC=C2)[C@@H](OCC2=CC=CC=C2)[C@H](OCC2=CC=CC=C2)[C@H]1OCC1=CC=CC=C1
CAS DataBase Reference 4132-28-9(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280-P271
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-24/25
WGK Germany  3
HS Code  29400090
NFPA 704
1
0 0

2,3,4,6-Tetra-O-benzyl-D-glucopyranose price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 86730 2,3,4,6-Tetra-O-benzyl-D-glucopyranose ≥98.0% (TLC) 4132-28-9 1g $26 2024-03-01 Buy
Sigma-Aldrich 86730 2,3,4,6-Tetra-O-benzyl-D-glucopyranose ≥98.0% (TLC) 4132-28-9 5g $60.5 2024-03-01 Buy
TCI Chemical T1914 2,3,4,6-Tetra-O-benzyl-D-glucopyranose >97.0%(HPLC) 4132-28-9 1g $43 2024-03-01 Buy
TCI Chemical T1914 2,3,4,6-Tetra-O-benzyl-D-glucopyranose >97.0%(HPLC) 4132-28-9 5g $117 2024-03-01 Buy
Alfa Aesar H27888 2,3,4,6-Tetra-O-benzyl-D-glucopyranose, 98+% 4132-28-9 1g $45.65 2024-03-01 Buy
Product number Packaging Price Buy
86730 1g $26 Buy
86730 5g $60.5 Buy
T1914 1g $43 Buy
T1914 5g $117 Buy
H27888 1g $45.65 Buy

2,3,4,6-Tetra-O-benzyl-D-glucopyranose Chemical Properties,Uses,Production

Description

2,3,4,6-Tetra-O-benzyl-D-glucopyranose is an important D-glucopyranose derivative, which is often used as a pharmaceutical intermediate in the synthesis of derivatives for the treatment of Alzheimer's disease, diabetes, and cancer.

Chemical Properties

White Crystaline Solid

Uses

2,3,4,6-Tetra-O-benzyl-D-glucopyranose (cas# 4132-28-9) is a compound useful in organic synthesis. For example, it enables the preparation of α-glucopyranosyl chloride as well as 1-C-α-D-glucopyranosyl derivatives; it can also be used in the preparation of important D-glucopyranosyl derivatives for glucosylation and other reactions.

Synthesis

Add 19.4g of 2,3,4,6-tetra-O-benzyl-β-D-glucosinolate to 500mL of acetone, and add 18.7g of N-bromosuccinyl in batches with stirring Imine (NBS), after the addition, react at 25°C for 0.5h. Most of the acetone was evaporated under reduced pressure, and a white solid was precipitated, which was diluted by adding 200 mL of 1mol/L hydrochloric acid and allowed to stand at -18°C for 3h. After suction filtration, the filter cake was washed with cold absolute ethanol, and recrystallized with absolute ethanol-cyclohexane to obtain 15.6 g of white flocculent solid 2,3,4,6-Tetra-O-benzyl-D-glucopyranose with a yield of 96.6%.

2,3,4,6-Tetra-O-benzyl-D-glucopyranose Preparation Products And Raw materials

Raw materials

Preparation Products

2,3,4,6-Tetra-O-benzyl-D-glucopyranose Suppliers

Global( 442)Suppliers
Supplier Tel Email Country ProdList Advantage
Beijing Ribio Biotech Co.,Ltd
010-62664360 +8613328773880 wucy@ribio.com.cn China 117 58
Shanghai Worldyang Chemical Co.,Ltd.
,+86-21-56795779; +8613651600618 sales@worldyachem.com China 879 58
Shanghai Yingrui Biopharma Co.,Ltd
21-33585366 export01@shyrchem.com CHINA 1320 58
Shanghai Jinli Pharmaceutical Co.,Ltd
+86-21-57256005 +86-15921811235 chang@shjlchem.com China 20 58
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12457 58
Frapp's ChemicalNFTZ Co., Ltd. 		+86 (576) 8169-6106 sales@frappschem.com China 885 50
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
Beijing Cooperate Pharmaceutical Co.,Ltd 		010-60279497 sales01@cooperate-pharm.com CHINA 1811 55
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Supplier Advantage
Beijing Ribio Biotech Co.,Ltd
58
Shanghai Worldyang Chemical Co.,Ltd.
58
Shanghai Yingrui Biopharma Co.,Ltd
58
Shanghai Jinli Pharmaceutical Co.,Ltd
58
Hebei Mojin Biotechnology Co., Ltd 		58
Frapp's ChemicalNFTZ Co., Ltd. 		50
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Beijing Cooperate Pharmaceutical Co.,Ltd 		55
Henan Tianfu Chemical Co.,Ltd. 		55

View Lastest Price from 2,3,4,6-Tetra-O-benzyl-D-glucopyranose manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,3,4,6-Tetra-O-benzyl-D-glucopyranose pictures 2023-08-24 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
4132-28-9
 US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
2,3,4,6-Tetra-O-benzyl-D-glucopyranose pictures 2022-09-30 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
4132-28-9
 US $0.00-0.00 / kg 1kg 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
2,3,4,6-Tetra-O-benzyl-D-glucopyranose pictures 2022-05-11 2,3,4,6-Tetra-O-benzyl-D-glucopyranose
4132-28-9
 US $0.00 / kg 1kg 98%min 10000kg WUHAN FORTUNA CHEMICAL CO., LTD

2,3,4,6-Tetra-O-benzyl-D-glucopyranose Spectrum

2,3,4,6-Tetra-O-benzyl-D-glucopyranose(4132-28-9)FT-IR

4132-28-9(2,3,4,6-Tetra-O-benzyl-D-glucopyranose)Related Search:

Tetrahydropyran Centchroman Benzyl benzoate BENZYL GLYCIDYL ETHER Benzyltrimethylammonium chloride
N,N-Dimethylbenzylamine 2,3,4,6-TETRA-O-BENZYL-ALPHA-D-GLUCOPYRANOSE Dibenzylideneacetone Benzyl chloride Benzyl alcohol
Benzyltriethylammonium chloride Benzyl bromide DEXTROSE 2,3,4,6-TETRA-O-BENZOYL-BETA-D-GLUCOPYRANOSYL ISOTHIOCYANATE (R)-Valiolamine Voglibose
(2S,3S,4S,5S)-5-Hydroxy-2,3,4-tris(phenylMethoxy)-5-[(phenylMethoxy)Methyl]-cyclohexanone Valiolamine (S)-Valiolamine Voglibose

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2,3,4,6-Tetra-O-benzyl-D-glucopyranose(for Voglibose) 2,3,4,6-TETRA-O-BENZYL-D-GLUCOPYRANOSE, 98%, MIXTURE OF ANOMERS 3,4,5-Tris(benzyloxy)-6-(benzyloxymethyl)tetrahydro-2H-pyran-2-ol 2,3,4,6-TETRA-O-BENZYL-D -GLUCOPYRANOSE CRYSTALLINE 2,3,4,6-Tetra-O-benzyl-D-glucopyranose 2,3,4,6-TETRABENZYL-D-GLUCOSE D-Glucopyranose, 2,3,4,6-tetrakis-O-(phenylmethyl)- 2,3,4,6-TETRA-O-BENZYL-A-D-GLUCOPYRANOSIDE 2,3,4,6-Tetra-O-benzyl-D-glucopyranose, 98+% 2,3,4,6-Tetra-O-benzyl-α-D-glucopyranose ,97% 2,3,4,6-Tetrakis-O-(phenylmethyl)-D-glucopyranose 2,3,4,6-Tetra-O-benz Tetra-O-benzyl-D-glucopyranose benzyl-D-glucopyranose Voglibose Impurity 4 2,3,4,6-TETRA-O-BENZYL-D-GLUCOPYRANOSE , MIXTURE OF ANOMERS 3,4,5-Tris(benzyloxy)-6-(benzyloxymethyl) 3,4,5-TRIS(BENZYLOXY)-6-[(BENZYLOXY)METHYL]OXAN-2-OL (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-[(benzyloxy)methyl]oxan-2-ol ucopyranose Tetra-O-Benzyl-D-Glucopyranose(2,3,4,6-Tetra-O-benzyl-D-glucopyranose) 2,3,4,6-Tetra-O-benzyl-D-glucopyranose ISO 9001：2015 REACH 2,3,4,6-Tetra-O-benzyl-O-glucopyranose (3R,4S,5R,6R)-3,4,5-tris(phenylmethoxy)-6-(phenylmethoxymethyl)oxan-2-ol (3R,4S,5R,6R)-3,4,5-tris(benzyloxy)-6-((benzyloxy)Methyl)tetrahydro-2H-pyran-2-ol 2,3,4, 6-4-o-benzyl-d-pyranoglucose Garlic oil 8000-78-0 Voglibose Intermediates 2,3,4,6-Tetrabenzyl-D-Glucopyranose 2,3,4,6-Tetra-O-benzyl-D-glucopyranose,NA 2,3,4,6-Tetra -0- benzyl- α -D- gluco pyranose 2,3,4,6-Tetrakis-O-benzyl-D-glucopyranose 4132-28-9 4132-28-9 6564-72-3 4231-28-9 Halogenated Heterocycles ,Pyrazoles Biochemistry Glucose O-Substituted Sugars Sugars aldehydes Carbohydrates & Derivatives Carbohydrate Synthesis Monosaccharides Specialty Synthesis Carbohydrates Carbohydrates A to Carbohydrates P-ZBiochemicals and Reagents Monosaccharide 13C & 2H Sugars Glycon Biochem