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6-Hydroxynaphthalene-2-sulphonic acid

CAS No.
93-01-6
Chemical Name:
6-Hydroxynaphthalene-2-sulphonic acid
Synonyms
Baum's acid;Schafferacid;Scheffers acid;SCHAEFFER ACID;SCHAFFER'S SALT;Schaffer`s acid;SCHAEFFER'S ACID;SCHAEFFER'S SALT;kyselinaschaferova;Kyselina schaferova
CBNumber:
CB7301210
Molecular Formula:
C10H8O4S
Molecular Weight:
224.23
MDL Number:
MFCD00035733
MOL File:
93-01-6.mol
Last updated:2023-11-01 14:31:33

6-Hydroxynaphthalene-2-sulphonic acid Properties

Melting point >300 °C(lit.)
Boiling point 335.63°C (rough estimate)
Density 1.4643 (rough estimate)
refractive index 1.5400 (estimate)
pka 0.41±0.40(Predicted)
CAS DataBase Reference 93-01-6(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII O937I7N48V
NIST Chemistry Reference 2-Naphthalenesulfonic acid, 6-hydroxy-(93-01-6)
EPA Substance Registry System 2-Naphthalenesulfonic acid, 6-hydroxy- (93-01-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3

6-Hydroxynaphthalene-2-sulphonic acid price More Price(11)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Matrix Scientific 100442 6-Hydroxynaphthalene-2-sulfonic acid 95+% 93-01-6 250mg $435 2021-12-16 Buy
AK Scientific T979 6-Hydroxynaphthalene-2-sulphonicacid 93-01-6 250mg $637 2021-12-16 Buy
Matrix Scientific 100442 6-Hydroxynaphthalene-2-sulfonic acid 95+% 93-01-6 1g $975 2021-12-16 Buy
American Custom Chemicals Corporation CHM0021585 6-HYDROXYNAPHTHALENE-2-SULPHONIC ACID 95.00% 93-01-6 1G $1076.92 2021-12-16 Buy
Alichem 93016 6-Hydroxynaphthalene-2-sulfonicacid 93-01-6 1g $998 2021-12-16 Buy
Product number Packaging Price Buy
100442 250mg $435 Buy
T979 250mg $637 Buy
100442 1g $975 Buy
CHM0021585 1G $1076.92 Buy
93016 1g $998 Buy

6-Hydroxynaphthalene-2-sulphonic acid Chemical Properties,Uses,Production

Chemical Properties

2-Hydroxynaphthalene- 6 -sulfonic acid [93-01-6]. (6-hydroxynaphthalene-2-sulfonic acid), Schaeffer acid, C10H8O4S, Mr 224.23, is readily soluble in water, from which it can be recrystallized as the monohydrate (mp 129℃). The sodium salt is sparingly soluble in cold water (1.7 %) but forms a 30 % solution at 80℃. Coupling with diazo compounds results in substitution in the 1-position as does treatment with bromine, nitrous acid, or oleum. Fusion with potassium hydroxide gives 2,6-dihydroxynaphthalene, amination gives 2- aminonaphthalene-6-sulfonic acid, and sulfonation (20 % oleum, 25℃) results in 2-hydroxynaphthalene-1,6-disulfonic acid.

Uses

2-Hydroxynaphthalene-6-sulfonic acid is used as a coupling component for a wide range of azo dyes, e.g., C.I. Acid Orange 12, C.I. Food Yellow 3, and C.I. Food Orange 2. It is also used as an intermediate for more highly substituted dye components and synthetic tanning agents. The 1-nitroso derivative forms an iron complex (C.I. Acid Green 1) which was formerly used as a wool dye.

Preparation

2-Naphthol is added to a mixture of sulfuric acid and sodium sulfate, and the reaction is continued at 90 C for 12 h. After pouring the reaction mixture into water, the sodium salt of the product is precipitated by addition of salt and filtered at 60℃ to separate the isomers.

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View Lastest Price from 6-Hydroxynaphthalene-2-sulphonic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
6-Hydroxynaphthalene-2-sulphonic acid pictures 2019-12-31 6-Hydroxynaphthalene-2-sulphonic acid
93-01-6
US $1.00 / g 1g 99% 200kg Career Henan Chemical Co
2-Hydroxy-6-naphthalenesulfonic acid 2-hydroxy-6-naphthalenesulfonicacid 2-Hydroxynaphthalene-6-sulfonic acid 2-Naphtol-6-sulfosaure 6-hydroxy-2-naphthalenesulfonicaci Baum's acid beta-Naphthol-6-sulfonic acid beta-naphthol-6-sulfonicacid beta-Naphtholsulfonic acid S beta-naphtholsulfonicacids SCHAFFER'S SALT SODIUM 6-HYDROXY-2-NAPHTHALENESULFONATE 2-naphthol-6-sulphonic acid 6-Hydroxy-6-Sulfonic Acid Scheffers acid 6-hydroxy-2-naphthalenesulfonic acid 6-HYDROXY-2-NAPHTHALENESULFONIC ACID SODIUM SALT 6-Hydroxynaphthalene-2-sulphonic acid 2-naphthol-6-sulfonic acid 2-NAPHTHOL-6-SULFONIC ACID SODIUM 2-NAPHTHOL-6-SULFONIC ACID SODIUM SALT 2-NAPHTHOL-6-SULFONIC ACID SODIUM SALT DIHYDRATE 2-NAPTHOL-6-SULFONIC ACID Schaffer`s acid 6-Hydroxy-2-Naphthalenesulphonic Acid 6-hydroxynaphthalene-2-sulfonic acid 2-Naphthol-6-potassiumsulfonate 2-Naphthalenesulfonic acid, 6-hydroxy- 1-naphthol-2-sulfonic acid 6-Hydroxy-2-naphthalenesulfonic acid sodium salt hydrate technical grade Kyselina 2-naftol-6-sulfonova Kyselina schaferova kyselina2-naftol-6-sulfonova kyselinaschaferova schaeffer’sbeta-acid schaeffer’sbeta-naphtholsulfonicacid Schaeffer's beta-acid Schaeffer's beta-naphtholsulfonic acid Schafferacid SODIUM 2-NAPHTHOL-6-SULFONATE SCHAEFFER'S ACID SCHAEFFER'S SALT SCHAEFFER ACID Ponceau 4R Impurity 4 Monomer Olaquindox Impurity 6 93-01-6 Organic Building Blocks Sulfonic/Sulfinic Acids Sulfur Compounds Building Blocks Organic acids Intermediates of Dyes and Pigments