ChemicalBook >> CAS DataBase List >>Sodium benzenolate

Sodium benzenolate

CAS No.
139-02-6
Chemical Name:
Sodium benzenolate
Synonyms
SODIUM PHENOXIDE;SODIUM PHENATE;SODIUM PHENOLATE;Phenolsodium;PHENYL SODIUM;SODIUM PHENYL;Phenoxysodium;phenolatesodium;sodiumcarbolate;Natriumphenolat
CBNumber:
CB7306886
Molecular Formula:
C6H5NaO
Molecular Weight:
116.09
MDL Number:
MFCD00013134
MOL File:
139-02-6.mol
Last updated:2023-11-10 11:05:08

Sodium benzenolate Properties

Melting point >300℃
Density 0,898 g/cm3
RTECS SM8780000
Flash point 28°C
storage temp. below 5° C
solubility DMSO (Slightly, Sonicated), Methanol (Slightly)
form Solid
color Pale Yellow to Pale Brown
Specific Gravity 0.898
Water Solubility Very soluble in water, soluble in alcoholSoluble in water, acetone and alcohol.
Sensitive Hygroscopic
Stability Hygroscopic
CAS DataBase Reference 139-02-6(CAS DataBase Reference)
FDA 21 CFR 310.545
EWG's Food Scores 1
FDA UNII 4NC0T56V35
EPA Substance Registry System Sodium phenate (139-02-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P301+P330+P331
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  3286
TSCA  No
HazardClass  8
PackingGroup  III
HS Code  2907110000
NFPA 704
0
3 0

Sodium benzenolate price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Alfa Aesar B25002 Sodium phenoxide, 98% 139-02-6 50g $88 2024-03-01 Buy
Alfa Aesar B25002 Sodium phenoxide, 98% 139-02-6 250g $348 2024-03-01 Buy
Usbiological 289056 Sodium phenoxide 139-02-6 25g $333 2021-12-16 Buy
AK Scientific W3042 Sodiumphenoxide 139-02-6 5g $34 2021-12-16 Buy
AHH MT-22340 Sodiumphenoxide 98% 139-02-6 1000g $398 2021-12-16 Buy
Product number Packaging Price Buy
B25002 50g $88 Buy
B25002 250g $348 Buy
289056 25g $333 Buy
W3042 5g $34 Buy
MT-22340 1000g $398 Buy

Sodium benzenolate Chemical Properties,Uses,Production

Chemical Properties

Sodium phenate, or sodium phenoxide, NaOC6H5, is a white crystalline substance that easily dissolves in water and alcohol. It decomposes when exposed to carbon dioxide in the air. It is produced by reacting sodium hydroxide solution (not carbonate) with phenol and subsequently evaporating the mixture. Sodium phenate is commonly used in the production of sodium salicylate.

Uses

Sodium phenoxide is used as a precursor to aryl ethers and involved in the preparation of phenyl ethers and metal phenolates. It serves as an antiseptic and used in organic synthesis.

Uses

As a general disinfectant, either in solution or mixed with slaked lime, etc., for toilets, stables, cesspools, floors, drains, etc.; for the manufacture of colorless or light-colored artificial resins, many medical and industrial organic Compounds and dyes; as a reagent in chemical analysis. Pharmaceutic aid (preservative).

Definition

ChEBI: Sodium phenolate is a phenolate. It has a role as a disinfectant.

Preparation

Sodium phenoxide was freshly prepared by adding sodium metal to phenol (0.45 g, 4.8 mmol) dissolved in diethyl ether (15 cm3), under an atmosphere of dry nitrogen. This was refluxed with (11) (1.0 g, 2.8 mmol) for 23 h. Following evaporation of the ether, water (20 cm3) was added and the mixture extracted into DCM. The DCM solution was dried (MgS04) and evaporated to give a solid (1.2 g). Fractional sublimation and recrystallisation from acetonitrile gave recovery of 2,4,6-tribromo-3,5-difluoropyridine (0.8 g, 80%) and 3-phenoxy-5-fluoro-2,4,6-tribromopyridine (0.2 g, 20%), m.p. 100±1 OC (Found: C, 31.3; H, 1.1; N, 2.9. C11H5Br3FNO requires C, 31.0; H, 1.2; N, 3.3%); IR spectrum no. 15; mass spectrum no. 15; nmr spectrum no. 19.

General Description

A white to reddish colored solid in the form of crystalline rods. Used as an antiseptic and in organic synthesis.

Air & Water Reactions

Decomposes in air. Soluble in water. In both cases, a corrosive alkaline solution forms that is a strong irritant to skin and eyes.

Reactivity Profile

Salts, basic, such as SODIUM PHENOLATE, are generally soluble in water. The resulting solutions contain moderate concentrations of hydroxide ions and have pH's greater than 7.0. They react as bases to neutralize acids. These neutralizations generate heat, but less or far less than is generated by neutralization of the bases in reactivity group 10 (Bases) and the neutralization of amines. They usually do not react as either oxidizing agents or reducing agents but such behavior is not impossible.

Hazard

Strong irritant to skin and tissue.

Safety Profile

Poison by subcutaneous route. A corrosive irritant to skin, eyes, and mucous membranes. When heated to decomposition it emits toxic fumes of Na2O. See also PHENOL and SODIUM HYDROXIDE.

Purification Methods

The ground powder is washed with Et2O, then heated at 60o/1mm for 12 to 24hours to remove any free phenol and solvent. [Kornblum & Lurie J Am Chem Soc 81 2710 1959, Beilstein 6 I 718.]

Global( 130)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 14764 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Shenyang Simchoice Chemical Co.,Ltd
+86-024-23769576 +86-15040101888 sales@simchoicechem.com China 254 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23556 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 9802 58

View Lastest Price from Sodium benzenolate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Sodium benzenolate pictures 2020-03-22 Sodium benzenolate
139-02-6
US $1.80-9.80 / KG 1g 90.0%-99.9% 800kg Career Henan Chemical Co
Sodium benzenolate pictures 2020-01-18 Sodium benzenolate
139-02-6
US $3.00 / KG 1KG 98% 1kg , 5kg, 50kg Career Henan Chemical Co
Phenol,sodiumsalt phenol,sodiumsalt(solid) phenolatesodium Phenolsodium phenolsodiumsalt sodiumcarbolate sodiumphenolate,solid SODIUM PHENYL PHENYL SODIUM Sodiumphenoxideanhydrous SodiuM ophenlate Sodium phenoxide, 95%, anhydrous Sodium phenoxide, 20% in methanol Natriumphenolat sodium phenylate Sodium benzenolate Phenoxysodium Sodium benzeneolate Sodium benzenolate ISO 9001:2015 REACH Kjeldahl Phenol Reagent, Pure, for Determination Of Nitrogen, Fisher Chemical SODIUM PHENATE SODIUM PHENOLATE SODIUM PHENOXIDE Amlexanox Impurity 9 139-02-6 C6H5ONa NaC6H5 C6H6ONa C6H5NaO C6H5ONa3H2O