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PHOSFOLAN

CAS No.
947-02-4
Chemical Name:
PHOSFOLAN
Synonyms
oms646;Cyolan;ac47031;Cayolan;cl47031;Cyalane;OMS 646;ei47031;CYOLANE;AC 47031
CBNumber:
CB7397875
Molecular Formula:
C7H14NO3PS2
Molecular Weight:
255.29
MDL Number:
MFCD00128041
MOL File:
947-02-4.mol
Last updated:2023-05-04 17:34:44

PHOSFOLAN Properties

Melting point 40.75°C
Boiling point 116.5°C
Density 1.42±0.1 g/cm3(Predicted)
refractive index n25D 1.5463
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form solid
pka -4.95±0.20(Predicted)
color White to Off-White
EWG's Food Scores 1-2
FDA UNII CHJ98J84AY
EPA Substance Registry System Phosfolan (947-02-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS06
Signal word  Danger
Hazard statements  H300+H310
Precautionary statements  P264-P280-P301+P310-P302+P350-P310
Hazard Codes  T+
Risk Statements  27/28
Safety Statements  28-36/37-45
RIDADR  2783
RTECS  NJ6475000
HazardClass  6.1(a)
PackingGroup  I

PHOSFOLAN Chemical Properties,Uses,Production

Chemical Properties

Phosfolan is a solid organophosphorus insecticide in yellow colour or colourless appearance. Phosfolan is susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. On heating, phosfolan gets decomposed and release/emits toxic gases and vapours, CO, NOx, SOx, and Pox. It does not undergo hazardous polymerisation reaction. Partial oxidation by oxidising agents may result in the release of toxic phosphorus oxides. Phosfolan is susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidising agents may result in the release of toxic phosphorus oxides. Phosfolan gets hydrolysed by alkalis.

Chemical Properties

Phosfolan is a colorless to yellow solid.

Uses

Insecticide.

Uses

Phosfolan was identified and determined to be a residual pesticide in okra samples.

Definition

ChEBI: Phosfolan is a phosphoric ester.

General Description

Colorless to yellow solid. Used as an insecticide.

Air & Water Reactions

Hydrolyzed by alkalis. [EPA, 1998].

Reactivity Profile

Organophosphates, such as PHOSFOLAN, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.

Health Hazard

Similar to parathion. Death may result due to respiratory arrest as a result of paralysis of respiratory muscles and intense bronchoconstriction. Also considered a cholinesterase inhibitor.

Fire Hazard

(Non-Specific -- Organophosphorus Pesticide, n.o.s.) PHOSFOLAN may burn but does not ignite readily. Container may explode in heat of fire. When heated to decomposition, PHOSFOLAN emits very toxic fumes of oxides of phosphorus, sulfur, and nitrogen. Hydrolyzed by alkalies.

Safety Profile

Poison by ingestion and skin contact. An insecticide used against leaf-feeding larvae of cotton insect pests. When heated to decomposition it emits very toxic fumes of POx, SOx, and NOx. See also ESTERS

Potential Exposure

An organophosphate, A potential danger to those involved in the manufacture, formulation and application of this insecticide.

Shipping

UN3464 Organophosphorus compound, solid, toxic, n.o.s, Hazard Class: 6.1; Labels: 6.1-Poisonous materials, Technical Name Required. UN2783 Organophosphorus pesticides, solid, toxic, Hazard Class: 6.1; Labels: 6.1-Poisonous materials.

Incompatibilities

Organophosphates are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrideds and active metals. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides Incompatible with nitrates and water. May hydrolyze upon contact with water, steam and moisture, and produce toxic oxides of phosphorus, nitrogen, sulfur, and chlorine

Waste Disposal

Consult with environmental regulatory agencies for guidance on acceptable disposal practices. Generators of waste containing this contaminant (≥100 kg/mo) must conform with EPA regulations governing storage, transportation, treatment, and waste disposal. In accordance with 40CFR165, follow recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office.

PHOSFOLAN Preparation Products And Raw materials

(Diethoxyphosphinyl)dithioimidocarbonic acid cyclic ethylene ester (diethoxyphosphinyl)dithio-imidocarbonicacicyclicethyleneester (diethoxyphosphinyl)dithioimidocarbonicacidcyclicethyleneester 1,2-Ethanedithiol, cyclic ester with P,P-diethyl phosphonodithioimidocarbonate 1,2-Ethanedithiol, cyclic S,S-ester with phosphonodithioimidocarbonic acid O,O-diethyl ester 1,2-ethanedithiol,cyclicesterwithp,p-diethylphosphonodithioimidocarbonat 1,2-ethanedithiol,cyclicesterwithp,p-diethylphosphonodithioimidocarbonate 1,2-ethanedithiol,cyclics,s-esterwithphosphonodithioimidocarbonicacidp, 1,3-dithiolan-2-ylidene-phosphoramidicacidiethylester 2-(Diethoxyphosphenylimino)-1,3-dithiolane 2-(diethoxyphosphinylimino)-1,3-dithiolane 2-[(Diethoxyphosphinyl)Imino]-1,3-dithiolane AC 47031 ac47031 American cyanamid 47031 American cyanamid ac 47,031 American cyanamid cl-47031 American Cyanamide 47031 americancyanamid47031 americancyanamidac47,031 americancyanamidcl-47031 americancyanamide47031 Cayolan CI-47031 CL 47031 cl47031 cl-47031 Cyalane Cyclic ethylene P,P-diethyl phosphonodithioimidocarbonate Cyclic ethylene(diethoxyphosphinothioyl)dithioimidocarbonate Imidocarbonic acid, phosphonodithio-, O,O-diethyl cyclic ethylene ester imidocarbonicacid,phosphonodithio-,cyclicethylenep,p-diethylester imidocarbonicacid,phosphonodithio-,p,p-diethylcyclicethyleneester OMS 646 oms646 P,P-Diethyl cyclic ethylene ester of phosphonodithioimidocarbonic acid p,p-diethylcyclicethyleneesterofphosphonodithioimidocarbonicacid p-diethylester phospholan Phosphoramidic acid, 1,3-dithiolan-2-ylidene-, diethyl ester PHOSFOLAN Phosfolan(content>15) Phosfolan emulsion(content 0.5-15%) Phosfolan powder granules phosfolan (ISO) diethyl 1,3-dithiolan-2-ylidenephosphoramidate Phosfolan E.C. Cyolane(ACC) PHOSFOLAN, 1GM, NEAT phosfolan (bsi,e-iso) phospholan (f-iso) diethoxyphosphoryl(1,3-dithiolan-2-ylidene)amine N-diethoxyphosphoryl-1,3-dithiolan-2-imine Phosfolan Solution, 100ppm cyclicethylene(diethoxyphosphinothioyl)dithioimidocarbonate cyclicethylenep,p-diethylphosphonodithioimidocarbonate cyclics,s-esterwithphosphonodithioimidocarbonicacidp,p-2-ethanedithiol Cyolan Cyolane cylan