ChemicalBook >> CAS DataBase List >>Phenyl chlorothionocarbonate
Phenyl chlorothionocarbonate
- CAS No.
- 1005-56-7
- Chemical Name:
- Phenyl chlorothionocarbonate
- Synonyms
- O-Phenyl carbonochloridothioate;PHENYL CHLOROTHIONOFORMATE;O-PHENYL CHLOROTHIONOFORMATE;PHENYL THIONOCHLOROFORMATE;phenylcarbonochloridothioate;phenyl thioxochloroformate;Phenoxythiocarbonyl chloride;O-phenyl chloromethanethioate;NSC 99103;Phenoxythiocar
- CBNumber:
- CB7480281
- Molecular Formula:
- C7H5ClOS
- Molecular Weight:
- 172.63
- MDL Number:
- MFCD00004920
- MOL File:
- 1005-56-7.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| Melting point | 51 °C |
|---|---|
| Boiling point | 81-83 °C/6 mmHg (lit.) |
| Density | 1.248 g/mL at 25 °C (lit.) |
| refractive index |
n |
| Flash point | 179 °F |
| storage temp. | Inert atmosphere,2-8°C |
| solubility | Chloroform, Ethyl Acetate |
| form | Liquid |
| Specific Gravity | 1.248 |
| color | Clear yellow |
| Water Solubility | decomposes |
| Sensitive | Moisture Sensitive |
| BRN | 774830 |
| CAS DataBase Reference | 1005-56-7(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363-P405 | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 26-36/37/39-45 | |||||||||
| RIDADR | UN 3265 8/PG 2 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | II | |||||||||
| HS Code | 29309070 | |||||||||
| NFPA 704 |
|
Phenyl chlorothionocarbonate price More Price(28)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 234524 | O-Phenyl chlorothionoformate 99% | 1005-56-7 | 5g | $96.8 | 2024-03-01 | Buy |
| Sigma-Aldrich | 234524 | O-Phenyl chlorothionoformate 99% | 1005-56-7 | 1g | $28.2 | 2023-06-20 | Buy |
| TCI Chemical | P1236 | Phenyl Chlorothionoformate >98.0%(GC)(T) | 1005-56-7 | 5g | $32 | 2024-03-01 | Buy |
| TCI Chemical | P1236 | Phenyl Chlorothionoformate >98.0%(GC)(T) | 1005-56-7 | 25g | $97 | 2024-03-01 | Buy |
| Alfa Aesar | L00838 | Phenyl chlorothionoformate, 98+% | 1005-56-7 | 1g | $28.65 | 2024-03-01 | Buy |
Phenyl chlorothionocarbonate Chemical Properties,Uses,Production
Chemical Properties
CLEAR YELLOW LIQUID
Uses
O-Phenyl chlorothionoformate has been used in:
- stereodirected synthesis of optically active, (?)-mintlactone
- synthesis of peptide α-thioesters having a variety of C-terminal amino acids
- synthesis of scyllo-inositol derivatives
- thionocarbonylation of unprotected thymine nucleosides
- preparation of phenoxythiocarbonyl esters of protected ribonucleosides
Uses
Phenyl Chlorothionoformate is used in the preparation of an bicyclic thymidine analogs as selective inhibitors of Thymidine monophosphate kinase Mycobacterium tuberculosis (TMPKmt).
Purification Methods
Purify it by dissolving in CHCl3, washing with H2O, drying (CaCl2), filtering, evaporating and distilling twice under a vacuum to give a clear yellow liquid. It is reactive and POISONOUS—work in a fume cupboard. Store it in sealed ampoules under N2. A possible impurity is O,O'-diphenyl thiocarbonate which has m 106o and remains behind in the distilling flask. [B.gemann et al. in Methoden Der Organischen Chemie (Houben-Weyl) 4th edn (E. Müller Ed.) Vol 9 Schwefel-Selen-Tellur Verbindungen pp. 807-808 1955, Rivier & Schalch Helv Chim Acta 6 612 1923, Kalson Chem Ber 20, 2384 1987, Rivier & Richard Helv Chim Acta 8 490 1925, Sch.nberg & Varga Justus Liebigs Ann Chem 483 176 1930, Sch.nberg & Vargha Chem Ber 64 1390 1931, Beilstein 6 III 609.]
Phenyl chlorothionocarbonate Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 256)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| Nanjing MSN chemical Co., Ltd | 25-57015632 +8618913029712 | export@msnchem.com | China | 25 | 34 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Wuhan Chemwonders Technology Inc. | 027-85778276 | info@chemwonders.com | CHINA | 176 | 58 |
| Shandong chuangyingchemical Co., Ltd. | 18853181302 | sale@chuangyingchem.com | CHINA | 5909 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 47465 | 58 |
| Shanghai Yudiao Chemistry Technology Co.,Ltd | 02137285211 18964703211 | info@yudiaochem.com | CHINA | 238 | 58 |
View Lastest Price from Phenyl chlorothionocarbonate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | Phenyl chlorothionocarbonate
1005-56-7
|
US $1.00 / kg | 1kg | 95%-99% | as request | Career Henan Chemical Co |
-
- Phenyl chlorothionocarbonate
1005-56-7
- US $1.00 / kg
- 95%-99%
- Career Henan Chemical Co
1005-56-7(Phenyl chlorothionocarbonate)Related Search:
Phenyl thiochloroformate.
Phenyl chlorothionoformate, 98+%
Formic acid, chlorothio-, O-phenyl ester
(Phenoxy)thioformyl chloride
Chloridothiocarbonic acid O-phenyl ester
Chloridothiocarbonic acid phenyl ester
Phenyl chlorothionocarbonate,99%
2-Phenyl chlorothionoformate
Phenyl chlorothionocarbonate, 99% 5GR
NSC 99103
Phenoxythiocar
Chlorothioformic Acid O-Phenyl Ester
Phenyl Thionochloroformate
O-Phenyl chlorothionoforMate 99%
Chlorothioformic Acid O-Phenyl Ester,Phenyl Thionochloroformate,Phenyl Chlorothionoformate
Phenyl chlorothionocarbonate
O-Phenyl chlorothioformate for synthesis
Carbonochloridothioicacid,O-phenylester
O-PHENYL CHLOROTHIOCARBONATE
O-PHENYL CHLOROTHIOFORMATE
PHENYL CHLOROTHIONOCARBONATE
PHENYL CHLOROTHIOXOFORMATE
CHLOROTHIOFORMIC ACID O-PHENYL ESTER
CHLOROTHIOFORMIC ACID PHENYL ESTER
HENYL CHLOROTHIONOCARBONATE
Phenylchlorothionocarbonate~Phenylthionochloroformate
PhenylChlorothionoformate>
orothionoformate
phenyl chloromethanethioate
O-Phenyl chlorotionoformate
Phenoxythiocarbonyl chloride
O-Phenyl carbonochloridothioate
O-PHENYL CHLOROTHIONOFORMATE
PHENYL CHLOROTHIONOFORMATE
PHENYL THIONOCHLOROFORMATE
phenyl thioxochloroformate
phenylcarbonochloridothioate
O-phenyl chloromethanethioate
1005-56-7
ClCSOC6H5
C7H5ClOS
Building Blocks
Thiocarbonyl Compounds
Sulfur Compounds
Organic Building Blocks
Sulfur Compounds (for Synthesis)
Building Blocks
Chemical Synthesis
Organic Building Blocks
Sulfur Compounds
Thiocarbonyl Compounds
Sulfur Compounds (for Synthesis)
Synthetic Organic Chemistry