Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Structure
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] structure
CAS No.
12354-85-7
Chemical Name:
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
Synonyms
Rh(Cp*)Cl2]2;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER;PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER;tube1183;Chiralyst P618;)rhodium(III) DichL;Bis[(pentamethylcycl;RHODIUM (III) CHLORIDE DIMER;DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC;PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)&
CBNumber:
CB7482876
Molecular Formula:
C20H30Cl4Rh210*
Molecular Weight:
618.08
MDL Number:
MFCD00061552
MOL File:
12354-85-7.mol
MSDS File:
SDS
Last updated:2023-05-15 10:43:51
Request For Quotation

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Properties

Melting point >300°C
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Chloroform (Sparingly), Methanol (Slightly)
form crystal
color red
Water Solubility Soluble in chloroform and acetone. Slightly soluble in tetrahydrofuran and methanol. Insoluble in water and diethylether
Stability Hygroscopic
NIST Chemistry Reference Rhodium, di-«mu»-chlorodichlorobis[(1,2,3,4,5-«eta»)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di-(12354-85-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332-H315
Precautionary statements  P261-P264-P280-P301+P312-P302+P352+P312-P304+P340+P312
Hazard Codes  Xn
Risk Statements  20/21/22-36/37/38-R36/37/38-R20/21/22
Safety Statements  26-36-S36-S26-24/25
WGK Germany  3
TSCA  No
HS Code  28439000
NFPA 704
1
2 0

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] price More Price(49)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 338370 Pentamethylcyclopentadienylrhodium(III) chloride dimer 97% 12354-85-7 250mg $344 2024-03-01 Buy
Sigma-Aldrich 338370 Pentamethylcyclopentadienylrhodium(III) chloride dimer 97% 12354-85-7 1g $855 2024-03-01 Buy
TCI Chemical P1788 (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer >96.0%(T) 12354-85-7 1g $476 2024-03-01 Buy
TCI Chemical P1788 (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer >96.0%(T) 12354-85-7 200mg $162 2024-03-01 Buy
Alfa Aesar 033657 Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer, 99% 12354-85-7 250mg $203 2023-06-20 Buy
Product number Packaging Price Buy
338370 250mg $344 Buy
338370 1g $855 Buy
P1788 1g $476 Buy
P1788 200mg $162 Buy
033657 250mg $203 Buy

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Chemical Properties,Uses,Production

Reaction

  1. Catalyst used in the functionalization of acetanilides under solventless conditions in a ball mill.
  2. Rhodiumcatalyzed regioselective direct C-H arylation of indoles with aryl boronic acids.
  3. Catalyst used in the asymmetric transfer hydrogenation of imines in water.
  4. Facile rhodium-catalyzed synthesis of fluorinated pyridines.
  5. Rhodium-catalyzed alkylation of azobenzenes with allyl acetates.
Reactions of 12354-85-7_1
Reactions of 12354-85-7_2

Chemical Properties

burgundy solid

Uses

Dichloro(pentamethylcyclopentadienyl)rhodium(III) dimer is used as a catalyst for amidation, reductive alkylation, hydrogenation, chiral hydrogenation reactions. It is also used as a catalyst for oxidative olefination reactions, C-C bond cleavage of secondary alcohols, oxidative annulation of pyridine and ortho C-H olefination of phenol derivatives.

Uses

Oxidative olefination reactions C-C bond cleavage of secondary alcohols Ortho C-H olefination of phenol derivatives Oxidative annulation of pyridines Oxidative ortho-acylation of benzamides with aldehydes via direct functionalization of the sp2 C-H bond A

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Preparation Products And Raw materials

Raw materials

Preparation Products

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Suppliers

Global( 242)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15371 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714 fandachem@gmail.com China 9350 55
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3012 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Nanjing Dolon Biotechnology Co.,Ltd. 		18905173768 sales@dolonchem.com CHINA 2972 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Accela ChemBio Inc. 		(+1)-858-699-3322 info@accelachem.com United States 19965 58
Supplier Advantage
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60
career henan chemical co 		58
Nanjing Dolon Biotechnology Co.,Ltd. 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Accela ChemBio Inc. 		58

View Lastest Price from Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] pictures 2020-11-16 Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
12354-85-7
 US $20.00 / KG 1KG 99% 10000KG Longyan Tianhua Biological Technology Co., Ltd
Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] pictures 2019-07-06 Bis[(pentamethylcyclopentadienyl)dichloro-rhodium]
12354-85-7
 US $1.00 / KG 1KG 99% 200kg Career Henan Chemical Co

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] Spectrum

Bis[(pentamethylcyclopentadienyl)dichloro-rhodium](12354-85-7)1HNMRBis[(pentamethylcyclopentadienyl)dichloro-rhodium](12354-85-7)Raman

12354-85-7(Bis[(pentamethylcyclopentadienyl)dichloro-rhodium])Related Search:

DILINOLEIC ACID Sodium chloride alpha,alpha'-Dichloro-p-xylene 1,2,3,4,5-Pentamethylcyclopentadiene 1,3-Cyclopentadiene
Dichloroacetic acid SODIUM CYCLOPENTADIENIDE Tetraphenylcyclopentadienone METHYLCYCLOPENTADIENE DIMER 2-Chloro-5-chloromethylpyridine
Choline chloride Dichloromethylphenylsilane Ammonium chloride Rhodium Dichlorodimethylsilane
(Pentamethylcyclopentadienyl)iridium(III) chloride dimer (1R,3S,5R)-2-(tert-butoxycarbonyl)-5-methyl-2-azabicyclo[3.1.0]hexane-3-carboxylic acid (R)-3-(4'-bromophenyl)-3-hydroxypropanenitrile

1of4

Di-mu-chlorodichlorobis(pentamethyl-pi-cyclopentadienyl)dirhodium Rhodium, di-mu-chlorodichlorobis[(1,2,3,4,5-eta)-1,2,3,4,5-pentamethyl-2,4-cyclopentadien-1-yl]di- DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE DICHLOROPENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) DIMER BIS[(PENTAMETHYLCYCLOPENTADIENYL)DICHLORO-RHODIUM] PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III)& Dichloro(pentamethylcyclopentadienyl)rhodium(II) dimer Tetrachlorobis(pentamethylcyclopentadienyl)dirhodium Dichloro(pentamethylcyclopentadienyl)rhodium(III)dimer,99% di-ae-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer Di-μ-chlorodichlorobis(pentamethylcyclopentadienyl)dirhodate DI-M-CHLORODICHLOROBIS(PENTAMETHYLCYCLOPENTADIENYL)DIRHODATE Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,98% Di-mu-chlorodichlorobis-(pentamethylcyclopentadienyl)dirhodate ,Rhodium≥31.3% Carbon≥39.0 [Rhodium≥31.3% Carbon≥39.0] Bis[(pentamethylcycl PentaMethyl cyclopentadienyl RhodiuM dichloride diMer Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,98% (Cp*RhCl2)2 Pentamethylcyclopentadienylrhodium(Ⅲ) chloride dimer Dichloro(pentaMethylcyclopentadienyl)rhodiuM(III) diMer,(Cp*RhCl2)2 PentaMethylcyclopentadienylrhodiuM(III) chloride diMer 97% 1,3-Cyclopentadiene, 1,2,3,4,5-pentamethyl-, rhodium complex Bis(dichloro(pentamethylcyclopentadienyl)rhodium) Bis(pentamethylcyclopentadienylrhodium dichloride) TIANFU-CHEM--Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] (Pentamethylcyclopentadienyl)rhodium(III) Dichloride Dimer,98% Pentamethylcyclopentadienylrhodium(III) chloride dimer, 33% Rh, Product of Umicore DI-MU-CHLORODICHLOROBIS-(PENTAMETHYLCYC tube1183 (Pentamethylcyclopentadienyl)rhodium(III)DichlorideDimer> )rhodium(III) DichL Bis[(pentamethylcyclopentadienyl)dichloro-rhodium] ISO 9001：2015 REACH PENTAMETHYLCYCLOPENTADIENYLRHODIUM CHLORIDE DIMER PENTAMETHYLCYCLOPENTADIENYLRHODIUM(III) CHLORIDE DIMER Rh(Cp*)Cl2]2 Di( μ -chloro)dichlorobis(pentamethylcyclopentadiene)dirhodium(III) Bis[dichloro[η5-(pentamethylcyclopentadienyl)]rhodium RHODIUM (III) CHLORIDE DIMER Chiralyst P618 12354-85-7 C10H15Cl4Rh2 C20H48Cl4Rh2 CH35C5RhCl22 RhC5Me5Cl22 C20H30Cl4Rh2 C20H30Cl4Rh210 2C10H152Cl2Rh Catalysis and Inorganic Chemistry metallocene Catalysis and Inorganic Chemistry Chemical Synthesis Rhodium Catalysts for Organic Synthesis Classes of Metal Compounds Homogeneous Catalysts Metal Complexes Rh (Rhodium) Compounds Synthetic Organic Chemistry