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Thiourea dioxide

CAS No.
1758-73-2
Chemical Name:
Thiourea dioxide
Synonyms
FORMAMIDINESULFINIC ACID;AMINOIMINOMETHANESULFINIC ACID;Thiurea dioxide;Thiourea S,S-dioxide;FORMAMIDINESULPHINIC ACID;aminoimino-methanesulfinicaci;FASTECH;Amino(imino);FAS PRIMER PAIR;Tiourea dioxide
CBNumber:
CB7761108
Molecular Formula:
CH4N2O2S
Molecular Weight:
108.12
MDL Number:
MFCD00002397
MOL File:
1758-73-2.mol
MSDS File:
SDS
Last updated:2024-03-28 13:39:29

Thiourea dioxide Properties

Melting point 124-127 °C (dec.)(lit.)
Boiling point 355.3±25.0 °C(Predicted)
Density 1.68
vapor pressure 0Pa at 25℃
refractive index 1.6550 (estimate)
storage temp. 2-8°C
solubility 27g/l
pka 2.40±0.10(Predicted)
form Crystalline Powder
color White
PH 4 (10g/l, H2O, 20℃)
Water Solubility 30 g/L (20 ºC)
Sensitive Moisture Sensitive
BRN 506653
InChIKey FYOWZTWVYZOZSI-UHFFFAOYSA-N
LogP -3.37 at 25℃
CAS DataBase Reference 1758-73-2(CAS DataBase Reference)
FDA UNII 42BWR07L73
EPA Substance Registry System Methanesulfinic acid, aminoimino- (1758-73-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06,GHS08
Signal word  Danger
Hazard statements  H251-H302-H315-H318-H330-H335-H373
Precautionary statements  P235-P280-P301+P312+P330-P304+P340+P310-P305+P351+P338+P310-P314
Hazard Codes  Xn,Xi
Risk Statements  5-22-36/37/38
Safety Statements  26-24/25-36
RIDADR  UN 3341 4.2/PG 2
WGK Germany  1
RTECS  PB0372500
TSCA  Yes
HazardClass  4.2
PackingGroup  II
HS Code  29309070
NFPA 704
3
2 3

Thiourea dioxide price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.20082 Aminoiminomethanesulfinic acid for synthesis 1758-73-2 250g $75.9 2024-03-01 Buy
Sigma-Aldrich F16001 Formamidinesulfinic acid ≥98% 1758-73-2 100g $78.8 2024-03-01 Buy
Sigma-Aldrich 8.20082 Aminoiminomethanesulfinic acid for synthesis 1758-73-2 1kg $212 2024-03-01 Buy
TCI Chemical F0115 Formamidinesulfinic Acid >93.0%(T) 1758-73-2 25g $36 2024-03-01 Buy
TCI Chemical F0115 Formamidinesulfinic Acid >93.0%(T) 1758-73-2 500g $217 2024-03-01 Buy
Product number Packaging Price Buy
8.20082 250g $75.9 Buy
F16001 100g $78.8 Buy
8.20082 1kg $212 Buy
F0115 25g $36 Buy
F0115 500g $217 Buy

Thiourea dioxide Chemical Properties,Uses,Production

Chemical Properties

white crystalline powder

Uses

Convenient reagent for the reduction of ketones to secondary alcohols.
Thiourea dioxide is an effective bleach when used alone or when used after hydrogen peroxide in a full bleaching process (Duffield, 1986; Cegarra et al, 1988). Bleaching with thiourea dioxide is not common practice but it is effective when used alone, and the process compares favorably with hydrogen peroxide bleaching. A formulation can include a commercial thiourea dioxide product, wetting agent and EDTA sequestering agent. Reductive bleaching is carried out at pH 7.0 at 70°C for 60 min (Duffield, 1986).
Thiourea dioxide

General Description

A white or light-yellow odorless crystalline powder. Mp:126°C. Soluble in water (27 g / L at room temperature). Decomposes exothermically at temperatures above 126°C with the emission of noxious gases (sulfur oxides, ammonia, carbon monoxide, nitrogen oxides and hydrogen sulfide) and carbon dioxide. Extended exposure to temperatures above 50°C and moisture may cause visible decomposition. Irritating to skin and mucous membranes. Corrosive to eye tissue. Used in leather processing, the paper industry, photographic industry, and in textile processing as a bleaching agent.

Air & Water Reactions

Soluble in water

Reactivity Profile

Thiourea dioxide is a reducing agent and a derivative of sulfinic acid (a weak inorganic acid). Decolorizes and bleaches materials by chemical reduction. Stable under normal temperatures and pressures. May decompose on exposure to moist air or water. Incompatible with strong oxidizing agents, strong bases. Aqueous solutions are acidic and corrosive.

Health Hazard

Fire will produce irritating, corrosive and/or toxic gases. Inhalation of decomposition products may cause severe injury or death. Contact with substance may cause severe burns to skin and eyes. Runoff from fire control may cause pollution.

Fire Hazard

Flammable/combustible material. May ignite on contact with moist air or moisture. May burn rapidly with flare-burning effect. Some react vigorously or explosively on contact with water. Some may decompose explosively when heated or involved in a fire. May re-ignite after fire is extinguished. Runoff may create fire or explosion hazard. Containers may explode when heated.

Flammability and Explosibility

Non flammable

Purification Methods

Dissolve it in five parts of aqueous 1:1% NaHSO3 at 60-63o (charcoal), then allow it to crystallise slowly, with agitation, at 10o. Filter and dry it immediately at 60o [Koniecki & Linch Anal Chem 30 1134 1958]. [Beilstein 3 I 36, 3 IV 145.]

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View Lastest Price from Thiourea dioxide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Thiourea dioxide pictures 2024-04-24 Thiourea dioxide
1758-73-2
US $70.00-60.00 / kg 1kg 99% 20Tons Hebei Dangtong Import and export Co LTD
Thiourea dioxide pictures 2024-03-29 Thiourea dioxide
1758-73-2
US $0.00-0.00 / kg 1kg 99% 50000kg Hebei Yibangte Import and Export Co. , Ltd.
Thiourea dioxide pictures 2023-09-23 Thiourea dioxide
1758-73-2
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
  • Thiourea dioxide pictures
  • Thiourea dioxide
    1758-73-2
  • US $70.00-60.00 / kg
  • 99%
  • Hebei Dangtong Import and export Co LTD
  • Thiourea dioxide pictures
  • Thiourea dioxide
    1758-73-2
  • US $0.00-0.00 / kg
  • 99%
  • Hebei Yibangte Import and Export Co. , Ltd.
HONGDA GROUP LIMITED LLC Amino(imino) Aminoiminomethanesulfinic acid for synthesis Methanesulfinicacid,aminoimino- AMIDINOSULFINIC ACID AMINOIMINOMETHANESULFINIC ACID THIOUREA DIOXIDE TNFRSF6 PRIMER PAIR THIOUREA DIOXIDE FAS PRIMER PAIR FASTECH Thiourea Dioxide Formamidine Sulphinic Acid Aminoiminomethanesulfinic acid FORMAMIDINESULFINIC ACID, 98+% FORMAMIDINESULFINIC ACID 99% Sulfocarbamide dioxide Aminoiminomethanesulphinic acid Aminoiminomethansulfinsure Formamidine sulfinate 1,1-Diamino-2-thiaethene2,2-dioxide Isothiourea 2,2-dioxide Tiourea dioxide Formamidinesulfinic acid,99% (4189-44-0) thiourea dioxide Methanesulfinic acid, 1-amino-1-imino- FormamidinesulfinicAcid> Thiourea dioxide ISO 9001:2015 REACH aminoimino-methanesulfinicaci AMINOIMINOMETHANESULFINIC ACID FORMAMIDINESULFINIC ACID Thiurea dioxide FORMAMIDINESULPHINIC ACID Thiourea S,S-dioxide Triethylamine hydrochloride 554-68-7 Formamidinesulfinic Acid, ≥ 90.0% 1758-73-2 1758-73-2;4189- NH2CNHSO2H H2NCNHSO2H CH4N2O2S Building Blocks Organic Building Blocks Sulfonic/Sulfinic Acids Sulfur Compounds Building Blocks Chemical Synthesis Organic Building Blocks Sulfonic/Sulfinic Acids Sulfur Compounds Inorganic Chemicals INORGANIC & ORGANIC CHEMICALS 1758-73-2