ChemicalBook >> CAS DataBase List >>N,N-Diphenyl-p-phenylenediamine

N,N-Diphenyl-p-phenylenediamine

CAS No.
74-31-7
Chemical Name:
N,N-Diphenyl-p-phenylenediamine
Synonyms
JZF;DFFD;DPPD;Diafen;antagedp;diafenff;usafgy-2;naugardj;nocracdp;nonflexh
CBNumber:
CB7763021
Molecular Formula:
C18H16N2
Molecular Weight:
260.33
MDL Number:
MFCD00003015
MOL File:
74-31-7.mol
MSDS File:
SDS
Last updated:2024-01-03 13:33:01

N,N-Diphenyl-p-phenylenediamine Properties

Melting point 143-145 °C(lit.)
Boiling point 220-225 °C0.5 mm Hg(lit.)
Density 1.2
refractive index 1.6300 (estimate)
Flash point 220-225°C/1mm
storage temp. Store below +30°C.
solubility DMSO (Slightly), Methanol (Slightly)
form Solid
pka 1.85±0.20(Predicted)
color Pale Grey to Very Dark Grey
Water Solubility <0.1 g/100 mL at 20 ºC
Merck 14,3329
BRN 2215944
Stability Stable. Incompatible with strong acids, strong oxidizing agents
LogP 4.536 (est)
Indirect Additives used in Food Contact Substances N,N'-DIPHENYL-P-PHENYLENEDIAMINE
CAS DataBase Reference 74-31-7(CAS DataBase Reference)
FDA UNII DD517SCM92
NIST Chemistry Reference 1,4-Benzenediamine, N,N'-diphenyl-(74-31-7)
EPA Substance Registry System N,N'-Diphenyl-p-phenylenediamine (74-31-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H317-H412
Precautionary statements  P273-P280-P302+P352
Hazard Codes  Xi
Risk Statements  43-52/53
Safety Statements  24-37-61
WGK Germany  1
RTECS  ST2275000
TSCA  Yes
HS Code  2921 51 90
Toxicity LD50 orally in Rabbit: 2370 mg/kg LD50 dermal Rat 4500 mg/kg
NFPA 704
1
2 0

N,N-Diphenyl-p-phenylenediamine price More Price(38)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.20536 N,N′-Diphenyl-1,4-phenylenediamine for synthesis 74-31-7 250g $132 2024-03-01 Buy
Sigma-Aldrich 8.20536 N,N′-Diphenyl-1,4-phenylenediamine for synthesis 74-31-7 10Kg $1510 2024-03-01 Buy
Sigma-Aldrich 292265 N,N′-Diphenyl-p-phenylenediamine 98% 74-31-7 5g $49.1 2024-03-01 Buy
Sigma-Aldrich 292265 N,N′-Diphenyl-p-phenylenediamine 98% 74-31-7 25g $101.6 2024-03-01 Buy
TCI Chemical D0609 N,N'-Diphenyl-1,4-phenylenediamine >95.0%(T) 74-31-7 25g $47 2024-03-01 Buy
Product number Packaging Price Buy
8.20536 250g $132 Buy
8.20536 10Kg $1510 Buy
292265 5g $49.1 Buy
292265 25g $101.6 Buy
D0609 25g $47 Buy

N,N-Diphenyl-p-phenylenediamine Chemical Properties,Uses,Production

Description

N,N'-Diphenyl-4-phenylenediamine (DPPD) is a rubber accelerant, formerly contained in the "black rubber mix". The most frequent occupational categories are in metal industry, homemakers, health services and laboratories, and building industries.

Chemical Properties

grey powder

Uses

Polymerization inhibitor. Antioxidant for rubber, petroleum oils, feedstuffs.

Uses

N1,N4-Diphenylbenzene-1,4-diamine can be used to prepare low pressure change, high temperature resistant flame retardant silicone rubber.

Uses

N,N'-Diphenyl-4-phenylene diamine is an antioxidant for rubber, petroleum oils, and feed stuffs; stabilizer; a polymerization inhibitor; used to retard copper degradation; as an intermediate for dyes, drugs, plasties and detergents; antidegradant for nitrile-butadiene rubber, natural, styrene-butadiene, isoprene, butadiene, and ehloroprene rubbers.

Definition

ChEBI: An N-substituted diamine that is 1,4-phenylenediamine in which one hydrogen from each amino group is replaced by a phenyl group.

General Description

Gray or dark gray powder or flakes.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

N,N-Diphenyl-p-phenylenediamine may react with oxidizing materials . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Fire Hazard

N,N-Diphenyl-p-phenylenediamine is combustible. N,N-Diphenyl-p-phenylenediamine may form explosive dust-air mixtures.

Contact allergens

A rubber accelerant, formerly contained in “blackrubber mix.” The most frequent occupational categories are in the metal industry, homemakers, health services and laboratories, and the building industry.

Purification Methods

Crystallise the diamine from EtOH, chlorobenzene/pet ether or *benzene. It has also been crystallised from aniline, then extracted three times with absolute EtOH. [Beilstein 13 H 80.]

N,N-Diphenyl-p-phenylenediamine Preparation Products And Raw materials

Global( 228)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12453 58
Henan Fengda Chemical Co., Ltd
+86-371-86557731 +86-13613820652 info@fdachem.com China 7377 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
Chemson Industrial (Shanghai) Co., Ltd.
86-21-65208861- 8007 sales1@chemson.com.cn CHINA 117 58
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9641 58

View Lastest Price from N,N-Diphenyl-p-phenylenediamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
N,N-Diphenyl-p-phenylenediamine pictures 2024-01-04 N,N-Diphenyl-p-phenylenediamine
74-31-7
US $30.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
N,N-Diphenyl-p-phenylenediamine pictures 2023-11-14 N,N-Diphenyl-p-phenylenediamine
74-31-7
US $0.00-0.00 / kg 1kg 99% 50000kg Hebei Yibangte Import and Export Co. , Ltd.
N,N-Diphenyl-p-phenylenediamine pictures 2023-10-14 N,N-Diphenyl-p-phenylenediamine
74-31-7
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Antage DP antagedp antigenep AntioxidantH DFFD Diafen Diafen FF diafenff Diphenyl DPPD Diphenyl phenylene diamine n,n’-diphenyl-p-phenylenediamin DIPHENYL-P-PHENYLENEDIAMINE Antioxidant PPD p-phenylenediphenyldiamine 1,4-DIANILINOBENZENE Antioxidant DPPD N,N'-DIPHENYL-P-PHENYLENEDIAMINE (SYM.) N,N'-DIPHENYL-P-PHENYLENEDIAMINE (SYM.), ANTIOXIDANT 4-AMINO-TRIPHENYLAMINE N,N'-Diphenyl-P-Phenylenediamine~90% N,N'-Diphenyl-p-phenylenediamine, tech. 1,4-Benzenediamine, N,N-diphenyl- NNDIPHENYLPARAPHENYLENEDIAMINE 44DIPHENYLPARAPHENYLENEDIAMINE NNDIPHENYLPHENYLENEDIAMINE DIPHENYL-PARA-PHENYLENEDIAMINE N,N′-Diphenyl-p-phenylendiamin 4-(N,N-Diphenylamino)aniline N-(4-Aminophenyl)-N,N-diphenylamine p-(Diphenylamino)aniline p-Aminotriphenylamine N,N'-(1,4-Phenylene)dianiline N,N'-Diphenyl-p-phenylenediamine,97% Diphenyl PPD DPPD Ekaland DPPD ekalanddppd Flexamine G flexamineg JZF n,n’-difenyl-p-fenylendiamin n,n’-difenyl-p-fenylendiamin(czech) n,n’-diphenyl-4-benzenediamine n,n’-diphenyl-4-phenylenediamine permanax18 permanaxdppd p-Phenylenediamine, N,N'-diphenyl- Stabilizer DPPD stabilizerdppd USAF gy-2 usafgy-2 4-Anilinodiphenylamine N,N'-Diphenyl-p-phenylendiaMine N1,N4-Diphenylbenzene-1,4-diaMine N,N'-diphenyl-p-phenylenediamine N,N'-diphenyl-1,4-benzenediamine N,N'-Diphenyl-1,4-phenylenediamine N,N'-Diphenyl-1,4-phenylenediamine for synthesis P-PHENYLAMINODIPHENYLAMINE