N,N-Diphenyl-p-phenylenediamine
- CAS No.
- 74-31-7
- Chemical Name:
- N,N-Diphenyl-p-phenylenediamine
- Synonyms
- JZF;DFFD;DPPD;Diafen;antagedp;diafenff;usafgy-2;naugardj;nocracdp;nonflexh
- CBNumber:
- CB7763021
- Molecular Formula:
- C18H16N2
- Molecular Weight:
- 260.33
- MDL Number:
- MFCD00003015
- MOL File:
- 74-31-7.mol
- MSDS File:
- SDS
Melting point | 143-145 °C(lit.) |
---|---|
Boiling point | 220-225 °C0.5 mm Hg(lit.) |
Density | 1.2 |
refractive index | 1.6300 (estimate) |
Flash point | 220-225°C/1mm |
storage temp. | Store below +30°C. |
solubility | DMSO (Slightly), Methanol (Slightly) |
form | Solid |
pka | 1.85±0.20(Predicted) |
color | Pale Grey to Very Dark Grey |
Water Solubility | <0.1 g/100 mL at 20 ºC |
Merck | 14,3329 |
BRN | 2215944 |
Stability | Stable. Incompatible with strong acids, strong oxidizing agents |
LogP | 4.536 (est) |
Indirect Additives used in Food Contact Substances | N,N'-DIPHENYL-P-PHENYLENEDIAMINE |
CAS DataBase Reference | 74-31-7(CAS DataBase Reference) |
FDA UNII | DD517SCM92 |
NIST Chemistry Reference | 1,4-Benzenediamine, N,N'-diphenyl-(74-31-7) |
EPA Substance Registry System | N,N'-Diphenyl-p-phenylenediamine (74-31-7) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS07 |
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Signal word | Warning | |||||||||
Hazard statements | H317-H412 | |||||||||
Precautionary statements | P273-P280-P302+P352 | |||||||||
Hazard Codes | Xi | |||||||||
Risk Statements | 43-52/53 | |||||||||
Safety Statements | 24-37-61 | |||||||||
WGK Germany | 1 | |||||||||
RTECS | ST2275000 | |||||||||
TSCA | Yes | |||||||||
HS Code | 2921 51 90 | |||||||||
Toxicity | LD50 orally in Rabbit: 2370 mg/kg LD50 dermal Rat 4500 mg/kg | |||||||||
NFPA 704 |
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N,N-Diphenyl-p-phenylenediamine price More Price(38)
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Sigma-Aldrich | 8.20536 | N,N′-Diphenyl-1,4-phenylenediamine for synthesis | 74-31-7 | 250g | $132 | 2024-03-01 | Buy |
Sigma-Aldrich | 8.20536 | N,N′-Diphenyl-1,4-phenylenediamine for synthesis | 74-31-7 | 10Kg | $1510 | 2024-03-01 | Buy |
Sigma-Aldrich | 292265 | N,N′-Diphenyl-p-phenylenediamine 98% | 74-31-7 | 5g | $49.1 | 2024-03-01 | Buy |
Sigma-Aldrich | 292265 | N,N′-Diphenyl-p-phenylenediamine 98% | 74-31-7 | 25g | $101.6 | 2024-03-01 | Buy |
TCI Chemical | D0609 | N,N'-Diphenyl-1,4-phenylenediamine >95.0%(T) | 74-31-7 | 25g | $47 | 2024-03-01 | Buy |
N,N-Diphenyl-p-phenylenediamine Chemical Properties,Uses,Production
Description
N,N'-Diphenyl-4-phenylenediamine (DPPD) is a rubber accelerant, formerly contained in the "black rubber mix". The most frequent occupational categories are in metal industry, homemakers, health services and laboratories, and building industries.
Chemical Properties
grey powder
Uses
Polymerization inhibitor. Antioxidant for rubber, petroleum oils, feedstuffs.
Uses
N1,N4-Diphenylbenzene-1,4-diamine can be used to prepare low pressure change, high temperature resistant flame retardant silicone rubber.
Uses
N,N'-Diphenyl-4-phenylene diamine is an antioxidant for rubber, petroleum oils, and feed stuffs; stabilizer; a polymerization inhibitor; used to retard copper degradation; as an intermediate for dyes, drugs, plasties and detergents; antidegradant for nitrile-butadiene rubber, natural, styrene-butadiene, isoprene, butadiene, and ehloroprene rubbers.
Definition
ChEBI: An N-substituted diamine that is 1,4-phenylenediamine in which one hydrogen from each amino group is replaced by a phenyl group.
General Description
Gray or dark gray powder or flakes.
Air & Water Reactions
Insoluble in water.
Reactivity Profile
N,N-Diphenyl-p-phenylenediamine may react with oxidizing materials . Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Fire Hazard
N,N-Diphenyl-p-phenylenediamine is combustible. N,N-Diphenyl-p-phenylenediamine may form explosive dust-air mixtures.
Contact allergens
A rubber accelerant, formerly contained in “blackrubber mix.” The most frequent occupational categories are in the metal industry, homemakers, health services and laboratories, and the building industry.
Purification Methods
Crystallise the diamine from EtOH, chlorobenzene/pet ether or *benzene. It has also been crystallised from aniline, then extracted three times with absolute EtOH. [Beilstein 13 H 80.]
N,N-Diphenyl-p-phenylenediamine Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12453 | 58 |
Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7377 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
Chemson Industrial (Shanghai) Co., Ltd. | 86-21-65208861- 8007 | sales1@chemson.com.cn | CHINA | 117 | 58 |
career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
Hubei xin bonus chemical co. LTD | 86-13657291602 | linda@hubeijusheng.com | CHINA | 22968 | 58 |
Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
View Lastest Price from N,N-Diphenyl-p-phenylenediamine manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-01-04 | N,N-Diphenyl-p-phenylenediamine
74-31-7
|
US $30.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2023-11-14 | N,N-Diphenyl-p-phenylenediamine
74-31-7
|
US $0.00-0.00 / kg | 1kg | 99% | 50000kg | Hebei Yibangte Import and Export Co. , Ltd. | ||
2023-10-14 | N,N-Diphenyl-p-phenylenediamine
74-31-7
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd |
- N,N-Diphenyl-p-phenylenediamine
74-31-7
- US $30.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
- N,N-Diphenyl-p-phenylenediamine
74-31-7
- US $0.00-0.00 / kg
- 99%
- Hebei Yibangte Import and Export Co. , Ltd.
- N,N-Diphenyl-p-phenylenediamine
74-31-7
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd