Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>Tetrahydrothiopyran-4-one

Tetrahydrothiopyran-4-one

Tetrahydrothiopyran-4-one Structure
Tetrahydrothiopyran-4-one structure
CAS No.
1072-72-6
Chemical Name:
Tetrahydrothiopyran-4-one
Synonyms
TETRAHYDRO-4H-THIOPYRAN-4-ONE;dihydro-2H-thiopyran-4(3H)-one;4H-Thiopyran-4-one, tetrahydro-;Penthianone;THIAN-4-ONE;4-OXOTHIANE;4-Oxothiane>THIAN-3-ONEOXIME;4-Thiacyclohexanon;4-thiacyclohexanone
CBNumber:
CB8202200
Molecular Formula:
C5H8OS
Molecular Weight:
116.18
MDL Number:
MFCD00006660
MOL File:
1072-72-6.mol
MSDS File:
SDS
Last updated:2023-05-25 18:01:19
Request For Quotation

Tetrahydrothiopyran-4-one Properties

Melting point 60-64 °C (lit.)
Boiling point 140.82°C (estimate)
Density 1.050 (estimate)
refractive index 1.5100 (estimate)
storage temp. Inert atmosphere,Room Temperature
solubility Acetonitrile (Slightly), Chloroform (Slightly)
form Crystalline Solid
color White to pale yellow
BRN 106464
InChIKey OVRJVKCZJCNSOW-UHFFFAOYSA-N
LogP 0.490 (est)
CAS DataBase Reference 1072-72-6(CAS DataBase Reference)
FDA UNII 667X5M356L
NIST Chemistry Reference 4H-Thiopyran-4-one, tetrahydro-(1072-72-6)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319
Precautionary statements  P264-P280i-P305+P351+P338-P337+P313
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  22-24/25
WGK Germany  3
HazardClass  IRRITANT
HS Code  29349990
NFPA 704
1
2 0

Tetrahydrothiopyran-4-one price More Price(39)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 155160 Tetrahydro-4H-thiopyran-4-one 99% 1072-72-6 1g $43.3 2024-03-01 Buy
Sigma-Aldrich 155160 Tetrahydro-4H-thiopyran-4-one 99% 1072-72-6 5g $128 2023-06-20 Buy
TCI Chemical O0112 4-Oxothiane >98.0%(GC) 1072-72-6 5g $68 2024-03-01 Buy
TCI Chemical O0112 4-Oxothiane >98.0%(GC) 1072-72-6 25g $218 2024-03-01 Buy
Alfa Aesar A15872 Tetrahydro-4H-thiopyran-4-one, 99% 1072-72-6 1g $39.65 2024-03-01 Buy
Product number Packaging Price Buy
155160 1g $43.3 Buy
155160 5g $128 Buy
O0112 5g $68 Buy
O0112 25g $218 Buy
A15872 1g $39.65 Buy

Tetrahydrothiopyran-4-one Chemical Properties,Uses,Production

Chemical Properties

WHITE TO PALE YELLOW CRYSTALLINE SOLID

Uses

Tetrahydro-?4H-?thiopyran-?4-?one is a cyclic carbonyl compound used as a reactant in the stereoselective preparation of [aryl(nitro)ethyl] carbonyl compounds via asymmetric Michael addition to nitroolefins catalyzed by chiral pyrrolidine-pyridine conjugate bases.

General Description

The diastereoselectivity of the aldol reaction of tetrahydro-4H-thiopyran-4-one has been studied.

Purification Methods

Purify it by recrystallisation from diisopropyl ether or pet ether and dry it in air. If too impure, then dissolve it in Et2O, wash with aqueous NaHCO3, then H2O, dry (MgSO4), filter, evaporate and the residue is recrystallised as before. [Cardwell J Chem Soc 715 1949.] The oxime can be recrystallised from CHCl3/pet ether (at -20o) and has m 84-85o [Barkenbus et al. J Org Chem 20 871 1955]. The 2,4-dinitrophenylhydrazone has m 186o (from EtOAc) [Barkenbus et al. J Org Chem 16 232 1951]. The S-dioxide is recrystallised from AcOH, m 173-174o [Fehnel & Carmack J Am Chem Soc 70 1813 1948, Beilstein 17 II 287, 17 III/IV 4172, 17/1 V 21].

Tetrahydrothiopyran-4-one synthesis

111-17-1
1072-72-6
Synthesis of Tetrahydrothiopyran-4-one from 3,3'-Thiodipropionic acid

Tetrahydrothiopyran-4-one Preparation Products And Raw materials

Raw materials

Propanoic acid, 3,3'-thiobis-, di-2-propenyl ester (9CI) 4H-Thiopyran-4-one, 2,3-dihydro- 2H-Thiopyran, 3,6-dihydro-4-[(trimethylsilyl)oxy]- 1,4-dioxa-8-thiaspiro<4.5>decane-6-carboxaldehyde Thian-4-one S-oxide
METHYL TETRAHYDRO-4-OXO-2H-THIOPYRAN-3-CARBOXYLATE TETRAHYDROTHIOPYRAN-4-OL 97 Dimethyl 3,3'-thiodipropanoate 1,5-DIBROMO-PENTAN-3-ONE diethyl 3,3'-thiobispropionate
PIPERIDINIUM, 1,1-DIMETHYL-4-OXO-, IODIDE 3,3'-Thiodipropionic acid

1of3

Preparation Products

Tetrahydrothiopyran-4-one oxiMe 4-Aminotetrahydrothiopyran-4-carbonitrile Thiopyrano[4,3-c]pyrazole, 1,4,6,7-tetrahydro- N-methyltetrahydro-2H-thiopyran-4-amine(SALTDATA: HCl)

Tetrahydrothiopyran-4-one Suppliers

Global( 309)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Beijing Cooperate Pharmaceutical Co.,Ltd 		010-60279497 sales01@cooperate-pharm.com CHINA 1811 55
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3012 60
Shanghai Yingrui Biopharma Co., Ltd. 		+86-21-33585366 - 03@ sales03@shyrchem.com CHINA 738 60
ATK CHEMICAL COMPANY LIMITED 		+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Zjartschem 		+86-571-8723 8903 jocelynpan@zjarts.com jocelynpan@zjarts.com CHINA 993 58
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
HaBo Hong Kong Co., Limited. 		+86-25-18512596065 info@habotech.com CHINA 933 58
Accela ChemBio Inc. 		(+1)-858-699-3322 info@accelachem.com United States 19965 58
Supplier Advantage
Capot Chemical Co.,Ltd. 		60
Beijing Cooperate Pharmaceutical Co.,Ltd 		55
Henan Tianfu Chemical Co.,Ltd. 		55
Nanjing ChemLin Chemical Industry Co., Ltd. 		60
Shanghai Yingrui Biopharma Co., Ltd. 		60
ATK CHEMICAL COMPANY LIMITED 		60
Zjartschem 		58
career henan chemical co 		58
HaBo Hong Kong Co., Limited. 		58
Accela ChemBio Inc. 		58

View Lastest Price from Tetrahydrothiopyran-4-one manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tetrahydrothiopyran-4-one pictures 2022-10-09 Tetrahydrothiopyran-4-one
1072-72-6
 US $0.00-0.00 / KG 1KG 98% 1Ton Henan Aochuang Chemical Co.,Ltd.
Tetrahydrothiopyran-4-one pictures 2021-10-29 Tetrahydrothiopyran-4-one
1072-72-6
 US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
Tetrahydrothiopyran-4-one pictures 2019-07-06 Tetrahydrothiopyran-4-one
1072-72-6
 US $1.00 / KG 1KG 99% 20kg Career Henan Chemical Co

Tetrahydrothiopyran-4-one Spectrum

Tetrahydrothiopyran-4-one(1072-72-6)MSTetrahydrothiopyran-4-one(1072-72-6)1HNMRTetrahydrothiopyran-4-one(1072-72-6)13CNMRTetrahydrothiopyran-4-one(1072-72-6)IR1Tetrahydrothiopyran-4-one(1072-72-6)IR2Tetrahydrothiopyran-4-one(1072-72-6)Raman

1072-72-6(Tetrahydrothiopyran-4-one )Related Search:

Tetrahydrothiopyran-4-one 1,1-dioxide,Tetrahydrothiopyran-4-one S,S-dioxide Tetrahydrothiophen-3-one Buprofezin Hydrochlorothiazide Tetrahydro-2H-thiopyran-4-amine
Tetrahydro-4H-pyran-4-one TETRAHYDROTHIOPYRAN-4-OL 97 Tetrahydrocurcumin L-Tetrahydrofolic Acid Tetrahydrothiopyran-4-carbaldehyde
Tetrahydrofurfuryl alcohol TETRAHYDRO-THIOPHEN-3-OL Tetrahydrothiophene Tetrahydropyranyl-4-acetic acid (TETRAHYDRO-PYRAN-4-YL)-ACETALDEHYDE
2H-Thiopyran-4-methanol, tetrahydro- 2-Thiophenecarboxylic acid, tetrahydro- 2-(TETRAHYDRO-2H-PYRAN-4-YL)ACETAMIDE

1of4

1-Thiacyclohexan-4-one 2,3,5,6-Tetrahydro-4-thiopyranone 4H-tetrahydrothiopyran-4-one 4-Oxotetrahydrothiopyran Penthianone Tetrahydro-1,4-thiapyrone Tetrahydro-1-thio-4-pyrone Tetrahydro-1-thio-gamma-pyrone Tetrahydro-4H-thiapyran-4-one Tetrahydro-4-thiopyrone Tetrahydrothia-4-pyranone Tetrahydrothiopyranone TETRAHYDROTHIOPYRAN-4-ONE TETRAHYDRO-2H-THIOPYRAN-4-ONE THIAN-4-ONE 4-thiacyclohexanone 4-OXOTHIANE THIAN-3-ONEOXIME 2,3,5,6-Tetrahydro-4H-thiopyran-4-one Tetrahydrothiopyran-4-one,99% Tetrahydrothiopyran-4-one ,98% Tetrahydro-4H-thiopyran-4... Tetrahydrothiapyran-4-one Tetrahydrothiopyran-4-one, 99% 5GR Thian-4-one, 4-Oxotetrahydro-2H-thiopyran Tetrahydro-4H-thiopyran-4-one 99% Tetrahydro-4H-thiopyran-4-one, 99%, 99% 4-tetrahydrothiopyranone 4H-Thiopyran-4-one, tetrahydro- (8CI)(9CI) Tetrahydrothian-4-one 4-Thiacyclohexanon 4-Oxothiane> Tetrahydrothiopyran-4-one ISO 9001：2015 REACH TETRAHYDRO-4H-THIOPYRAN-4-ONE 4H-Thiopyran-4-one, tetrahydro- dihydro-2H-thiopyran-4(3H)-one 1072-72-6 C5H8OS C5H14OS Building Blocks S-Containing Others Heterocyclic Building Blocks Building Blocks Chemical Synthesis Heterocyclic Building Blocks Ring Systems Heterocyclic Building Blocks Others S-Containing