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Dibenzyl sulphide

CAS No.
538-74-9
Chemical Name:
Dibenzyl sulphide
Synonyms
BENZYLSULFID;Benzy Sulfide;BENZYL SULFIDE;BENZYLSULPHIDE;dibenzylsulfane;Dibenzyl sulfid;benzylthioether;DIBENZYL SULFIDE;Benzyl thioether;Sulfide, benzyl-
CBNumber:
CB8319302
Molecular Formula:
C14H14S
Molecular Weight:
214.33
MDL Number:
MFCD00004784
MOL File:
538-74-9.mol
MSDS File:
SDS
Last updated:2023-05-25 18:01:19

Dibenzyl sulphide Properties

Melting point 44-47 °C (lit.)
Boiling point 131 °C / 2mmHg
Density 1.0880
refractive index 1.6170 (estimate)
Flash point >110°C
storage temp. 0-10°C
form Crystals
color White
Water Solubility <0.1 g/100 mL at 21 ºC
Merck 14,1145
BRN 1911157
Stability Stable. Combustible. Incompatible with strong oxidizing agents.
LogP 3.169 (est)
CAS DataBase Reference 538-74-9(CAS DataBase Reference)
FDA UNII Q08048624M
NIST Chemistry Reference Benzene, 1,1'-[thiobis(methylene)]bis-(538-74-9)
EPA Substance Registry System Dibenzyl sulfide (538-74-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H335-H315
Precautionary statements  P280-P305+P351+P338-P321
Safety Statements  22-24/25
RIDADR  UN 3335
WGK Germany  2
RTECS  DC0512500
13
TSCA  Yes
HS Code  29309090
Toxicity LD50 orl-rat: >2 g/kg ATDAEI 15(Suppl 1),S89,1996
NFPA 704
1
1 0

Dibenzyl sulphide price More Price(15)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 33820 Dibenzyl sulfide ≥95.0% (HPLC) 538-74-9 100g $108 2024-03-01 Buy
TCI Chemical B0440 Benzyl Sulfide >98.0%(GC) 538-74-9 25g $33 2024-03-01 Buy
Alfa Aesar B22337 Dibenzyl sulfide, 99% 538-74-9 25g $28.1 2021-12-16 Buy
Alfa Aesar B22337 Dibenzyl sulfide, 99% 538-74-9 100g $60.3 2021-12-16 Buy
Frontier Specialty Chemicals JK385275 Benzyl Sulfide 98% 538-74-9 100g $69 2021-12-16 Buy
Product number Packaging Price Buy
33820 100g $108 Buy
B0440 25g $33 Buy
B22337 25g $28.1 Buy
B22337 100g $60.3 Buy
JK385275 100g $69 Buy

Dibenzyl sulphide Chemical Properties,Uses,Production

Chemical Properties

beige crystals or powder with an unpleasant smell

Uses

Organic synthesis.

Synthesis Reference(s)

Canadian Journal of Chemistry, 53, p. 1480, 1975 DOI: 10.1139/v75-205
Tetrahedron Letters, 27, p. 1073, 1986 DOI: 10.1016/S0040-4039(86)80051-X

General Description

Colorless plates or pale beige crystalline solid with a crippling stench .

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Organosulfides, such as Dibenzyl sulphide, are incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Many of these compounds may liberate hydrogen sulfide upon decomposition or reaction with an acid.

Fire Hazard

Dibenzyl sulphide is combustible.

Safety Profile

Moderately toxic by ingestion.When heated to decomposition it emits toxic vapors ofSOx.

Purification Methods

Crystallise the sulfide from EtOH/water (10:1), or repeatedly from Et2O. It has also been purified by chromatography on Al2O3 (pentane as eluent), then recrystallised from EtOH [Kice & Bowers J Am Chem Soc 84 2390 1962]. Dry it in a vacuum at 30o over P2O5, fused under nitrogen and re-dried. [Beilstein 6 IV 2649.]

Dibenzyl sulphide Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 185)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
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View Lastest Price from Dibenzyl sulphide manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
benzylsulfide pictures 2023-02-13 benzylsulfide
538-74-9
US $10.00 / KG 1KG 99% 50MT Hebei baicao biology science and technology co., ltd
Dibenzyl sulfide  pictures 2020-02-26 Dibenzyl sulfide
538-74-9
US $0.00-0.00 / KG 100g 99.0%+ 100 tons Shaanxi Dideu Medichem Co. Ltd
benzylsulfide pictures 2019-07-11 benzylsulfide
538-74-9
US $3.00 / KG 1KG 99 100kg Career Henan Chemical Co
  • benzylsulfide pictures
  • benzylsulfide
    538-74-9
  • US $10.00 / KG
  • 99%
  • Hebei baicao biology science and technology co., ltd
BENZYLSULFID BENZYL SULFIDE DIBENZYL SULFIDE DIBENZYL SULPHIDE Benzene, 1,1'-[thiobis(methylene)]bis- Benzyl sulfide, 98% 100GR Dibenzyl sulfid BENZYLSULPHIDE dibenzylsulfane Thiobis(methylene)bis(benzene) Benzy Sulfide Benzyl sulfide,98% Benzyl monosulfide Benzyl thioether benzylmonosulfide benzylthioether Dibenzyl monosulfide dibenzylmonosulfide dibenzylthioether Sulfide, benzyl- sulfide,dibenzyl [(Benzylsulfanyl)methyl]benzene 1,1’-(thiobis(methylene))bis-benzen 1,1’-(thiobis(methylene))bisbenzene 1,1’-[thiobis(methylene)]bis-benzen 1,1’-thiobis(methylene)bis-Benzene 1,3-Diphenyl-2-thiapropane Benzyl Sulfide > Dibenzyl sulphide USP/EP/BP 538-74-9 C6H5CH22S C14H14S Building Blocks Sulfides/Disulfides Sulfur Compounds Organic Building Blocks sulfide Flavor