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Carbonylchlorohydrotris(triphenylphosphine)ruthenium

CAS No.
16971-33-8
Chemical Name:
Carbonylchlorohydrotris(triphenylphosphine)ruthenium
Synonyms
RuHCl(CO)(PPh3)3;Carbonylchlorohydridotris(triphenylphosphine)ruthenium;Ru(CO)ClH(PPh3)3;mer-RuH(PPh3)3(CO)Cl;carbonylchlorohydridotris(triphenyl-phosphine)rut;Carbonylchlorohydrido tris (triphenylphosphine) ru;carbonylchlorohydrotris(triphenylphosphine)ruthenium;Carbonylchlorohydrotris(triphen-ylphosphineruthenium(Ⅱ);Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium;Carbonylchlorohydrotris(triphenylphosphine)ruthenium(II)
CBNumber:
CB8487823
Molecular Formula:
C55H45ClOP3Ru
Molecular Weight:
951.39
MDL Number:
MFCD31942895
MOL File:
16971-33-8.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

Carbonylchlorohydrotris(triphenylphosphine)ruthenium Properties

Melting point 204-206 °C (dec.)(lit.)
Boiling point approximate 360℃
storage temp. Keep in dark place,Inert atmosphere,Room temperature
form Powder
color Cream to tan
Water Solubility insoluble
Sensitive Air stable, light sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302+H312+H332-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352+P312-P304+P340+P312-P305+P351+P338
Hazard Codes  Xn,T
Risk Statements  20/21/22-36/37/38
Safety Statements  26-37/39-36/37/39-22
WGK Germany  3
HS Code  29310099
NFPA 704
1
2 1

Carbonylchlorohydrotris(triphenylphosphine)ruthenium price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 334995 Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) 16971-33-8 1g $133 2024-03-01 Buy
Sigma-Aldrich 334995 Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) 16971-33-8 5g $383 2024-03-01 Buy
Alfa Aesar 044955 Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) 16971-33-8 1g $93.65 2024-03-01 Buy
Alfa Aesar 044955 Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) 16971-33-8 5g $417 2024-03-01 Buy
Strem Chemicals 44-0085 Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II), 99% 16971-33-8 1g $82 2024-03-01 Buy
Product number Packaging Price Buy
334995 1g $133 Buy
334995 5g $383 Buy
044955 1g $93.65 Buy
044955 5g $417 Buy
44-0085 1g $82 Buy

Carbonylchlorohydrotris(triphenylphosphine)ruthenium Chemical Properties,Uses,Production

Reaction

  1. Catalyst for alcohol α-allylation with dienes or allenes under transfer hydrogenation conditions.
  2. Catalyst for tandem isomerization (to imine), followed by Friedel Crafts alkylation.
  3. Catalyst for amination of alcohols with ammonia.
Reactions of 16971-33-8

Chemical Properties

pale yellow crystals

Uses

Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II) is used as a raw material to synthesize other ru-hydride catalysts. It is involved in the hydrogenation of ring-opening metathesis polymers such as norbornene and other cyclic olefin ROMP polymers used as plastics, resins and optical materials. It can act as an alternative catalyst to rhodium hydrogenation catalyst. It also serves as a catalyst in the hydrogenation of conjugated diene copolymers like acrylonitrile-butadiene rubber (NBR).

Carbonylchlorohydrotris(triphenylphosphine)ruthenium Preparation Products And Raw materials

Raw materials

Preparation Products

Carbonylchlorohydrotris(triphenylphosphine)ruthenium Suppliers

Global( 160)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 12333 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17368 58
Shanghai Daeyeon Chemicals Co., Ltd
021-64478606 +8615900664856 daeyeon001@vip.163.com China 2062 58
Shanghai Bosheng Metal Materials Co. LTD
18601346310 CHINA 153 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58

View Lastest Price from Carbonylchlorohydrotris(triphenylphosphine)ruthenium manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Carbonylchlorohydrotris(triphenylphosphine)ruthenium pictures 2019-07-06 Carbonylchlorohydrotris(triphenylphosphine)ruthenium
16971-33-8
US $1.00 / KG 1KG 99% 200kg Career Henan Chemical Co

Carbonylchlorohydrotris(triphenylphosphine)ruthenium Spectrum

CARBONYLCHLOROHYDRIDOTRIS(TRIPHENYLPHOSPHINE)RUTHENIUM (II) carbonylchlorohydridotris(triphenyl-phosphine)rut carbonylchlorohydrotris(triphenylphosphine)ruthenium Hydridochlorocarbonyltris-(triphenylphosphino)-ruthenium Carbonylchlorohydridotris(triphenylphosphine)ruthenium(II),99% Carbonylchlorohydrido tris (triphenylphosphine) ru Carbonylchlorohydridotris(triphenylphosphine)rutheniuM(II),98% (PPh3)3(CO)HRuCl Ru(CO)ClH(PPh3)3 mer-RuH(PPh3)3(CO)Cl Carbonylchlorohydridotris(triphenylphosphine)ruthenium(Ⅱ) Carbonylchlorohydrotris(triphenylphosphine)ruthenium(II) Carbonylchlorohydrotris(triphenylphosphine)ruthenium ISO 9001:2015 REACH 16971-33-8 Carbonylchlorohydrotris(triphenylphosphine)ruthenium Carbonylchlorohydridotris(triphenylphosphine)ruthenium RuHCl(CO)(PPh3)3 Carbonylchlorohydridotris(triphenylphosphine)ruthenium(Il) Carbonylchlorohydrotris(triphen-ylphosphineruthenium(Ⅱ) [carbonylchlorohydridotris(triphenylphosphane)ruthenium(II)] 16971-33-8 C55H47ClOP3Ru C55H45ClOP3Ru RuCOClHPC6H533 C6H53P3RuCOClH C55H46ClOP3Ru Ru Catalysts Catalysis and Inorganic Chemistry Ru metal carbonyl complex Ru Catalysts Ruthenium Catalysis and Inorganic Chemistry