ChemicalBook >> CAS DataBase List >>Allyl acetate

Allyl acetate

CAS No.
591-87-7
Chemical Name:
Allyl acetate
Synonyms
2-Propenyl acetate;ALLYL ACETATE;acetated’allyle;AllylAcetate99%;3-Acetoxypropene;PROPENYL ACETATE;Allyl acetate 99%;Allyl Acetate >3-acetoxy-1-propene;Allyl acetate, 98%+
CBNumber:
CB8746311
Molecular Formula:
C5H8O2
Molecular Weight:
100.12
MDL Number:
MFCD00008721
MOL File:
591-87-7.mol
MSDS File:
SDS
Last updated:2023-11-23 20:02:38

Allyl acetate Properties

Melting point 6°C
Boiling point 103-104 °C (lit.)
Density 0.928 g/mL at 25 °C (lit.)
vapor pressure 27.2 hPa (20 °C)
refractive index n20/D 1.404(lit.)
Flash point 44 °F
storage temp. 2-8°C
solubility 28g/l
form Liquid
color Clear colorless
Specific Gravity 0.928
explosive limit 2.1-13.0%(V)
Water Solubility slightly
Merck 14,285
BRN 1742050
LogP 0.970
CAS DataBase Reference 591-87-7(CAS DataBase Reference)
FDA UNII E4U5E5990I
NIST Chemistry Reference Acetic acid, 2-propenyl ester(591-87-7)
EPA Substance Registry System Acetic acid, 2-propen-1-yl ester (591-87-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS06
Signal word  Danger
Hazard statements  H225-H301-H312-H319-H330
Precautionary statements  P210-P280-P301+P310+P330-P302+P352+P312-P304+P340+P310-P305+P351+P338
Hazard Codes  F,T
Risk Statements  11-21-23/25-36-25
Safety Statements  16-26-36-45-27
RIDADR  UN 2333 3/PG 2
WGK Germany  3
RTECS  AF1750000
Autoignition Temperature 705 °F
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29153990
Toxicity LD50: 0.13 g/kg orally in rats; 1.1 ml/kg dermally in rabbits (Smyth); LD50 in rats, mice (mg/kg): 142, 170 orally (Jenner)
NFPA 704
3
3 0

Allyl acetate price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.20554 Allyl acetate for synthesis 591-87-7 100mL $129 2024-03-01 Buy
Sigma-Aldrich 8.20554 Allyl acetate for synthesis 591-87-7 500mL $591 2024-03-01 Buy
Sigma-Aldrich 185248 Allyl acetate 99% 591-87-7 100ml $63.2 2024-03-01 Buy
Sigma-Aldrich 185248 Allyl acetate 99% 591-87-7 500ml $126.6 2024-03-01 Buy
TCI Chemical A0020 Allyl Acetate >98.0%(GC) 591-87-7 25mL $46 2024-03-01 Buy
Product number Packaging Price Buy
8.20554 100mL $129 Buy
8.20554 500mL $591 Buy
185248 100ml $63.2 Buy
185248 500ml $126.6 Buy
A0020 25mL $46 Buy

Allyl acetate Chemical Properties,Uses,Production

Chemical Properties

Allyl acetate is a flammable, colorless liquid with an acrid odor.

Uses

Ally acetate is used in industrial intermediate. Used in synthesis of colophony and bond.

Uses

Ally acetate is used in nonalcoholic beverages at 1 ppm, ice cream and ices at 2 ppm, candy at 5 ppm, baked goods at 5 ppm, and margarine at 2 ppm.

Production Methods

Allyl acetate is produced by the following methods: decarboxylation of allylmalonic acid with heat, boiling ethyl 4- chloro-N-valerate in quinoline, and acetoxylation of propylene.
Allyl acetate is produced primarily for manufacturing allyl alcohol. It is also used as a synthetic flavoring for cheese, butter, and fruit.

General Description

A liquid. Insoluble in water and slightly less dense than water. Hence floats on water. Flash point below 75°F. Poisonous by ingestion and moderately toxic by inhalation and skin contact. Irritating to skin and eyes.

Air & Water Reactions

Highly flammable. Insoluble in water.

Reactivity Profile

Allyl acetate is an ester. Reacts with acids to liberate heat along with alcohols and acids. Generates heat with strong oxidizing acids. The reaction may be sufficiently exothermic to ignite the reaction products. Also generates heat with basic solutions. Generates flammable hydrogen with alkali metals and hydrides. Emits acrid smoke and irritating fumes when heated to decomposition.

Hazard

Skin and eye irritant; poisonous.

Health Hazard

TOXIC; may be fatal if inhaled, ingested or absorbed through skin. Inhalation or contact with some of these materials will irritate or burn skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.

Fire Hazard

HIGHLY FLAMMABLE: Will be easily ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion and poison hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.

Safety Profile

Poison by ingestion. Moderately toxic by inhalation and skin contact. A skin and eye irritant. When heated to decomposition it emits acrid smoke and irritating fumes. Dangerous fire hazard. See also ALLYL COMPOUNDS

Potential Exposure

Allyl Acetate is used to control insects in homes and animal shelters, and to treat lice in humans. May be used to enhance taste of dairy products and fruit. Generally speaking, most allyl compounds may be metabolized to allyl alcohol (see A:0540) which is metabolized to acrolein (see A:0380).

Shipping

UN2333 Allyl acetate, Hazard Class: 3; Labels: 3-Flammable liquid, 6.1-Poisonous materials

Purification Methods

The ester is freed from peroxides by standing with crystalline ferrous ammonium sulfate, then washed with 5% NaHCO3, followed by saturated CaCl2 solution. Dry it with Na2SO4 and fractionally distil it in an all-glass apparatus. FLAMMABLE LIQUID. [Beilstein 2 H 136, 2 IV 180.]

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides. Incompatible with strong acids (liberates heat), nitrates, strong alkalis (liberates heat). Contact with alkali metals and strong reducing agents such as hydrides evolves highly flammable hydrogen gas. Attacks some plastics, coatings, and rubber. Flow or agitation of substance may generate electrostatic charges due to low conductivity; ground all equipment containing this material

Waste Disposal

Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.

75-36-5
107-18-6
591-87-7
Synthesis of Allyl acetate from Acetyl chloride and Allyl alcohol
Global( 203)Suppliers
Supplier Tel Email Country ProdList Advantage
Zouping mingyuan import & export trading co., ltd
+86-0543-2240078 +8618364991597 myzhao793@163.com China 994 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12452 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5990 58
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9354 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58

View Lastest Price from Allyl acetate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Allyl acetate pictures 2023-11-24 Allyl acetate
591-87-7
US $30.00-10.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
Allyl acetate pictures 2023-09-06 Allyl acetate
591-87-7
US $30.00-10.00 / KG 50KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
Allyl acetate pictures 2023-07-27 Allyl acetate
591-87-7
US $1.50 / g 1g 99.0% Min 100 Tons Shaanxi Didu New Materials Co. Ltd
  • Allyl acetate pictures
  • Allyl acetate
    591-87-7
  • US $30.00-10.00 / kg
  • 0.99
  • Hebei Yanxi Chemical Co., Ltd.
  • Allyl acetate pictures
  • Allyl acetate
    591-87-7
  • US $30.00-10.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
  • Allyl acetate pictures
  • Allyl acetate
    591-87-7
  • US $1.50 / g
  • 99.0% Min
  • Shaanxi Didu New Materials Co. Ltd
2-Propenyl ester of acetic acid 2-propenylmethanoate 3-acetoxy-1-propene liquid-solid phase transfer Allyl acetate, 99% 100ML 2-Propen-1-ol acetate Allyl acetate 99% Allyl acetate, 98%+ Chloro allyl acetate 3-Acetoxypropene 2-Propenyl ethanoate ALLYL ACETATE ACETIC ACID ALLYL ESTER acetated’allyle Aceticacid,2-propenylester aceticacidprop-2-enylester CH2=C(CH3)OC(=O)CH3 PROPENYL ACETATE AllylAcetate99% ALLYL ACETATE EP (ACETIC ACID ALLYL ESTER) Allyl Acetate > ALLYL ACETATE FOR SYNTHESIS 100 ML Acetic acid, 2-propen-1-yl ester prop-2-enyl acetate 2-Propenyl acetate Cabergoline Impurity 24 591-87-7 CH3CO2CH2CHCH2 CH3COOCH2CHCH2 CH3COOC3H5 591877 ALKYNE Carbonyl Compounds C2 to C5 Building Blocks Organic Building Blocks Esters Allyl Monomers Monomers Polymer Science