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ChemicalBook >> CAS DataBase List >>2,4,6-TRINITROANILINE

2,4,6-TRINITROANILINE

2,4,6-TRINITROANILINE Structure
2,4,6-TRINITROANILINE structure
CAS No.
489-98-5
Chemical Name:
2,4,6-TRINITROANILINE
Synonyms
TNA;MATB;CLEC3B;PICRAMIDE;Picramide, MATB;Picramide TNA MATB;2,4,6-TRINITROANILINE;2,4,6-Trinitrobenzenamine;Benzenamine,2,4,6-trinitro-;(2,4,6-trinitrophenyl)amine
CBNumber:
CB8850553
Molecular Formula:
C6H4N4O6
Molecular Weight:
228.12
MDL Number:
MFCD00007149
MOL File:
489-98-5.mol
Last updated:2023-10-21 09:08:48

2,4,6-TRINITROANILINE Properties

Melting point 193.5°C
Boiling point 369.91°C (rough estimate)
Density 1.7620
refractive index 1.6700 (estimate)
storage temp. -20°C
pka pK1:-10.23(+1) (25°C)
Water Solubility 19.87mg/L(25 ºC)
FDA UNII ZL7CZQ6FZC
EPA Substance Registry System 2,4,6-Trinitroaniline (489-98-5)

SAFETY

Risk and Safety Statements

Hazard Codes  O,T
Risk Statements  49-8-23/24/25-34
Safety Statements  53-17-23-36/37/39-45
RIDADR  0153
HazardClass  1.1D
PackingGroup  II

2,4,6-TRINITROANILINE Chemical Properties,Uses,Production

Uses

Explosive compositions.

Production Methods

Picric acid is converted to 2,4,6-trinitrochlorobenzene by treatment with PCl5, or a similar chlorinating agent; this is then aminated under mild reaction conditions.

General Description

Yellow monoclinic crystals.

Air & Water Reactions

Insoluble in water.

Reactivity Profile

Explosive by heat or shock. 2,4,6-TRINITROANILINE is an aromatic nitrate. Aromatic nitrates range from slight to strong oxidizing agents. If mixed with reducing agents, including hydrides, sulfides and nitrides, they may begin a vigorous reaction that culminates in a detonation. The aromatic nitro compounds may explode in the presence of a base such as sodium hydroxide or potassium hydroxide even in the presence of water or organic solvents. The explosive tendencies of aromatic nitro compounds are increased by the presence of multiple nitro groups.

Hazard

Dangerous, explodes by heat or shock.

Fire Hazard

Flash point data for 2,4,6-TRINITROANILINE are not available. 2,4,6-TRINITROANILINE is probably combustible.

Safety Profile

An explosive. When heated to decomposition it emits toxic vapors of NOx.

2,4,6-TRINITROANILINE synthesis

88-89-1
489-98-5
Synthesis of 2,4,6-TRINITROANILINE from PICRIC ACID

2,4,6-TRINITROANILINE Preparation Products And Raw materials

Raw materials

AMMONIUM 2,4,6-TRINITROPHENOLATE Benzenamine, N-butyl-2,4,6-trinitro- 4,6-DINITROBENZOFUROXANE 2'-NITROACETANILIDE 1,3,5-TRINITROBENZENE
2,4,6-TRINITROCHLOROBENZENE Methyl picrate Triphenylphosphine oxide Cyanuric acid

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Preparation Products

3,5-Dinitro-2-picramidylpyridine 1,2,3,5-Tetranitrobenzene 1,2,3,4,5,6-Benzenehexamine-3HCl

2,4,6-TRINITROANILINE Spectrum

2,4,6-TRINITROANILINE(489-98-5)MS2,4,6-TRINITROANILINE(489-98-5)IR12,4,6-TRINITROANILINE(489-98-5)IR2

489-98-5(2,4,6-TRINITROANILINE)Related Search:

2,2-diphenyl-1-picrylhydrazyl 2,2-DI(4-TERT-OCTYLPHENYL)-1-PICRYL-HYDRAZYL, FREE RADICAL 2,4,6-TRINITROANILINE HexanitrodiphenylaMine 1,1-DIPHENYL-2-PICRYLHYDRAZINE
N,N-dimethyl-2,4,6-trinitroaniline 4'-NITRO-5'-(PICRYLAMINO)BENZO-18-CROWN-6 AURANTIA 1,3,5-triazido-2,4,6-trinitrobenzene DIPICRYLAMINE SODIUM SALT
2,4,5-TRINITROANILINE TNP-L-ALANINE TNP-L-ASPARTIC ACID 2,4,6-TRINITRO-2'-METHYLDIPHENYLAMINE TNP-L-GLUTAMIC ACID
TNP-ALPHA-AMINOBUTYRIC ACID TNP-BETA-ALANINE TNP-GAMMA-AMINOBUTYRIC ACID

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PICRAMIDE TNA 2,4,6-TRINITROANILINE MATB 1-Amino-2,4,6-trinitrobenzene 2,4,6-Trinitrobenzenamine Picramide, MATB (2,4,6-trinitrophenyl)amine 2,4,6-Trinitroaniline solution CLEC3B Benzenamine,2,4,6-trinitro- Picramide TNA MATB 2,4,6-trinitroaniline {= TNA} Recombinant Human CLEC3B Protein, His Tag ANTI-CLEC3B (CENTER) antibody produced in rabbit 489-98-5 NO23C6H2NH2 C6H4N4O6 O2N3C6H2NH2