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Diethyl 1,1-cyclopropanedicarboxylate

Diethyl 1,1-cyclopropanedicarboxylate structure

CAS No.: 1559-02-0

Chemical Name:: Diethyl 1,1-cyclopropanedicarboxylate

Synonyms: DIETHYL CYCLOPROPANE-1,1-DICARBOXYLATE;1,1-CYCLOPROPANEDICARBOXYLIC ACID DIETHYL ESTER;Diethyl 1;NSC 21376;RARECHEM AL BO 0836;opropane-1,1-dicarboxyL;DiethyldifluoroMalonate96%;1-Cyclopropanedicarboxylate;1,1-Dicarbethoxycyclopropane;Ethyl 1,1-cyclopropanedicarboxylate

CBNumber:: CB8853145

Molecular Formula:: C9H14O4

Molecular Weight:: 186.21

MDL Number:: MFCD00001283

MOL File:: 1559-02-0.mol

Last updated:2023-10-16 17:43:51

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Diethyl 1,1-cyclopropanedicarboxylate Properties

Melting point	134-136 °C(lit.)
Boiling point	94-96 °C/10 mmHg (lit.)
Density	1.055 g/mL at 25 °C (lit.)
refractive index	n20/D 1.433(lit.)
Flash point	188 °F
storage temp.	Sealed in dry,Room Temperature
solubility	Acetone (Slightly), Chlorform (Slightly), Methanol (Slightly)
form	Liquid
color	Clear colorless
BRN	2049509
CAS DataBase Reference	1559-02-0(CAS DataBase Reference)
FDA UNII	D56NXJ5UMC
NIST Chemistry Reference	Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H227

Precautionary statements

P210-P280-P370+P378-P403+P235-P501-P210e-P280a-P370+P378a-P501a

Hazard Codes

Risk Statements

36/37/38

Safety Statements

26-36-24/25-23

RIDADR

UN 3261 8/PG 2

WGK Germany

HazardClass

IRRITANT

HS Code

29172090

NFPA 704

	2
1		0

Diethyl 1,1-cyclopropanedicarboxylate price More Price(34)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	147710	Diethyl cyclopropane-1,1-dicarboxylate 97%	1559-02-0	5g	$103	2023-06-20	Buy
Sigma-Aldrich	147710	Diethyl cyclopropane-1,1-dicarboxylate 97%	1559-02-0	25g	$381	2023-06-20	Buy
TCI Chemical	C1341	Diethyl 1,1-Cyclopropanedicarboxylate >96.0%(GC)	1559-02-0	5g	$16	2024-03-01	Buy
TCI Chemical	C1341	Diethyl 1,1-Cyclopropanedicarboxylate >96.0%(GC)	1559-02-0	25g	$37	2024-03-01	Buy
Alfa Aesar	H56568	Diethyl cyclopropane-1,1-dicarboxylate	1559-02-0	1g	$27.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
147710	5g	$103	Buy
147710	25g	$381	Buy
C1341	5g	$16	Buy
C1341	25g	$37	Buy
H56568	1g	$27.65	Buy

Diethyl 1,1-cyclopropanedicarboxylate Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

Diethyl 1,1-Cyclopropanedicarboxylate (cas# 1559-02-0) is a compound useful in organic synthesis.

Synthesis Reference(s)

Synthesis, p. 690, 1980 DOI: 10.1055/s-1980-29171

General Description

Diethyl cyclopropane-1,1-dicarboxylate participates in ring-opening addition reactions with various nucleophilic reagents.

Purification Methods

If it is free from OH bands in the IR, then fractionally distil the ester and redistil the middle fraction. Otherwise shake it with aqueous NaHCO3, dry it (MgSO4), filter and distil as before or re-esterify it. [As synthon see Danishefsky Acc Chem Res 12 66 1979, Beilstein 9 I 314, 9 II 512, 9 III 3595, 9 IV 2786.]

Diethyl 1,1-cyclopropanedicarboxylate Preparation Products And Raw materials

Raw materials

Preparation Products

1-AMINO-CYCLOPROPANEMETHANOL 1-TRIFLUOROMETHYLCYCLOPROPANE-1-CARBOXYLIC ACID 1-(4-Fluorophenylcarbamoyl)cyclopropanecarboxylic acid SINOVA SL-03967 ethyl 1-(trifluoroMethyl)cyclopropanecarboxylate

Ethyl 1-aminocyclopropanecarboxylate hydrochloride

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Diethyl 1,1-cyclopropanedicarboxylate Suppliers

Global( 370)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12453	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Shanghai Daken Advanced Materials Co.,Ltd	+86-371-66670886	info@dakenam.com	China	15371	58
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9352	55
Nanjing ChemLin Chemical Industry Co., Ltd.	025-83697070	product@chemlin.com.cn	CHINA	3012	60
Shandonghaohong biotechnology Co.,ltd.	0635-6175299 13961496334	sale@inyelchem.com	CHINA	44	55
Anhui Royal Chemical Co., Ltd.	+86-25-86655873 +8613962173137	marketing@royal-chem.com	China	205	55
Yancheng Green Chemicals Co.,Ltd	+undefined-86-25-86655873	info@royal-chem.com	China	114	58
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58

Supplier	Advantage
Hebei Mojin Biotechnology Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Shanghai Daken Advanced Materials Co.,Ltd	58
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
Nanjing ChemLin Chemical Industry Co., Ltd.	60
Shandonghaohong biotechnology Co.,ltd.	55
Anhui Royal Chemical Co., Ltd.	55
Yancheng Green Chemicals Co.,Ltd	58
career henan chemical co	58

View Lastest Price from Diethyl 1,1-cyclopropanedicarboxylate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-10-16	Diethyl 1,1-cyclopropanedicarboxylate 1559-02-0	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd
2023-09-06	Diethyl 1,1-cyclopropanedicarboxylate 1559-02-0	US $0.00-0.00 / KG	1KG	99%	500000kg	Hebei Guanlang Biotechnology Co., Ltd.
2022-09-30	Diethyl 1,1-cyclopropanedicarboxylate 1559-02-0	US $0.00-0.00 / kg	1kg	98%	1Ton	Henan Aochuang Chemical Co.,Ltd.

Diethyl 1,1-cyclopropanedicarboxylate
1559-02-0
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

Diethyl 1,1-cyclopropanedicarboxylate
1559-02-0
US $0.00-0.00 / KG
99%
Hebei Guanlang Biotechnology Co., Ltd.

Diethyl 1,1-cyclopropanedicarboxylate
1559-02-0
US $0.00-0.00 / kg
98%
Henan Aochuang Chemical Co.,Ltd.

Diethyl 1,1-cyclopropanedicarboxylate Spectrum

Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0)MS Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0)¹HNMR Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0)¹³CNMR Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0)IR1 Diethyl 1,1-cyclopropanedicarboxylate(1559-02-0)Raman

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Cyclopropane DIETHYL 2-PHENYL-1,1-CYCLOPROPANEDICARBOXYLATE 2-VINYLCYCLOPROPANE-1,1-DICARBOXYLIC ACID DIETHYL ESTER

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RARECHEM AL BO 0836 CYCLOPROPANE-1,1-DICARBOXYLIC ACID DIETHYL ESTER DIETHYL 1,1-CYCLOPROPANEDICARBOXYLATE DIETHYL 1,1-CYCLOPROPANEDICARBOXYLATE, 9 7% DiethyldifluoroMalonate96% 1,1-Bis(ethoxycarbonyl)cyclopropane Ethyl 1,1-cyclopropanedicarboxylate DIETHYL 1,1-CYCLOPROPANE-DICARBONYLATE 1,1-Cyclopropanedicarboxylic acid, 1,1-diethyl ester Diethyl 1,1-cyclopropanedicarboxylate ,99% Diethyl 1,1-cyclopropane dicarboxyliate 1-Cyclopropanedicarboxylate Diethyl 1 Diethyl 1,1-cyclopropanedicarboxylate, 97% 25GR 1,1-Dicarbethoxycyclopropane NSC 21376 1, 1 - cyclopropyl dicarboxylic acid diethyl ester Diethyl 1,1-Cyclopropanedicarboxylate > opropane-1,1-dicarboxyL DIETHYL 1,1-CYCLOPROPANEDICARBOXYLATE CAS 1559-02-0 TIANFU CHEM -- Diethyl 1,1-cyclopropanedicarboxylate 1,1-CYCLOPROPANEDICARBOXYLIC ACID DIETHYL ESTER DIETHYL CYCLOPROPANE-1,1-DICARBOXYLATE Diethylcyclopropan-1,1-dicarboxylat Diethyl Cyclopropane-1,1-Dcarboxylate 1559-02-0 C9H14O4 C3H4CO2C2H52 C1 to C5 C8 to C9 Carboxylic Acids Carbonyl Compounds Building Blocks Esters Organic Building Blocks Simple 3-Membered Ring Compounds Cyclopropanes Building Blocks C8 to C9 Carbonyl Compounds Chemical Synthesis Organic Building Blocks Aliphatics Cyclopropanes Simple 3-Membered Ring Compounds Cycloalkanes C8 to C9 Carbonyl Compounds Esters bc0001