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Triethylenediamine

Triethylenediamine Structure
Triethylenediamine structure
CAS No.
280-57-9
Chemical Name:
Triethylenediamine
Synonyms
DABCO;1,4-DIAZABICYCLO[2.2.2]OCTANE;teda;TED;BACO;Diazabicyclooctane;1,4-diazabicyclooctane;1,4-diazobicyclo[2.2.2]octane;Bicyclo[2.2.2]-1,4-diazaoctane;Dabco 33LV
CBNumber:
CB9164730
Molecular Formula:
C6H12N2
Molecular Weight:
112.17
MDL Number:
MFCD00006689
MOL File:
280-57-9.mol
MSDS File:
SDS
Last updated:2024-03-11 13:45:03
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Triethylenediamine Properties

Melting point 156-159 °C(lit.)
Boiling point 174 °C
Density 1.02 g/mL
vapor pressure 2.9 mm Hg ( 50 °C)
refractive index n20/D 1.4634(lit.)
Flash point 198 °F
storage temp. Store below +30°C.
solubility 400g/l
form Hygroscopic Crystals
pka 3.0, 8.7(at 25℃)
color White to pale yellow
Water Solubility 46 g/100 mL (26 ºC)
Sensitive Hygroscopic
Merck 14,9669
BRN 103618
Stability Stable, but very hygroscopic. Incompatible with strong oxidizing agents, strong acids. Highly flammable.
LogP -0.49 at 20℃
CAS DataBase Reference 280-57-9(CAS DataBase Reference)
FDA UNII X8M57R0JS5
NIST Chemistry Reference Triethylenediamine(280-57-9)
EPA Substance Registry System 1,4-Diazabicyclo[2.2.2]octane (280-57-9)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07
Signal word  Danger
Hazard statements  H228-H302-H315-H318
Precautionary statements  P210-P240-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xn,F
Risk Statements  22-36/37/38-52/53-41-36/38-11
Safety Statements  26-60-37/39-3-16-36/37-61
RIDADR  UN 1325 4.1/PG 2
WGK Germany  1
RTECS  HM0354200
F  3
Autoignition Temperature 350 °C
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29335920
Toxicity LD50 orally in Rabbit: 700 mg/kg
NFPA 704
2
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Triethylenediamine price More Price(57)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.03456 1,4-Diazabicyclo[2.2.2]octane for synthesis 280-57-9 100g $75.7 2024-03-01 Buy
Sigma-Aldrich 8.03456 1,4-Diazabicyclo[2.2.2]octane for synthesis 280-57-9 250g $148 2024-03-01 Buy
Sigma-Aldrich 8.03456 1,4-Diazabicyclo[2.2.2]octane for synthesis 280-57-9 1kg $470 2024-03-01 Buy
Sigma-Aldrich 290734 Dabco? 33-LV 280-57-9 100ml $83.6 2024-03-01 Buy
Sigma-Aldrich 290734 Dabco? 33-LV 280-57-9 500ml $278 2024-03-01 Buy
Product number Packaging Price Buy
8.03456 100g $75.7 Buy
8.03456 250g $148 Buy
8.03456 1kg $470 Buy
290734 100ml $83.6 Buy
290734 500ml $278 Buy

Triethylenediamine Chemical Properties,Uses,Production

Chemical Properties

Triethylenediamine also known as DABCO or TEDA, is a highly symmetrical molecule with a cage structure. The colorless extremely hygroscopic crystals is a highly nucleophilic tertiary amine base, which is used as a catalyst and reagent in polymerization and organic synthesis.

Uses

1,4-Diazabicyclo[2.2.2]octane is used as polyurethane catalyst, Balis-Hillman reaction catalyst complexing ligand and lewis base. It finds use in dye lasers and in mounting samples for fluorescence microscopy and as anti-fade reagent shown to scavenge free radicals due to flurochrome excitation of fluorochromes. Further, it is an oxidation and polymerization catalyst.

Uses

An anti-fade reagent shown to scavenge free-radicals due to flurochrome excitation.

Definition

ChEBI: Triethylenediamine is an organic heterobicylic compound that is piperazine with an ethane-1,2-diyl group forming a bridge between N1 and N4. It is typically used as a catalyst in polymerization reactions. It has a role as a catalyst, a reagent and an antioxidant. It is a bridged compound, a tertiary amino compound, a saturated organic heterobicyclic parent and a diamine.

Preparation

Triethylenediamine can be produced from ethylenediamine or ethanolamine, diethanolamine, or diethylenetriamine with a variety of different catalysts.

Reactions

Triethylenediamine reacts virtually quantitatively with bromine to give a 1/1 adduct. With alkyl halides it forms quaternary salts, even in nonpolar solvents. Apart from its highly nucleophilic nature, triethylenediamine exhibits catalytic activity in base-catalyzed reactions.

General Description

Dabco?33-LV (Db) is a gelling catalyst and a bidentate ligand that forms a self-assembled monolayer (SAM) on a variety of substrates. It functionalizes the surface and immobilizes the surface atoms.

Hazard

Skin irritant.

Flammability and Explosibility

Flammable

Purification Methods

DABCO crystallises from 95% EtOH, pet ether or MeOH/diethyl ether (1:1). Dry it under vacuum over CaCl2 and BaO. It can be sublimed in vacuo, and readily at room temperature. It has also been purified by removal of water during azeotropic distillation of a *benzene solution. It is then recrystallised twice from anhydrous diethyl ether under argon, and stored under argon [Blackstock et al. J Org Chem 52 1451 1987]. [Beilstein 23/3 V 487.]

Triethylenediamine synthesis

103-76-4
280-57-9
Synthesis of Triethylenediamine from 1-(2-Hydroxyethyl)piperazine

Triethylenediamine Preparation Products And Raw materials

Raw materials

Ethylenediamine PIPERAZINE HEXAHYDRATE Diethylenetriamine CHLOROETHANE Polyethylene-polyamines
Triethylenetetramine 1,4,7,10,13-Pentaazatridecane 1-(2-Hydroxyethyl)piperazine Sodium Methoxide

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Preparation Products

Dehydroacetic acid (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-1,1'-BINAPHTHYL ETHYL 2-(BROMOMETHYL)ACRYLATE 3-FLUOROPYRIDINE-2-CARBOXYLIC ACID (R)-(+)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl
5-Bromopyrimidine-2-carbonitrile 1.1'-Binaphthyl-2.2'-diphemyl phosphine (S)-(-)-2,2'-Bis(diphenylphosphino)-1,1'-binaphthyl Tribenuron methyl 2-Chloro-3-fluoropyridine-4-carboxylic acid
5-BROMOPYRIMIDINE-2-CARBOXYLIC ACID (R)-(+)-TolBINAP Piperazine (1,4-diazabicyclo[2.2.2]octan-1-ium-1-ylsulfonyl)(tert-butoxycarbonyl)amide 1-(chloromethyl)-4-aza-1-azonia bicyclo[2.2.2]octane chloride

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Triethylenediamine Suppliers

Global( 631)Suppliers
Supplier Tel Email Country ProdList Advantage
Shandong Believe Chemical PTE.LTD
+86-18553607090 +8618553607090 1093908296@qq.com China 1684 58
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12453 58
Shandong Juchuang Chemical Co., LTD 		+86-18885615001 +86-18885615001 admin@juchuangchem.com China 387 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Shanghai Time Chemicals CO., Ltd. 		+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714 fandachem@gmail.com China 9352 55
Anhui Royal Chemical Co., Ltd. 		+86-25-86655873 +8613962173137 marketing@royal-chem.com China 205 55
Hefei TNJ Chemical Industry Co.,Ltd. 		+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
Tianjin Zhongxin Chemtech Co., Ltd. 		+86-022-66880623 +8618622897568 sales@tjzxchem.com China 559 58
Supplier Advantage
Shandong Believe Chemical PTE.LTD
58
Hebei Mojin Biotechnology Co., Ltd 		58
Shandong Juchuang Chemical Co., LTD 		58
Capot Chemical Co.,Ltd. 		60
Henan Tianfu Chemical Co.,Ltd. 		55
Shanghai Time Chemicals CO., Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55
Anhui Royal Chemical Co., Ltd. 		55
Hefei TNJ Chemical Industry Co.,Ltd. 		55
Tianjin Zhongxin Chemtech Co., Ltd. 		58

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View Lastest Price from Triethylenediamine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Triethylenediamine pictures 2024-04-17 Triethylenediamine
280-57-9
 US $1.00 / KG 1KG ≥99% 2000mt/year Jinan Finer Chemical Co., Ltd
Triethylenediamine pictures 2024-03-11 Triethylenediamine
280-57-9
 US $45.00-30.00 / kg 500kg 99.9 200tons Shandong Juchuang Chemical Co., LTD
Triethylenediamine pictures 2023-11-16 Triethylenediamine
280-57-9
 US $0.00-0.00 / kg 1kg 99% 50000kg Hebei Yibangte Import and Export Co. , Ltd.
  • Triethylenediamine pictures
  • Triethylenediamine
    280-57-9
  • US $0.00-0.00 / kg
  • 99%
  • Hebei Yibangte Import and Export Co. , Ltd.

Triethylenediamine Spectrum

Triethylenediamine(280-57-9)MSTriethylenediamine(280-57-9)1HNMRTriethylenediamine(280-57-9)13CNMRTriethylenediamine(280-57-9)IR1Triethylenediamine(280-57-9)IR2Triethylenediamine(280-57-9)RamanTriethylenediamine(280-57-9)ESR

280-57-9(Triethylenediamine)Related Search:

Dicyclopentadiene Diethylenetriaminepentaacetic acid N-OCTANE Hexamethylenediamine 2-(2-Aminoethylamino)ethanol
Zidovudine Triethylenetetramine N,N-Diisopropylethylamine Ethyl Azidoacetate Diphenylphosphoryl azide
Methoxydiethylborane Triisopropanolamine TRIFLUOROACETALDEHYDE HYDRATE Triethylene glycol diacrylate Triethylenethiophosphoramide
Triethylsilane Triethanolamine Diethylaminoethanol

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Bicyclo(2,2,2)-1,4-diazaoctane Dabco(rg~TEDA~Triethylenediamine TRIETHLENE DIAMINE 1,4-DIAZABICYCLO(2.2.2)OCTAN 1,4-Diazabicyclo(2.2.2)octane, 97+% 1,4-diazabicyclo[2.2.2]octane solution teda, dabco TRIETHYLENEDIAMINE=1,4-DIAZABICYCLO(2,2,2)OCTANE 1,4-Diazabicyclooctan 1,4-Diazabicyclo2.2.2üoctane 1,4-Diazabicyclo2.2.2üoctane, 98+% DABCO(R), TED, Triethylenediamine DABCO(R) 33-LV N,N'-2-hydroxyethyl piperazine 1,4-Diazabicyclo[2.2.2]octane, 97% 100GR Dabco 33-LV,1,4-Diazabicyclo[2.2.2]octane solution 1,4-Diazabicyclo[2.2.2]octane{DABCO} bicyclo(2.2.2)-1,4-diazaoctane Bicyclo[2.2.2]octane, 1,4-diaza- D 33LV d33lv Dabco R-8020 Dabco S-25 dabco33lv dabcocrystal dabcoeg dabcor-8020 dabcos-25 n,n’-endo-ethylenepiperazine N,N'-endo-Ethylenepiperazine TEDA-L33 Texacat TD-33 texacattd100 thancattd33 triethylene-diamine,hexahydrate LUPRAGEN(R) N 201 LUPRAGEN(R) N 202 LUPRAGEN(R) N 203 DABCO(TM) DABCO(TM) 33-LV AURORA 15187 2,2'-Diazabicyclo[2.2.2]octane TRIETHYLENEDIAMINE 1,4-Diazabicyclo[2.2.2]octane, 97% 25GR 1,4-Diazabicyclo[2.2.2]octane, 97% 500GR DABCO Triethylenediamine 1,4-DIAZABICYCLO[2.2.2]OCTANE FOR SYNTHE Sanya ethyl diaMine ANTI-FAM155B(C-TERMINAL) antibody produced in rabbit FAM155B Protein TED TMEM28 Transmembrane protein FAM155B DABCO,TEDA 1,4-Diazabicyclo[2.2.2]octane ReagentPlus(R), >=99% 1,4-Diazabicyclo[2.2.2]octane Vetec(TM) reagent grade, 98% Triethylenediamine≥ 99% (GC) o[2.2.2]octane