(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one

CAS No.
6662-83-5
Chemical Name:
(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one
Synonyms
Kopsanone;Kopsan-22-one;(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one;6H,13aH-3a,5a-Ethano-5,11-methano-1H-indolizino[8,1-cd]carbazol-14-one, 2,3,4,5,11,12-hexahydro-, (3aR,5R,5aR,10bR,11R,13aS)-
CBNumber:
CB92324741
Molecular Formula:
C20H22N2O
Molecular Weight:
306.4
MDL Number:
MOL File:
6662-83-5.mol
Last updated:2022-12-21 16:56:50

(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one Properties

Melting point 284-5°C
FDA UNII 3GFZ578CMF

(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one Chemical Properties,Uses,Production

Description

This alkaloid from Vinca erecta Rgl. et Schmalh does not appear to be identical with that isolated from Aspidosperma duckei Hub. and A. macrocarpa Mart. This base is reported to have a specific rotation of [C\' 1 D + 98.6° (c 0.18, CHCI3). The structure has been assigned on the basis of chemical and spectroscopic evidence.

References

Rakhimov et al., Khim. Prir. Soedin., 6, 713 (1970)

(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one Preparation Products And Raw materials

Raw materials

Preparation Products

(2R,3R,5R,11S)-3,11-Methanoaspidofractinin-22-one Kopsan-22-one Kopsanone 6H,13aH-3a,5a-Ethano-5,11-methano-1H-indolizino[8,1-cd]carbazol-14-one, 2,3,4,5,11,12-hexahydro-, (3aR,5R,5aR,10bR,11R,13aS)- 6662-83-5