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ChemicalBook >> CAS DataBase List >>(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Structure
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE structure
CAS No.
443965-14-8
Chemical Name:
(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
Synonyms
(S)-SIPHOS;(R)-SIPHOS;(R)-SIPHOS 97%;(R)-SIPHOS（WS200888）;N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE;(R)-N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite;(R)-N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite;N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98%;N-DIMETHYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (R)-SIPHOS
CBNumber:
CB9285479
Molecular Formula:
C19H20NO2P
Molecular Weight:
325.34
MDL Number:
MFCD08459340
MOL File:
443965-14-8.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
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(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Properties

Melting point 95-96°C
Boiling point 429.6±55.0 °C(Predicted)
alpha +505° (c 0.5, CH2Cl2)
form solid
pka 2.19±0.20(Predicted)
color white
optical activity [α]22/D +480°, c = 1 in chloroform
Sensitive moisture sensitive

SAFETY

Risk and Safety Statements

WGK Germany  3
HS Code  29299090

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-5150 (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (R)-SIPHOS 443965-14-8 100mg $107 2024-03-01 Buy
Strem Chemicals 15-5150 (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine, min. 98% (R)-SIPHOS 443965-14-8 500mg $421 2024-03-01 Buy
American Custom Chemicals Corporation ING0001116 (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE 95.00% 443965-14-8 50MG $607.95 2021-12-16 Buy
American Custom Chemicals Corporation ING0001116 (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE 95.00% 443965-14-8 250MG $788.29 2021-12-16 Buy
AK Scientific 7382AJ (11AR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-De:1',7'-Fg][1,3,2]dioxaphosphocin-5-dimethylamine 443965-14-8 50mg $258.8 2021-12-16 Buy
Product number Packaging Price Buy
15-5150 100mg $107 Buy
15-5150 500mg $421 Buy
ING0001116 50MG $607.95 Buy
ING0001116 250MG $788.29 Buy
7382AJ 50mg $258.8 Buy

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Chemical Properties,Uses,Production

Reaction

  1. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of α-dehydroamino esters.
  2. Chiral ligands for the rhodium-catalyzed asymmetric hydrogenation of itaconic acid derivatives.
  3. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of β-dehydroaminoesters.
  4. Chiral ligands for rhodium-catalyzed asymmetric hydrogenation of enamides.
  5. Chiral ligands for rhodium-catalyzed asymmetric Pauson-Khand reaction.
  6. Chiral ligands for palladium-catalyzed asymmetric umpolung allylation of aldehydes.
Reactions of 443965-14-8_1
Reactions of 443965-14-8_2

Chemical Properties

White power

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Preparation Products And Raw materials

Raw materials

Benzyl chloride Ethanol Acetone Sodium bromide Methanesulfonic acid
Hydrogen peroxide Sodium chloride Toluene N,N-Diisopropylethylamine Nickel
Cinchonidine Boron tribromide Palladium 3-Hydroxybenzaldehyde Hexamethylphosphorous triamide
(R)-1,1'-SPIROBIINDANE-7,7'-DIOL Ethyl acetate Hydrochloric acid Sodium bicarbonate Hydrogen
Dichloromethane Sodium hydroxide PETROLEUM ETHER

1of5

Preparation Products

(11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE Suppliers

Global( 39)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Arbor Chemical Co., Ltd. 		021-60451682 act@arborchemical.com CHINA 906 58
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
Zhuoer Chemical Co., Ltd 		02120970332; +8613524231522 sales@zhuoerchem.com China 3015 58
CR Corporation Lomited 		fred.wen@crcorporation.cn CHINA 12069 58
Labnetwork lnc. 		+86-27-50766799 +8618062016861 contact@labnetwork.com China 19994 58
GIHI CHEMICALS CO.,LIMITED 		+8618058761490 info@gihichemicals.com China 49999 58
Aladdin Scientific 		+1-833-552-7181 sales@aladdinsci.com United States 57511 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94838 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006608290; 18621169109 market03@meryer.com China 40241 62
BeiJing Hwrk Chemicals Limted 0757-86329057 18934348241 sales4.gd@hwrkchemical.com China 14067 55
Supplier Advantage
Shanghai Arbor Chemical Co., Ltd. 		58
Dayang Chem (Hangzhou) Co.,Ltd. 		58
Zhuoer Chemical Co., Ltd 		58
CR Corporation Lomited 		58
Labnetwork lnc. 		58
GIHI CHEMICALS CO.,LIMITED 		58
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
BeiJing Hwrk Chemicals Limted 55

443965-14-8((11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE)Related Search:

Indene Dimethylamine (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE
N-DIMETHYL-[(S)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE N-DIMETHYL-[(R)-1,1'-SPIROBIINDANE-7,7'-DIYL]PHOSPHORAMIDITE (R)-SIPHOS (S)-SIPHOS (11AS)-(-)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-dimethylamine,min.98%(R)-SIPHOS N-DIMETHYL-[(R)-1,1-SPIROBIINDANE-7,7-DIYL]PHOSPHORAMIDITE, (R)-SIPHOS (11aR)-(+)-10,11,12,13-Tetrahydrodiindeno[7,1-de:1μ,7μ-fg][1,3,2]dioxaphosphocin-5-dimethylamine, N-Dimethyl-[(R)-1,1μ-spirobiindane-7,7μ-diyl]phosphoramidite N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite ,98% (11aR)-10,11,12,13-Tetrahydro-N,N-dimethyldiindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (11aR)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (R)-SIPHOS (R)-SIPHOS（WS200888） Diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine, 10,11,12,13-tetrahydro-N,N-dimethyl-, (11aR)- (R)-SIPHOS 97% (R)-N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite (11AR)-(+)-10,11,12,13-TETRAHYDRODIINDENO[7,1-DE:1',7'-FG][1,3,2]DIOXAPHOSPHOCIN-5-DIMETHYLAMINE (11aR)-10,11,12,13-Tetrahydro-N,N-dimethyl-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin-5-amine (R)-N-Dimethyl-[(R)-1,1'-spirobiindane-7,7'-diyl]phosphoramidite 443965-14-8 C19H20NO2P Chiral Phosphine Chiral Spiro Ligand CPN