Ethyl benzoate
- CAS No.
- 93-89-0
- Chemical Name:
- Ethyl benzoate
- Synonyms
- BENZOIC ACID ETHYL ESTER;Manufacture;Ethylbenzoat;Nat.Ethyl benzoate;BENZOIC ETHER;Benzoic acid ethyl;Benxoicacidethylester;ETHYL BENZOATE FOR SYNTHESIS 1 L;FEMA 2422;Large Stock
- CBNumber:
- CB9318180
- Molecular Formula:
- C9H10O2
- Molecular Weight:
- 150.17
- MDL Number:
- MFCD00009109
- MOL File:
- 93-89-0.mol
- MSDS File:
- SDS
| Melting point | -34 °C |
|---|---|
| Boiling point | 212 °C(lit.) |
| Density | 1.045 g/mL at 25 °C(lit.) |
| vapor density | 5.17 (vs air) |
| vapor pressure | 1 mm Hg ( 44 °C) |
| refractive index |
n |
| FEMA | 2422 | ETHYL BENZOATE |
| Flash point | 184 °F |
| storage temp. | Store below +30°C. |
| solubility | 0.5g/l |
| form | Liquid |
| color | Clear colorless to pale yellow |
| Relative polarity | 0.228 |
| Odor | at 100.00 %. fruity dry musty sweet wintergreen |
| Odor Type | minty |
| explosive limit | 1%(V) |
| Water Solubility | INSOLUBLE |
| Merck | 14,3766 |
| JECFA Number | 852 |
| BRN | 1908172 |
| Dielectric constant | 6.0（20℃） |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
| LogP | 2.59 at 23℃ |
| Substances Added to Food (formerly EAFUS) | ETHYL BENZOATE |
| FDA 21 CFR | 172.515 |
| CAS DataBase Reference | 93-89-0(CAS DataBase Reference) |
| EWG's Food Scores | 2 |
| FDA UNII | J115BRJ15H |
| NIST Chemistry Reference | Benzoic acid, ethyl ester(93-89-0) |
| EPA Substance Registry System | Benzoic acid, ethyl ester (93-89-0) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS09,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H411-H227-H303-H315-H319 | |||||||||
| Precautionary statements | P210e-P280a-P305+P351+P338-P403+P235-P501a-P273 | |||||||||
| Hazard Codes | N | |||||||||
| Risk Statements | 51/53 | |||||||||
| Safety Statements | 24/25-61 | |||||||||
| RIDADR | UN 3082 9 / PGIII | |||||||||
| WGK Germany | 1 | |||||||||
| RTECS | DH0200000 | |||||||||
| Autoignition Temperature | 914 °F | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29163100 | |||||||||
| Toxicity | LD50 orally in rats: 6.48 g/kg, Smyth et al., Arch. Ind. Hyg. Occup. Med. 10, 61 (1954) | |||||||||
| NFPA 704 |
|
Ethyl benzoate price More Price(30)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | W242217 | Ethyl benzoate natural, ≥99%, FCC, FG | 93-89-0 | 100g | $79.9 | 2024-03-01 | Buy |
| Sigma-Aldrich | W242217 | Ethyl benzoate natural, ≥99%, FCC, FG | 93-89-0 | 1kg | $1040 | 2024-03-01 | Buy |
| Sigma-Aldrich | W242209 | Ethyl benzoate ≥99%, FCC, FG | 93-89-0 | 1kg | $76.5 | 2024-03-01 | Buy |
| Sigma-Aldrich | W242209 | Ethyl benzoate ≥99%, FCC, FG | 93-89-0 | 25kg | $562 | 2024-03-01 | Buy |
| Sigma-Aldrich | E12907 | Ethyl benzoate ≥99% | 93-89-0 | 5g | $29.1 | 2024-03-01 | Buy |
Ethyl benzoate Chemical Properties,Uses,Production
Description
Ethyl benzoate, C9H10O2, is the ester formed by the condensation of benzoic acid and ethanol. It is a colorless liquid that is almost insoluble in water, but miscible with most organic solvents.
As with many volatile esters, ethyl benzoate has a pleasant odor which could be described similar to wintergreen mint. It is a component of some artificial fruit flavors.
Chemical Properties
Ethyl benzoate is a colourless liquid that has a somewhat fruity odor similar to ylang-ylang, but milder than methyl benzoate. Soluble in ethanol, ethyl ether, petroleum ether, propylene glycol, mineral oil and most non-volatile oils, insoluble in water and glycerin.
Occurrence
Reported found in volatiles from hard, mature peaches, pineapple and currant. Also reported found in apple juice, banana, guava, cranberry, raspberry, sweet cherry, Parmesan cheese, butter, milk, white wine, red wine, cider, whiskies, cocoa, black tea, fresh plum, apple brandy, cherry brandy, Bourbon vanilla, naranjilla fruit, ceriman or pinanona, pimento berry, olive and passion fruit.
Uses
Ethyl benzoate is used as a perfume scent. It acts as a food flavoring agent. It is an active component of artificial fruit flavors. Further, it is used in cosmetics and personal care products as fragrance ingredients and preservatives.
Uses
Ethyl Benzoate acts as an aroma and flavour compound due to the volatile ester group in its structure. In perfumery under the name Essence de Niobe; in manufacture of Peau d'Espagne; artificial fruit essence.
Definition
ChEBI: Ethyl benzoate is a benzoate ester obtained by condensation of benzoic acid and ethanol. It is a volatile oil component found in ripe kiwifruit, cranberry juice, and palm kernel oil. It has a role as a flavouring agent, a fragrance and a volatile oil component. It is a benzoate ester and an ethyl ester.
Preparation
By esterification of ethyl alcohol and benzoic acid in the presence of anhydrous aluminum sulfate and a trace of sulfuric acid; by transesterification of methyl benzoate with ethanol in the presence of potassium ethylate
Aroma threshold values
Detection: 100 ppb; recognition: 150 ppb
Taste threshold values
Taste characteristics at 30 ppm: sweet, medicinal, green, minty, fruity, birch beer and wintergreen-like.
Synthesis Reference(s)
The Journal of Organic Chemistry, 25, p. 1703, 1960 DOI: 10.1021/jo01080a004
Synthetic Communications, 20, p. 2267, 1990 DOI: 10.1080/00397919008053167
Tetrahedron Letters, 22, p. 1509, 1981 DOI: 10.1016/S0040-4039(01)90363-6
General Description
Natural occurrence: Feijoa, guava, plum, raspberry, rum, strawberry, Virginia tobacco.
Flammability and Explosibility
Not classified
Biochem/physiol Actions
Taste at 10 ppm
Safety Profile
Moderately toxic by ingestion. Mildly toxic by skin contact. A skin and eye irritant. Combustible liquid when exposed to heat or flame; can react with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS
Ethyl benzoate Preparation Products And Raw materials
Raw materials
Preparation Products
1of3
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Wuhan Biet Co., Ltd. | +8617320528784 | min@biet.com.cn | China | 41 | 58 |
| Hebei Guanlang Biotechnology Co,.LTD | +8619930503252 | daisy@crovellbio.com | China | 5964 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12456 | 58 |
| Dorne Chemical Technology co. LTD | +86-13583358881 +86-18560316533 | Ethan@dornechem.com | China | 294 | 58 |
| Ouhuang Engineering Materials (Hubei) Co., Ltd | +8617702722807 | admin@hbouhuang.com | China | 1696 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| Zhejiang ZETian Fine Chemicals Co. LTD | 18957127338 | stella@zetchem.com | China | 2141 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 | sales@finerchem.com | China | 2967 | 58 |
View Lastest Price from Ethyl benzoate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-24 | Ethyl benzoate
93-89-0
|
US $1.00 / g | 1g | 99% | 1000kg | Dorne Chemical Technology co. LTD | |
 |
2024-04-24 | Ethyl benzoate
93-89-0
|
US $0.00 / Kg/Drum | 1KG | 99% | 500mt/year | Jinan Finer Chemical Co., Ltd | |
 |
2024-04-19 | Ethyl benzoate
93-89-0
|
US $1.00 / KG | 1KG | 99.91% | 200000 | Ouhuang Engineering Materials (Hubei) Co., Ltd |
-
- Ethyl benzoate
93-89-0
- US $1.00 / g
- 99%
- Dorne Chemical Technology co. LTD
-
- Ethyl benzoate
93-89-0
- US $0.00 / Kg/Drum
- 99%
- Jinan Finer Chemical Co., Ltd
-
- Ethyl benzoate
93-89-0
- US $1.00 / KG
- 99.91%
- Ouhuang Engineering Materials (Hubei) Co., Ltd