Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene
- CAS No.
- 125051-32-3
- Chemical Name:
- Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene
- Synonyms
- 784;Irgacure 784;Bis(2,6-difluoro-3-(1-hydropyrro-1-yl)-phenyl)titanocene;Photoinitiator-784;photo sensitizer 784;LS 784;PI 784;FMT,784;APi-784;)phenyl]-
- CBNumber:
- CB9370465
- Molecular Formula:
- C30H12F4N2Ti
- Molecular Weight:
- 524.3
- MDL Number:
- MFCD00274256
- MOL File:
- 125051-32-3.mol
- MSDS File:
- SDS
Melting point | 160-170°C |
---|---|
Density | 1.43 at 20℃ |
vapor pressure | 0-0.001Pa at 25-50℃ |
storage temp. | below 5° C |
form | Powder |
Hydrolytic Sensitivity | 4: no reaction with water under neutral conditions |
InChI | InChI=1S/2C10H6F2N.2C5.Ti/c2*11-8-3-4-10(9(12)7-8)13-5-1-2-6-13;2*1-2-4-5-3-1;/h2*1-6H;;;/q4*-1;+4 |
InChIKey | HRVFAWAOUBYIBB-UHFFFAOYSA-N |
SMILES | FC1=C(N2C=CC=C2)C=CC(F)=[C-]1[Ti+4]12345678([C-]9=C(C=CC(N%10C=CC=C%10)=C9F)F)(C9=C1[C-]2C3=C49)C1=C5C6=C7[C-]81 |
LogP | 9.5 at 20℃ |
Surface tension | 72.4mN/m at 10g/L and 20℃ |
EPA Substance Registry System | Titanium, bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]- (125051-32-3) |
SAFETY
Risk and Safety Statements
Symbol(GHS) | GHS02,GHS08,GHS09 |
---|---|
Signal word | Danger |
Hazard statements | H228-H361f-H373-H411 |
Precautionary statements | P210-P280-P260-P308+P313 |
Hazard Codes | F,Xn,N |
Risk Statements | 36/37/38-51/53-62-48/22-11 |
Safety Statements | 26-36/37/39-61-36/37-33-22-7 |
TSCA | Yes |
HS Code | 2914199090 |
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene price
Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
---|---|---|---|---|---|---|---|
Apolloscientific | PC52112 | Bis(2,6-difluoro-3-(1-hydropyrrol-1-yl)phenyl)titanocene 99% | 125051-32-3 | 10g | $435 | 2021-12-16 | Buy |
SynQuest Laboratories | 9H22-3-00 | Bis(2,6-difluoro-3-(1-hydropyrrol-1-yl)phenyl)titanocene 99% | 125051-32-3 | 10g | $480 | 2021-12-16 | Buy |
BLDpharm | BD764326 | Easepi784 98% | 125051-32-3 | 1g | $19 | 2021-12-16 | Buy |
BLDpharm | BD764326 | Easepi784 98% | 125051-32-3 | 5g | $57 | 2021-12-16 | Buy |
Crysdot | CD00011660 | Easepi784 97% | 125051-32-3 | 5g | $79 | 2021-12-16 | Buy |
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Chemical Properties,Uses,Production
Description
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene, also known as Photosensitizer Irgacure 784, is an excellent photoinitiator used in a variety of holography material systems. It belongs to titanium‐complex free radical photoinitiator. As a highly active orange solid photoinitiator, Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene has good photoactivity, thermal stability, and low toxicity. Irgacure 784 has high solubility doped in liquid methyl methacrylate (MMA) monomer, far more than the photoinitiator PQ[1-2].
Uses
BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE is a highly active orange solid photoinitiator with good photoactivity, thermal stability and low toxicity. As an active diluent, it is mainly used for UV and visible light curing of unsaturated prepolymers together with single or multi-functional vinyl monomers and oligomers.
Hazard
Toxic to aquatic life with long lasting effects [Hazardous to the aquatic environment, long-term hazard]; Flammable solid [Danger Flammable solids]; Suspected of damaging fertility or the unborn child [Warning Reproductive toxicity]
References
[1] Liu Y, et al. Volume holographic recording in Irgacure 784-doped PMMA photopolymer. Optics Express, 2017; 25: 20654-20662.
[2] Li Z, et al. Near‐Infrared‐Induced Cationic Polymerization Initiated by Using Upconverting Nanoparticles and Titanocene. Macromolecular Rapid Communications, 2019; 40: 1900047.
Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene Preparation Products And Raw materials
Raw materials
Preparation Products
Supplier | Tel | Country | ProdList | Advantage | |
---|---|---|---|---|---|
Jiangxi Lotchem Co.,Ltd. | +8615270827708 | lancetu@jxlotchem.com | CHINA | 338 | 58 |
Tianjin Huiren Chemtech Co., Ltd | 86-22-23707858; +8613672008665 | huirentech@foxmail.com | China | 110 | 58 |
Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503259 +86-19930503259 | cherry@crovellbio.com | China | 18459 | 58 |
Changyi Longchang Bio-Chemical Co., LTD | +86-13256193735 +86-13256193735 | info@longchangchemical.com | China | 169 | 58 |
Wuhan Kemi-Works Chemical Co., Ltd. | +86-2785736489 +8618171418573 | sales@kemiworks.com | China | 704 | 58 |
Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12452 | 58 |
Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5988 | 58 |
Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 14764 | 58 |
Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21700 | 55 |
Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9354 | 55 |
View Lastest Price from Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene manufacturers
Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
---|---|---|---|---|---|---|---|---|
2024-03-28 | Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene
125051-32-3
|
US $6.00-0.20 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | ||
2024-03-28 | Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl)-3H-pyrrol-3-yl)titanium
125051-32-3
|
US $5.00 / KG | 1KG | 99% | 500mt/year | Jinan Finer Chemical Co., Ltd | ||
2023-10-21 | Irgacure 784
125051-32-3
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd |
- Bis[2,6-difluoro-3-(1H-pyrrol-1-yl)phenyl]titanocene
125051-32-3
- US $6.00-0.20 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
- Bis(cyclopenta-1,3-diene)bis(1-(2,4-difluorophenyl)-3H-pyrrol-3-yl)titanium
125051-32-3
- US $5.00 / KG
- 99%
- Jinan Finer Chemical Co., Ltd
- Irgacure 784
125051-32-3
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
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