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3-Chloro-2-methylpropene

CAS No.
563-47-3
Chemical Name:
3-Chloro-2-methylpropene
Synonyms
METHALLYL CHLORIDE;Mac;3-chloro-2-methylprop-1-ene;3-CHLORO-2-METHYL-1-PROPENE;Isobutenyl chloride;beta-methylallylchloride;Methylallyl chloride;BETA-METHALLYL CHLORIDE;1-CHLORO-2-METHYL-2-PROPENE;NCI-C54820
CBNumber:
CB9402043
Molecular Formula:
C4H7Cl
Molecular Weight:
90.55
MDL Number:
MFCD00000953
MOL File:
563-47-3.mol
MSDS File:
SDS
Last updated:2023-12-25 17:47:29

3-Chloro-2-methylpropene Properties

Melting point -80 °C (lit.)
Boiling point 71-72 °C (lit.)
Density 0.925 g/mL at 20 °C (lit.)
vapor density 3.12 (vs air)
vapor pressure 102 mm Hg ( 20 °C)
refractive index n20/D 1.427(lit.)
Flash point 9 °F
storage temp. 2-8°C
solubility H2O: insoluble
form Liquid
color Clear
explosive limit 2.2-10.4%(V)
Water Solubility 0.5 g/L (20 ºC)
Merck 14,2148
BRN 878160
CAS DataBase Reference 563-47-3(CAS DataBase Reference)
EWG's Food Scores 3-4
FDA UNII 7A9X1C3I3O
Proposition 65 List 3-Chloro-2-methylpropene
NIST Chemistry Reference 1-Propene, 3-chloro-2-methyl-(563-47-3)
IARC 2B (Vol. 63, 115) 2018
EPA Substance Registry System 3-Chloro-2-methyl-1-propene (563-47-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H225-H302+H332-H314-H317-H411
Precautionary statements  P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  F,C,N
Risk Statements  11-20/22-34-43-51/53
Safety Statements  9-16-29-36/37/39-45-61-26
RIDADR  UN 2554 3/PG 2
WGK Germany  2
RTECS  UC8050000
Autoignition Temperature 899 °F
TSCA  Yes
HazardClass  3
PackingGroup  II
HS Code  29032900
NFPA 704
3
2 1

3-Chloro-2-methylpropene price More Price(32)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.05905 3-Chloro-2-methyl-1-propene for synthesis 563-47-3 100mL $45.7 2024-03-01 Buy
Sigma-Aldrich 8.05905 3-Chloro-2-methyl-1-propene for synthesis 563-47-3 500mL $77.3 2024-03-01 Buy
Sigma-Aldrich 108030 3-Chloro-2-methyl-1-propene technical grade, 90% 563-47-3 100ml $47 2024-03-01 Buy
Sigma-Aldrich 108030 3-Chloro-2-methyl-1-propene technical grade, 90% 563-47-3 1l $72 2024-03-01 Buy
TCI Chemical C0209 3-Chloro-2-methyl-1-propene >98.0%(GC) 563-47-3 25mL $21 2024-03-01 Buy
Product number Packaging Price Buy
8.05905 100mL $45.7 Buy
8.05905 500mL $77.3 Buy
108030 100ml $47 Buy
108030 1l $72 Buy
C0209 25mL $21 Buy

3-Chloro-2-methylpropene Chemical Properties,Uses,Production

Description

3-Chloro-2-methylpropene is used as an intermediate to produce carbofuran, herbicides, plastics, pharmaceuticals and other organics. It is also used as an additive in textile and perfumes. It was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate and cationic polymerization of 3-Chloro-2-methylpropene with AICI3 and AIBr3 as initiators. It is also the reactant for the synthesis of cyclobutanone.

Chemical Properties

clear liquid

Uses

3-Chloro-2-methyl-1-propene was used to study ring opening polymerization of oxirane derivatives using organotin phosphate condensate. It was used to study cationic polymerization of 3-Chloro-2-methyl-1-propene using using AICI3 and A3IBr, as initiators.

Uses

In organic synthesis.

Uses

3-Chloro-2-methylpropene has been used as reactant in the synthesis of cyclobutanone. It is used as an intermediate in the production of plastics, pharmaceuticals and other organic chemicals.

Definition

ChEBI: 3-Chloro-2-methylpropene is an organochlorine compound.

Biological Functions

MAC is a valuable index for clinical anesthesia, but it is seldom employed without taking other factors into consideration. For example, inhibiting movement in only 50% of patients is not acceptable. Consequently, if an inhalational agent were being used alone—that is, without the administration of other anesthetics or analgesic drugs—the anesthesiologist would employ a multiple of its MAC value to ensure immobility.MAC is frequently multiplied by a factor of 1.3 to achieve nearly 100% clinical efficacy. On the other hand, useful clinical results may be achieved with doses of anesthetics below MAC levels. For example, mild analgesia and amnesia often occur with doses of inhalational agents that are near 0.5 MAC. In this state, it may even be possible to communicate with patients intraoperatively, while their recall is limited.

Synthesis Reference(s)

The Journal of Organic Chemistry, 46, p. 824, 1981 DOI: 10.1021/jo00317a041

General Description

A colorless to straw-colored liquid with a sharp penetrating odor. Less dense than water and insoluble in water. Flash point below 0°F. May be toxic by ingestion. Irritating to skin and eyes. Used to make plastics and pharmaceuticals.

Air & Water Reactions

Highly flammable. 3-Chloro-2-methylpropene may react with water at elevated temperatures. . Insoluble in water.

Reactivity Profile

3-Chloro-2-methylpropene is sensitive to light. 3-Chloro-2-methylpropene can react vigorously with oxidizers. 3-Chloro-2-methylpropene is incompatible with strong bases. 3-Chloro-2-methylpropene may react with water at elevated temperatures. .

Hazard

Irritant; poison; anesthetic; questionable carcinogen; toxic.

Health Hazard

Inhalation causes irritation of nose and throat. Contact of vapor or liquid with eyes causes irritation. Liquid irritates skin. Ingestion causes irritation of mouth and stomach.

Safety Profile

Confirmed carcinogen with experimental carcinogenic, neoplastigenic, and tumorigenic data. Experimental reproductive effects. An irritant. Human mutation data reported. Very dangerous fire hazard when exposed to heat, flame, or oxidizers. Moderately explosive when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use alcohol foam, CO2, dry chemical. When heated to decomposition it emits toxic fumes of Cl-. See also CHLORINATED HYDROCARBONS, ALIPHATIC; and ALLYL COMPOUNDS.

Carcinogenicity

3-Chloro-2-methylpropene is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.

Global( 271)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12452 58
Henan Fengda Chemical Co., Ltd
+8613613820652 info@fdachem.com China 5085 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21700 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58

View Lastest Price from 3-Chloro-2-methylpropene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
3-Chloro-2-methylpropene pictures 2023-12-26 3-Chloro-2-methylpropene
563-47-3
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
3-Chloro-2-methylpropene pictures 2023-06-20 3-Chloro-2-methylpropene
563-47-3
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
3-Chloro-2-methylpropene pictures 2023-03-06 3-Chloro-2-methylpropene
563-47-3
US $50.00-20.00 / KG 1KG 99% 10000kg Hebei Guanlang Biotechnology Co,.LTD
2-CHLORO-2-METHYL-1-PROPANE 3-CHLORO-2-METHYL-1-PROPENE 97+% 2-Methyl-3-chloroprop-1-ene 3-Chloro-2-methylpropene , 90%,tech 3-Chloro-2-methylpropene ,90% 3-Chloro-2-methyl-1-propene,β-Methallyl chloride 3-Chloro-2-Methylpropene, tech., 90% 1LT 3-Chloro-2-Methylpropene, tech., 90% 50ML 2-Methylallyl chloride, 2-Methylprop-2-en-1-yl chloride 3-Chloroisobutene beta-Methallyl Chloride 2-Methylallyl Chloride 2-Methyl-2-propenyl Chloride 3-CHLORO-2-METHYL-1-PROPENE FOR SYNTHESI METHALLYLCHLORIDEBOTTOMS 3-Chloro-2-Methyl-1-propene contains ~250 ppM Pentaerythritol tetrakis(3,5-di-tert-butyl-4-hydroxyhydrocinnaMate) as stabilizer, 98% 3-Chlor-2-methyl-1-propen 3-Chlor-2-methyl-prop-1-en 3-Chlor-2-methylpropen 3-chloro-2-methyl 3-chloro-2-methyl-1-propen 3-chloro-2-methyl-propen 3-Chloro-2-methylpropene-1 3-chloroisobu 3-Cloro-2-metil-prop-1-ene Methallylchlorid NCI-C54820 Propene, 3-chloro-2-methyl- Propene,3-chloro-2-methyl- γ-Chloroisobutylene 3-CHLORO-2-METHYLPROPENE 3-CHLOROISOBUTYLENE 3-CHLOROISOBUTENE AKOS BBS-00004062 2-METHYLALLYL CHLORIDE 2-METHYL-2-PROPENYL CHLORIDE beta-Methylallyl chloride chloruedemethallyle(french) Chlorure de methallyle chloruredemethallyle chloruredemethallyle(french) Cloruro di metallile clorurodimetallile gamma-Chloroisobutylene 1-propene,3-chloro-2-methyl- 2-(Chloromethyl)-1-propene 2-methallylchloride 2-Methyl-3-chloro-1-propene 2-Methyl-3-chloropropene 2-Methyl-allylchlorid 3-Chloro-2-Methylpropylene 3-CHLORO-2-METHYLPROPENE, TECH., 90% 3-Chloro-2-methyl-1-propene > 3-Chloro-2-methylpropene ISO 9001:2015 REACH TIANFU CHEM 563-47-3 3-Chloro-2-methylpropene 3-chloro-2-methylprop-1-ene Mac BETA-METHALLYL CHLORIDE Isobutenyl chloride METHALLYL CHLORIDE Methylallyl chloride