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2-Bromophenylboronic acid

CAS No.
244205-40-1
Chemical Name:
2-Bromophenylboronic acid
Synonyms
o-BBBA;2-broMoborate;AKOS BRN-0929;RARECHEM AH PB 0074;2-Bromophenylboronic;2-BROMOPHENYLBORONIC ACID;O-BROMOPHENYLBORONIC ACID;(2-bromophenyl)boronicaci;2-BROMOBENZENEBORONIC ACID;2-Bromobenzeneboronicacid,98%
CBNumber:
CB9421532
Molecular Formula:
C6H6BBrO2
Molecular Weight:
200.83
MDL Number:
MFCD01114672
MOL File:
244205-40-1.mol
MSDS File:
SDS
Last updated:2024-04-08 13:48:25

2-Bromophenylboronic acid Properties

Melting point 113 °C(lit.)
Boiling point 329.2±44.0 °C(Predicted)
Density 1.67±0.1 g/cm3(Predicted)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Acetonitrile (Slightly), Chloroform (Slightly), DMSO (Slightly), Methanol (Sparingly)
form Powder
pka 8.25±0.58(Predicted)
color White to off-white
Water Solubility Soluble in methanol. Slightly soluble in water.
BRN 8542615
CAS DataBase Reference 244205-40-1(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xn,Xi
Risk Statements  36/37/38-22
Safety Statements  37/39-26
WGK Germany  3
HazardClass  IRRITANT
HS Code  29319090
NFPA 704
1
2 0

2-Bromophenylboronic acid price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 473804 2-Bromophenylboronic acid ≥95.0% 244205-40-1 5g $31.6 2024-03-01 Buy
Sigma-Aldrich 473804 2-Bromophenylboronic acid ≥95.0% 244205-40-1 25g $150 2024-03-01 Buy
TCI Chemical B2889 2-Bromophenylboronic Acid (contains varying amounts of Anhydride) 244205-40-1 5g $64 2024-03-01 Buy
Alfa Aesar L18581 2-Bromobenzeneboronic acid, 98% 244205-40-1 1g $30.65 2024-03-01 Buy
Alfa Aesar L18581 2-Bromobenzeneboronic acid, 98% 244205-40-1 5g $78.65 2024-03-01 Buy
Product number Packaging Price Buy
473804 5g $31.6 Buy
473804 25g $150 Buy
B2889 5g $64 Buy
L18581 1g $30.65 Buy
L18581 5g $78.65 Buy

2-Bromophenylboronic acid Chemical Properties,Uses,Production

Chemical Properties

White to off-white powder

Uses

2-Bromobenzeneboronic acid is a boronic acid derivative that is widely used in organic synthesis for carbon-carbon bond formation. In Suzuki coupling, aryl halides and boronic acid aryl or vinyl esters or boronic acids are coupled using Pd(PPh3)4.

Application

2-Bromophenylboronic Acid is used as an inhibitor of the hormone sensitive lipase.
Catalyzes the formation of amide bonds from amines and carboxylic acids.
Used to promote greener amidations of carboxylic acids and amines in catalytic amounts. This technology avoids the requirement of preactivation of the carboxylic acid or use of coupling reagents.
It is also an important intermediate for Organic Light-Emitting Diod ( OLED) .

Preparation

2-Bromophenylboronic acid synthesis: take 2-bromoaniline as raw material, synthesize the intermediate 1-Bromo-2-iodobenzene through diazotization and iodination, and then carry out magnesium iodide exchange with isopropylmagnesium bromide to synthesize o-bromophenylmagnesium bromide, It is then subjected to substitution reaction with trimethyl borate to synthesize methyl o-bromophenylboronic acid, and then hydrolyzed to synthesize 2-bromophenylboronic acid.

121-43-7
583-55-1
244205-40-1
Synthesis of 2-Bromophenylboronic acid from Trimethyl borate and 1-Bromo-2-iodobenzene
Global( 378)Suppliers
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Tianjin Xinshengjiahe Science & Technology Development Co,.Ltd
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Henan Fengda Chemical Co., Ltd
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View Lastest Price from 2-Bromophenylboronic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Bromophenylboronic acid pictures 2024-04-08 2-Bromophenylboronic acid
244205-40-1
US $34.00-1.20 / kg 1kg 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
 2-Bromophenylboronic acid pictures 2023-05-04 2-Bromophenylboronic acid
244205-40-1
US $48.00-40.00 / KG 1KG 99% 200tons Guangzhou Sunton Biotechnology Co., Ltd.
2-Bromophenylboronic acid pictures 2023-03-13 2-Bromophenylboronic acid
244205-40-1
US $0.00-0.00 / kg 1kg 98%Min 1000kg LY Global chemicals co.,ltd .

2-Bromophenylboronic acid Spectrum

2-broMoborate o-BBBA 2-Bromophenylboronic acid >=95.0% Boronic acid,B-(2-bromophenyl)- AKOS BRN-0929 RARECHEM AH PB 0074 O-BROMOPHENYLBORONIC ACID 2-BROMOPHENYLBORONIC ACID 2-BROMOBENZENEBORONIC ACID 2-Bromophenylboronic 2-Bromophenylboronic Acid (contains varying amounts of Anhydride) 2-Bromobenzeneboronicacid,98% 2-Bromophenylboronic acid,97% 2-BroMophenylboronic Acid  2-BroMophenylboronic acid, 97% 5GR 2-Bromophenylboronic acid ,98% VLOOKUP(C12,[1]Export!$D:$H,5,0) 2-Bromobenzeneboronic acid 98% (2-bromophenyl)boronicaci Boronic acid, B-(2-bromopheny!)- 244205-40-1 C6H6BBrO2 Organometallic Reagents Aryl Boronic Acids Boronic Acids and Derivatives Boronic Acids and Derivatives Boronate Ester Boronic Acid Potassium Trifluoroborate Pyridines blocks BoronicAcids Bromides B (Classes of Boron Compounds) Boronic Acids Aryl Boronic Acids