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METHYL ALPHA-CHLOROACRYLATE

CAS No.
80-63-7
Chemical Name:
METHYL ALPHA-CHLOROACRYLATE
Synonyms
METHYL 2-CHLOROACRYLATE;METHYL 2-CHLORO-2-PROPENATE;Methyl 2-chloro-2-propenoate;Acryli;METHYL CHLOROACRYLATE;METHYL-A-CHLOROACRYLATE;chloro-2acrylatedemethyle;Methyl 2-chloropropenoate;METHYL ALPHA-CHLOROACRYLATE;methyl2-chloro-2-propenoate
CBNumber:
CB9436196
Molecular Formula:
C4H5ClO2
Molecular Weight:
120.53
MDL Number:
MFCD00051368
MOL File:
80-63-7.mol
MSDS File:
SDS
Last updated:2024-03-14 15:18:32

METHYL ALPHA-CHLOROACRYLATE Properties

Melting point -37 °C
Boiling point 52 °C (50 mmHg)
Density 1.189
refractive index 1.442-1.444
Flash point 33 °C
storage temp. Keep in dark place,Inert atmosphere,2-8°C
form Liquid
color Clear colorless to slightly brown
EWG's Food Scores 1
FDA UNII 47PG4L077J
EPA Substance Registry System Methyl 2-chloroacrylate (80-63-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06
Signal word  Danger
Hazard statements  H330-H301-H311-H314-H226
Precautionary statements  P260-P271-P284-P304+P340-P310-P320-P403+P233-P405-P501-P264-P270-P301+P310-P321-P330-P405-P501-P280-P302+P352-P312-P322-P361-P363-P405-P501-P260-P264-P280-P301+P330+P331-P303+P361+P353-P363-P304+P340-P310-P321-P305+P351+P338-P405-P501
Hazard Codes  T+
Risk Statements  34-26-24/25-10
Safety Statements  45-38-36/37/39-26-16
RIDADR  2927
HazardClass  6.1(a)
PackingGroup  II
HS Code  29161995

METHYL ALPHA-CHLOROACRYLATE price More Price(2)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M296468 Methyl2-Chloroacrylate 80-63-7 5g $85 2021-12-16 Buy
American Custom Chemicals Corporation HCH0327969 METHYL-2-CHLOROACRYLATE 95.00% 80-63-7 5MG $498.63 2021-12-16 Buy
Product number Packaging Price Buy
M296468 5g $85 Buy
HCH0327969 5MG $498.63 Buy

METHYL ALPHA-CHLOROACRYLATE Chemical Properties,Uses,Production

Description

Methyl 2-chloroacrylate is a colorless liquid.Molecular weight = 120.54; Boiling point = 52℃ at51 mmHg. Hazard Identification (based on NFPA-704 MRating System): Health 3, Flammability 3, Reactivity 0.Slightly soluble in water; solubility 5 ,1 mg/mL at 22℃.

Chemical Properties

Methyl 2-chloroacrylate is a colorless liquid.

Chemical Properties

clear colorless to pale yellow liquid

Uses

Methyl 2-Chloroacrylate is used as a reagent in various coupling reactions.

General Description

Colorless liquid. Used to make acrylic high polymer with properties closely resembling those of polymethylmethacrylate. Monomer for specialty polymers (e.g., aircraft glazing).

Air & Water Reactions

Insoluble in water.

Reactivity Profile

METHYL ALPHA-CHLOROACRYLATE is sensitive to prolonged exposure to light, moisture and heat. METHYL ALPHA-CHLOROACRYLATE is incompatible with oxidizers and polymerizers.

Health Hazard

METHYL ALPHA-CHLOROACRYLATE is a skin, eye, and lung irritant. The least trace on skin raises large blisters. It is also a respiratory poison; breathing the vapors can cause pulmonary edema.

Fire Hazard

Flash point data for METHYL ALPHA-CHLOROACRYLATE are not available; however, METHYL ALPHA-CHLOROACRYLATE is probably combustible.

Potential Exposure

Used to make acrylic high polymer with properties closely resembling those of polymethylmethacrylate. Monomer for specialty polymers e.g., aircraft glazing). Corrosive. Lacrimator.

First aid

If this chemical gets into the eyes, remove any con-tact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seek medi-cal attention immediately. If this chemical contacts the skin,remove contaminated clothing and wash immediately withsoap and water. Seek medical attention immediately. If thischemical has been inhaled, remove from exposure, begin res-cue breathing (using universal precautions, including resusci-tation mask) if breathing has stopped and CPR if heart actionhas stopped. Transfer promptly to a medical facility. Whenthis chemical has been swallowed, get medical attention.Give large quantities of water and induce vomiting. Do notmake an unconscious person vomit. Medical observation isrecommended for 24- -48 h after breathing overexposure, aspulmonary edema may be delayed. As first aid for pulmonaryedema, a doctor or authorized paramedic may consideradministering a corticosteroid spray.

storage

Color Code—Red: Flammability Hazard: Store ina flammable liquid storage area or approved cabinet awayfrom ignition sources and corrosive and reactive materials.Color Code—Blue: Health Hazard/Poison: Store in a securepoison location. Prior to working with this chemical youshould be trained on its proper handling and storage. Storein tightly closed containers in a cool, well-ventilated areaaway from oxidizers and reducing agents. Where possible,automatically pump liquid from drums or other storage containers to process containers.

Shipping

UN2929 Toxic liquids, flammable, organic, n.o.s., Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard, 3-Flammable liquid, Technical Name Required.

Incompatibilities

apor may form explosive mixture with air. May hydrolyze upon contact with moisture. Incompatible with nitrates. Methyl 2-chloroacrylate is sensitive to prolonged exposure to light, moisture and heat. Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, epoxides, and polymerizers. Compounds of the carboxyl group react with all bases, both inorganic and organic (i.e., amines) releasing substantial heat, water and a salt that may be harmful. Incompatible with arsenic compounds (releases hydrogen cyanide gas), diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides (releasing heat, toxic, and possibly flammable gases), thiosulfates and dithionites (releasing hydrogen sulfate and oxides of sulfur). May be a polymerization hazard

50-00-0
96-34-4
80-63-7
Synthesis of METHYL ALPHA-CHLOROACRYLATE from Formaldehyde and Methyl chloroacetate
Global( 124)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
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+86-371-66670886 info@dakenam.com China 15928 58
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View Lastest Price from METHYL ALPHA-CHLOROACRYLATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
METHYL ALPHA-CHLOROACRYLATE pictures 2019-08-08 METHYL ALPHA-CHLOROACRYLATE
80-63-7
US $1.00 / KG 1KG 98% 1000KG Career Henan Chemical Co
METHYL-A-CHLOROACRYLATE METHYL ALPHA-CHLOROACRYLATE METHYL CHLOROACRYLATE Methyl alpha-chloroacrylate, stabilized with hydroquinone, 98+% Methyl alpha-chloroacrylate, 98+%, stabilized with hydroquinone Methyl alpha-chloroacrylate, stabilized with hydroquinone, 99% 25GR Methyl 2-Chloroacrylate (stabilized with HQ) Methyl alpha-chloroacrylate, 99%, stabilized α-Chloroacrylic acid methyl ester Methyl alpha-chloroacrylate,99%,stabilized with hydroquinone Acryli Methyl alpha-chloroacrylate, stabilized with hydroquinone, 99% 2-chloro-2-propenoicacid,methylester 2-chloro-2-propenoicacimethylester 2-Chloroacrylic acid, methyl ester 2-chloroacrylicacid,methylester 2-chloro-acrylicacimethylester 2-Chloropropenoic acid, methyl ester 2-Propenoic acid, 2-chloro-, methyl ester Acrylic acid, 2-chloro-, methyl ester chloro-2acrylatedemethyle Methyl 2-chloropropenoate methyl2-chloro-2-propenoate Methylester kyseliny 2-chlorakrylove methylesterkyseliny2-chlorakrylove methylesterkyseliny2-chlorakrylove(czech) Methyl 2-Chloroacrylate (stabilized with HQ) > Methyl 2-chloroprop-2-enoate alpha-Chloroacrylic Acid Methyl Ester Methyl 2-Chloroacrylate (stabilized with hydroquinone) 80-63-7 METHYL ALPHA-CHLOROACRYLATE METHYL 2-CHLORO-2-PROPENATE METHYL 2-CHLOROACRYLATE Methyl 2-chloro-2-propenoate 80-63-7 monomer