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TRI-TERT-BUTYL BORATE

CAS No.
7397-43-5
Chemical Name:
TRI-TERT-BUTYL BORATE
Synonyms
BORON T-BUTOXIDE;ritert-butylborate;BORON TERT-BUTOXIDE;TRI-TERT-BUTOXYBORANE;TRI-TERT-BUTYL BORATE;Tri-tert-butyl borate 98%;Tri-tert-butyl borate,98%;boricacidtri-tert-butylester;Tri(1,1-dimethylethoxy)borane;Boric acid tri(1,1-dimethylethyl) ester
CBNumber:
CB9457210
Molecular Formula:
C12H27BO3
Molecular Weight:
230.15
MDL Number:
MFCD00009652
MOL File:
7397-43-5.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

TRI-TERT-BUTYL BORATE Properties

Melting point 18-19 °C (lit.)
Boiling point 101 °C/74 mmHg (lit.)
Density 0.811 g/mL at 25 °C (lit.)
refractive index n20/D 1.389(lit.)
Flash point 85 °F
storage temp. Flammables area
form Liquid
color Colorless
Specific Gravity 0.811
Hydrolytic Sensitivity 7: reacts slowly with moisture/water

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS02
Signal word  Warning
Hazard statements  H226
Precautionary statements  P210-P240-P241-P280a-P303+P361+P353-P501a
Risk Statements  10
Safety Statements  16-33
RIDADR  UN 1993 3/PG 3
WGK Germany  3
TSCA  No
HazardClass  3.2
PackingGroup  III
NFPA 704
2
0 0

TRI-TERT-BUTYL BORATE price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 236608 Tri-tert-butyl borate 98% 7397-43-5 50g $90 2024-03-01 Buy
Alfa Aesar H55461 Tri-tert-butyl borate 97% 7397-43-5 5g $57.65 2024-03-01 Buy
Alfa Aesar H55461 Tri-tert-butyl borate 97% 7397-43-5 25g $216.65 2024-03-01 Buy
TRC T795298 tris(Oxo[(oxoboranyl)oxy]borane)bis(tris(Propan-2-yloxy)borane) 7397-43-5 500mg $90 2021-12-16 Buy
American Custom Chemicals Corporation ING0006878 TRI-TERT-BUTYL BORATE 95.00% 7397-43-5 50G $2583.16 2021-12-16 Buy
Product number Packaging Price Buy
236608 50g $90 Buy
H55461 5g $57.65 Buy
H55461 25g $216.65 Buy
T795298 500mg $90 Buy
ING0006878 50G $2583.16 Buy

TRI-TERT-BUTYL BORATE Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS LIQUID

Uses

Tri-tert-butyl borate can be used as:

  • An additive in the synthesis of chiral α-hydroxy esters by reacting dimethylzinc with α-ketoesters using (?)-2-exo-morpholinoisobornane-10-thiol.
  • A starting material in the synthesis of boronate of (+)-pinane-2,3-diol.

Synthesis Reference(s)

The Journal of Organic Chemistry, 43, p. 2731, 1978 DOI: 10.1021/jo00407a051

General Description

Tri-tert-butyl borate is an organoborate commonly used to prepare other borate esters. It is also used as a substrate in Rh-catalyzed carbonylation reactions.

TRI-TERT-BUTYL BORATE Preparation Products And Raw materials

Raw materials

Preparation Products

TRI-TERT-BUTYL BORATE Suppliers

Global( 37)Suppliers
Supplier Tel Email Country ProdList Advantage
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
Alfa Chemistry
+1-5166625404 Info@alfa-chemistry.com United States 21317 58
GIHI CHEMICALS CO.,LIMITED
+8618058761490 info@gihichemicals.com China 49999 58
Shanghai Acmec Biochemical Technology Co., Ltd.
+undefined18621343501 product@acmec-e.com China 33349 58
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006608290; 18621169109 market03@meryer.com China 40241 62
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30132 84
Shanghai Hanhong Scientific Co.,Ltd. 021-54306202 13764082696; info@hanhongsci.com China 42982 64
Tianjin heowns Biochemical Technology Co., Ltd. 400 638 7771 sales@heowns.com China 14443 57
Shanghai Nuohey Chemical Co., Ltd. 021-52212593 13761626812 sales@nuohey.com China 10692 60
Shanghai Balmxy Pharmaceutical Co., Ltd 021-24206007 13764915196 sales@balmxy.com China 6719 55
Tri(1,1-dimethylethoxy)borane Tri-tert-butyl borate,98% Tri-tert-butyl borate,Boron tert-butoxide, Tri-tert-butoxyborane Tri-tert-butyl borate 98% Boric acid,tris(1,1-dimethylethyl) ester boricacidtri-tert-butylester BORON T-BUTOXIDE TRI-TERT-BUTYL BORATE TRI-TERT-BUTOXYBORANE BORON TERT-BUTOXIDE Boron tert-butoxide, Tri-tert-butoxyborane Boric acid tri(1,1-dimethylethyl) ester ritert-butylborate tris(Oxo[(oxoboranyl)oxy]borane) bis(tris(Propan-2-yloxy)borane) 7397-43-5 CH33CO3B Organoborates Organometallic Reagents Boronic Acids and Derivatives