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D(+)-Phenylalaninol

D(+)-Phenylalaninol structure

CAS No.: 5267-64-1

Chemical Name:: D(+)-Phenylalaninol

Synonyms: D-PHENYLALANINOL;H-D-PHE-OL;D-Phenylalanino;(R)-2-AMINO-3-PHENYL-1-PROPANOL;(2R)-2-amino-3-phenylpropan-1-ol;(R)-2-AMINO-3-PHENYL-PROPAN-1-OL;H-D-Phen-ol;R-228060-001;D-PHENYLANINOL;D-PHEYLALANINOL

CBNumber:: CB9741308

Molecular Formula:: C9H13NO

Molecular Weight:: 151.21

MDL Number:: MFCD00064298

MOL File:: 5267-64-1.mol

MSDS File:: SDS

Last updated:2024-01-21 21:00:53

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D(+)-Phenylalaninol Properties

Melting point	93-95 °C(lit.)
Boiling point	122 °C / 4mmHg
alpha	23 º (c=1.2, 1 N HCl 22 ºC)
Density	1.0406 (rough estimate)
refractive index	23.5 ° (C=1.2, 1mol/L HCl)
storage temp.	Keep in dark place,Sealed in dry,Room Temperature
solubility	Soluble in Dichloromethane, Ethyl Acetate, Methanol.
form	Crystalline Powder and Chunks
pka	12.85±0.10(Predicted)
color	White to yellow
optical activity	[α]/D +22.8°, c = 1.2 in 1 M HCl
Sensitive	Air Sensitive
BRN	4665408
InChI	InChI=1/C9H13NO/c10-9(7-11)6-8-4-2-1-3-5-8/h1-5,9,11H,6-7,10H2/t9-/s3
InChIKey	STVVMTBJNDTZBF-DJEYLCQNNA-N
SMILES	C(C1C=CC=CC=1)[C@@H](N)CO \|&1:7,r\|
CAS DataBase Reference	5267-64-1(CAS DataBase Reference)
FDA UNII	A6QY3U3O3V

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05

Signal word

Danger

Hazard statements

H314

Precautionary statements

P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363

Hazard Codes

C,Xi

Risk Statements

Safety Statements

26-36/37/39-45-27

RIDADR

UN 3259 8/PG 3

WGK Germany

10-23

HazardClass

IRRITANT

HazardClass

PackingGroup

III

HS Code

29221990

NFPA 704

	0
3		0

D(+)-Phenylalaninol price More Price(32)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	284491	(R)-(+)-2-Amino-3-phenyl-1-propanol 98%	5267-64-1	5g	$142	2023-01-07	Buy
TCI Chemical	P1289	D-Phenylalaninol >98.0%(GC)(T)	5267-64-1	5g	$72	2024-03-01	Buy
TCI Chemical	P1289	D-Phenylalaninol >98.0%(GC)(T)	5267-64-1	25g	$218	2024-03-01	Buy
Alfa Aesar	L09697	D-Phenylalaninol, 98%	5267-64-1	1g	$40.65	2024-03-01	Buy
Usbiological	019430	D-Phenylalaninol	5267-64-1	5g	$403	2021-12-16	Buy

Product number	Packaging	Price	Buy
284491	5g	$142	Buy
P1289	5g	$72	Buy
P1289	25g	$218	Buy
L09697	1g	$40.65	Buy
019430	5g	$403	Buy

D(+)-Phenylalaninol Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

D-Phenylalaninol is used as a chiral auxiliary for asymmetric Michael reactions. It is an enantiomer of L-Phenylalaninol, an inhibitor of intestinal Phenylalanine absorption. It acts as an inhibiting agent to the enzymes which are responsible for the breakdown of endorphins.

Purification Methods

It can be recrystallised from Et2O, *C6H6/pet ether (b 40-60o) or toluene and distilled in a vacuum. It has been purified by dissolving in Et2O, drying over K2CO3, filtering, evaporating to a small volume, cooling in ice and collecting the plates. Store them in the presence of KOH (i.e. CO2—free atm). [Karrer & Ehrhardt Helv Chim Acta 34 3203 1951, Oeda Bull Chem Soc Jpn 13 465 1938.] The picrate has m 141-141.5o (from EtOH/pet ether). The hydrogen oxalate has m 177o, 161-162o [Hunt & McHale J Chem Soc 2073 1957]. The racemate has m 87-88o from *C6H6/pet ether (75-77o from Et2O), and the hydrochloride has m 139-141o [Fodor et al. J Chem Soc 1858 1951]. [Beilstein 13 IV 1920.]

D(+)-Phenylalaninol Preparation Products And Raw materials

Raw materials

(R)-2-Amino-3-phenylpropionic acid methylester FMOC-D-PHENYLALANINOL (2R)-3-PHENYL-1,2-PROPANEDIAMINE D-Phenylalanine

Preparation Products

Cbz-D-Phenylalaninol 1-[(4R)-4-(phenylmethyl)-2-thioxo-3-thiazolidinyl]-Ethanone TMC-58B

D(+)-Phenylalaninol Suppliers

Global( 508)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Chongqing Chemdad Co., Ltd	+86-023-61398051 +8613650506873	sales@chemdad.com	China	39916	58
Zhengzhou Anbu Chem Co.,Ltd	+86-0371-88006763; +8615988602810	sales@anbuchem.com	China	3000	58
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12456	58
Sichuan HongRi Pharma-Tech Co.,Ltd	+86-028-64841719 +8618980456393	daisy@enlaibio.com	China	1369	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21691	55
Shanghai Time Chemicals CO., Ltd.	+86-021-57951555 +8617317452075	jack.li@time-chemicals.com	China	1807	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Accela ChemBio Inc.	(+1)-858-699-3322	info@accelachem.com	United States	19965	58
Hebei Guanlang Biotechnology Co., Ltd.	+86-19930503282	alice@crovellbio.com	China	8823	58

Supplier	Advantage
Chongqing Chemdad Co., Ltd	58
Zhengzhou Anbu Chem Co.,Ltd	58
Hebei Mojin Biotechnology Co., Ltd	58
Sichuan HongRi Pharma-Tech Co.,Ltd	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
Shanghai Time Chemicals CO., Ltd.	55
career henan chemical co	58
Accela ChemBio Inc.	58
Hebei Guanlang Biotechnology Co., Ltd.	58

View Lastest Price from D(+)-Phenylalaninol manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-24	d-phe-ol 5267-64-1	US $0.00-0.00 / kg	1kg	98%	1T+	Sichuan HongRi Pharma-Tech Co.,Ltd
2024-03-16	D(+)-Phenylalaninol 5267-64-1	US $0.00 / KG	100g	98%+	100kg	WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD
2023-08-18	D(+)-Phenylalaninol 5267-64-1	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd

d-phe-ol
5267-64-1
US $0.00-0.00 / kg
98%
Sichuan HongRi Pharma-Tech Co.,Ltd

D(+)-Phenylalaninol
5267-64-1
US $0.00 / KG
98%+
WUHAN CIRCLE POWDER TECHNOLOGY CO.,LTD

D(+)-Phenylalaninol
5267-64-1
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

D(+)-Phenylalaninol Spectrum

D(+)-Phenylalaninol(5267-64-1)MS D(+)-Phenylalaninol(5267-64-1)¹HNMR D(+)-Phenylalaninol(5267-64-1)¹³CNMR D(+)-Phenylalaninol(5267-64-1)IR1 D(+)-Phenylalaninol(5267-64-1)IR2 D(+)-Phenylalaninol(5267-64-1)Raman

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D-(+)-Phenylalinol S/R-Phenylalaninol BENZENEPROPANOL, .BETA.-AMINO-, (.BETA.R)- D-Penylalaninol D-PHEYLALANINOL D-PHENYLANINOL (D)-(+)-2-PHENYLALANINOL / D-(+)-2-AMINO-3-PHENYL-1-PROPANOL D-Phenylalaninol(R+Phenylalaninol) Benzenepropanol, beta-amino-, (R)- D-Phenylalaninol ,98% (R)-3-Phenyl-2-amino-1-propanol (R)-3-Phenyl-2-aminopropane-1-ol (αR)-α-(Hydroxymethyl)benzeneethanamine H-D-Phen-ol D(+)-2-Amino-3-phenyl-1-propanol,98% D-PHENYLALANINOL ((R)-(+)-2-AMINO-3-PHENYL-1-PROPANOL) ((1R)-1-HydroxyMethyl-2-phenylethyl)aMine (2R)-2-AMino-3-phenyl-1-propanol (R)-(+)-2-AMino-3-phenyl-1-glycinol (R)-2-AMino-1-hydroxy-3-phenylpropane (R)-2-BenzylethanolaMine (βR)-β-AMino-benzenepropanol D-Phenylalaninol, (2R)-2-Amino-1-hydroxy-3-phenylpropane BENZENEPROPANOL, B-AMINO-, (BR)- D-(R)-PHENYLALANINOL (+)-D-PHENYLALANINOL D(+)-PHENYLALANINOL D-ALPHA-PHENYLALANINOL D(+)-2-AMINO-3-PHENYL-1-PROPANOL D-2-PHENYLALANINOL H-D-PHENYLALANINOL (R)-(+)-2-AMINO-3-PHENYL-1-PROPANOL (R)-(+)-PHENYLALANINOL (R)-PHENYLALANINOL PHENYLALANINOL-D (R)-2-amino-3-phenylpropanol (R)-2-Amino-3-phenyl-1-propanol D(+)-Phenylalaninol D(+)-2-Amino-3-phenyl-1-propanol D-2-Amino-3-phenyl-1-propanol,99%e.e. (R)-(+)-2-Amino-3-phenyl-1-propanol 98% R-228060-001 D-Phenylalaninol> Benzenepropanol, β-amino-, (βR)- D(+)-Phenylalaninol USP/EP/BP D-(+)-2-Amino-3-phenyl-1-proanol (+)-D-Phenylalaninol (2R)-2-amino-3-phenylpropan-1-ol D-PHENYLALANINOL (R)-2-AMINO-3-PHENYL-1-PROPANOL (R)-2-AMINO-3-PHENYL-PROPAN-1-OL D-Phenylalanino H-D-PHE-OL 5267-64-1 15267-64-1 Amino Alcohols (Chiral) Chiral Building Blocks Asymmetric Synthesis Amino Acid Derivatives Amino Alcohols