ChemicalBook >> CAS DataBase List >>(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine

CAS No.
104372-31-8
Chemical Name:
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine
Synonyms
(-)-CAMPHORSULFONYLOXAZIRIDINE;(10-camphorsulfonyl)oxaziridine;R-(10-Camphorsulfonyl)oxaziridine;(R)-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(-)-((CAMPHORYL) SULFONYL)OXAZIRIDINE;(1R)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE;(1R)-(-)-(10-Camphorsulfonyl)oxaziridin;(1R)-(-)-(10-CAMPHORSULFONYL)OXAZIRIDINE;(1R)-(-)-2,N-EPOXY-EXO-10,2-BORNANESULTAM;(1R)-(-)-(10-CAMPHORSULPHONYL)OXAZIRIDINE
CBNumber:
CB9768000
Molecular Formula:
C10H15NO3S
Molecular Weight:
229.3
MDL Number:
MFCD00075428
MOL File:
104372-31-8.mol
Last updated:2023-08-17 18:11:45

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Properties

Melting point 170-174 °C
Boiling point 317.6±25.0 °C(Predicted)
alpha -46.6 º (c=2, CHCl3 25 ºC)
Density 1.2486 (rough estimate)
refractive index 1.5060 (estimate)
Flash point 170℃
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
pka -11.75±0.40(Predicted)
form Powder
color White
optical activity [α]20/D 44°, c = 2.2 in chloroform
BRN 6274369
CAS DataBase Reference 104372-31-8(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-24/25
WGK Germany  3
10
HS Code  29349990
NFPA 704
1
0 0

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine price More Price(34)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 349003 (1R)-(?)-(10-Camphorsulfonyl)oxaziridine 104372-31-8 1g $109.2 2024-03-01 Buy
TCI Chemical C1327 (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent] >95.0%(T) 104372-31-8 1g $30 2024-03-01 Buy
TCI Chemical C1327 (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent] >95.0%(T) 104372-31-8 5g $88 2024-03-01 Buy
Alfa Aesar H59544 (1R,2S)-(-)-2,N-Epoxy-10,2-camphorsultam, 96% 104372-31-8 1g $93.65 2024-03-01 Buy
TRC C175095 (1R)-(-)-(10-Camphorsulfonyl)oxaziridine 104372-31-8 50g $405 2021-12-16 Buy
Product number Packaging Price Buy
349003 1g $109.2 Buy
C1327 1g $30 Buy
C1327 5g $88 Buy
H59544 1g $93.65 Buy
C175095 50g $405 Buy

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Chemical Properties,Uses,Production

Chemical Properties

White crystalline powder

Uses

Reactant involved in:

  • Asymmetric synthesis of proton pump inhibitors
  • Asymmetric synthesis of polyhydroxylated pyrrolidines
  • Diastereoselective hydroxylation of chlorophylls a and b enolate anions

Used in impregnated silica nanoparticles for removal of sulfur mustard from wastewater

Used to modify blebbistatin for investigations of myosin inhibitor design

Uses

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine is a useful synthetic intermediate. Used for asymmetric hydroxylation.

107869-45-4
104372-31-8
Synthesis of (1R)-(-)-(10-Camphorsulfonyl)oxaziridine from (+)-10-CAMPHORSULFONIMINE

(1R)-(-)-(10-Camphorsulfonyl)oxaziridine Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 240)Suppliers
Supplier Tel Email Country ProdList Advantage
Changzhou Chontech Baocheng Chemical Co.,Ltd
+86-51982698291; +undefined15295095616 info@hhbhswkj.com China 73 58
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12453 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15371 58
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3012 60
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8822 58
Xi'an Kono chem co., Ltd.,
029-86107037 13289246953 info@konochemical.com China 2995 58

View Lastest Price from (1R)-(-)-(10-Camphorsulfonyl)oxaziridine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine pictures 2023-08-18 (1R)-(-)-(10-Camphorsulfonyl)oxaziridine
104372-31-8
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
(1R)-(-)-(10-Camphorsulfonyl)oxaziridine pictures 2023-02-18 (1R)-(-)-(10-Camphorsulfonyl)oxaziridine
104372-31-8
US $0.00-0.00 / kg 1kg 98% kgs Aromsyn Co., Ltd.
(1(R))-()-(10-Camphorsulfonyl)oxaziridine pictures 2022-09-19 (1(R))-()-(10-Camphorsulfonyl)oxaziridine
104372-31-8
US $20.00 / kg 1kg 99% 5000 tons Hebei Duling International Trade Co. LTD
(-)-(2S,8AR)-(CAMPHORSULFONYL)OXAZIRIDINE (2S,8AR)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE (1R)-(-)-(10-CAMPHORSULFONYL)OXAZIRIDINE (1R)-(-)-(10-CAMPHORSULPHONYL)OXAZIRIDINE (1R)-(-)-2,N-EPOXY-EXO-10,2-BORNANESULTAM (1R)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE (R)-2,N-EPOXY-EXO-10,2-BORNANESULTAM (-)-((CAMPHORYL) SULFONYL)OXAZIRIDINE (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent] (-)-CAMPHORSULFONYLOXAZIRIDINE (-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine, 99+% ee, 99+% 4H-4a,7-Methanooxazirino3,2-i2,1benzisothiazole, tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aR,7S,8aR)- (2S,8AS)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE (2S 8AR)-(-)-(CAMPHORYLSULFONYL)OXAZIRIDINE [ASYMMETRIC OXIDIZING GRADE] 98+% R-(10-Camphorsulfonyl)oxaziridine Tetrahydro-9,9-dimethyl-4H-4a,7-methanooxazirino[3,2-i][2,1]benzisothiazole 3,3-dioxide (10-camphorsulfonyl)oxaziridine (1R)-(-)-(Camphorylsulfonyl)oxaziridine, (1R)-(-)-2,N-Epoxy-exo-10,2-bornanesultam (-)-(2S,8AR)-(Camphorylsulfonyl)oxaziridine, 98%, ee:99+% (-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine, 99+% ee (-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine,98+% (4aR,7S,8aR)-Tetrahydro-9,9-diMethyl-4H-4a,7-Methano-1,2-oxazirino[3,2-i]-2,1-benzisothiazole 3,3-Dioxide (1R,2S)-(-)-2,N-Epoxy-10,2-caMphorsultaM, 96% (1R)-(-)-(10-Camphorsulfonyl)oxaziridine 1R)-(-)-(Camphorylsulfonyl)oxaziridine (R)-(10-Camphorsulfonyl)oxaziridine,99%e.e. 7,7-dimethyl-4-(2-oxaziridinylsulfonylmethyl)-3-bicyclo[2.2.1]heptanone (1R)-(-)-(10-Camphorsulfonyl)oxaziridin (2S,8aR)-(-)-(Camphorylsulfonyl)oxaziridine [Asymmetric Oxidizing Reagent]> (-)-(2S,8aR)-(Camphorylsulfonyl)oxaziridine 4H-4a,7-Methanooxazirino[3,2-i][2,1]benzisothiazole, tetrahydro-9,9-dimethyl-, 3,3-dioxide, (4aR,7S,8aR)- (9CI, ACI) Tetrahydro-9,9-dimethyl-4H-4a,7-methanooxazirino3,2-i2,1benzisothiazole 3,3-dioxide (4aR,7S,8aR)- 104372-31-8 Oxidation Bicyclic Monoterpenes Terpenes Sulfur Compounds (for Synthesis) Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Hydroxylation Biochemistry Oxidation Sulfur Compounds (for Synthesis) Synthetic Organic Chemistry Terpenes Intermediates & Fine Chemicals Pharmaceuticals Asymmetric Synthesis Bicyclic Monoterpenes chiral Chiral Reagents