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Dimethomorph

Dimethomorph Structure
Dimethomorph structure
CAS No.
110488-70-5
Chemical Name:
Dimethomorph
Synonyms
4-(3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl)-morpholin (e,z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl]morpholine (e,z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)acryloyl]morpholine 4-(3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl)morpholine;dimethomoph;Z-DIMETHOMORPH;3-(4-Chlorophenyl)-3-(3,4-diMethoxyphenyl)-1-Morpholinoprop-2-en-1-one;3-(4-Chlorophenyl)-3-(3,4-diMethoxyphenyl)-1-(4-Morpholinyl)-2-propen-1-one;FORUM;ACROBAT;CME 151;AcrobatWP;Festival C
CBNumber:
CB9774944
Molecular Formula:
C21H22ClNO4
Molecular Weight:
387.86
MDL Number:
MFCD01632781
MOL File:
110488-70-5.mol
MSDS File:
SDS
Last updated:2024-01-26 09:42:24
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Dimethomorph Properties

Melting point 125-149°C
Boiling point 584.9±50.0 °C(Predicted)
Density 1.231±0.06 g/cm3(Predicted)
vapor pressure 1 x 10-6 Pa (25 °C)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform: Soluble,Methanol: Soluble
pka -1.19±0.20(Predicted)
Water Solubility 50 mg l-1 (20-23 °C)
Merck 13,3248
BRN 8794474
LogP 2.680
FDA UNII 3EXL2158GV
Pesticides Freedom of Information Act (FOIA) Dimethomorph
EPA Substance Registry System Dimethomorph (110488-70-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS08,GHS09
Signal word  Danger
Hazard statements  H360F-H411
Precautionary statements  P202-P273-P280-P308+P313-P391-P405
Hazard Codes  N
Risk Statements  51/53
Safety Statements  61
RIDADR  UN3077 9/PG 3
WGK Germany  2
RTECS  QE0478300
Toxicity LD50 in rats (mg/kg): 321 i.p.; 3900 orally; >5000 dermally; LC50 (4-hr inhalation): >4.2 mg/ml (Veenstra, Owen)

Dimethomorph price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 46027 Dimethomorph mixture of E + Z isomers 110488-70-5 100mg $101 2024-03-01 Buy
Cayman Chemical 24247 Dimethomorph ≥95% 110488-70-5 50mg $44 2024-03-01 Buy
Cayman Chemical 24247 Dimethomorph ≥95% 110488-70-5 100mg $74 2024-03-01 Buy
TRC D460530 Dimethomorph 110488-70-5 5g $590 2021-12-16 Buy
American Custom Chemicals Corporation HCH0012814 4-[3-(4-CHLOROPHENYL)-3-(3,4-DIMETHOXYPHENYL)-1-OXO-2-PROPENYL]-MORPHOLINE 95.00% 110488-70-5 1G $716.1 2021-12-16 Buy
Product number Packaging Price Buy
46027 100mg $101 Buy
24247 50mg $44 Buy
24247 100mg $74 Buy
D460530 5g $590 Buy
HCH0012814 1G $716.1 Buy

Dimethomorph Chemical Properties,Uses,Production

Description

Dimethomorph is a cinnamic acid derivative and a member of the morpholine chemical family. Dimethomorph is a mixture of E- and Z-isomers in the ratio of about 1:1 and only the Z-isomer has the fungicidal activity. It fungicidal activity works by the inhibition of sterol (ergosterol) synthesis.
Dimethomorph is a systemic fungicide to protect against various fungal pathogens in vines and other crops. Dimethomorph is used to against downy mildews, late blights, anthracnose, septoria leaf spot, crown rot, and root rot for curbubits, grapevines, head lettuce, onions, potatoes, tomatoes, and fruit including blackberries, raspberries, strawberries.

References

[1] http://www.fao.org
[2] http://pmep.cce.cornell.edu
[3] http://sitem.herts.ac.uk/aeru/ppdb/en/Reports/245.htm

Description

Dimethomorph is a morpholine fungicide that inhibits fungal cell wall formation. It inhibits mycelial growth of the oomycete fungi P. citrophthora, P. parasitica, P. capsici, and P. infestans (EC50s = 0.14, 0.38, <0.1, and 0.16-0.3 μg/ml, respectively) but is less active against the green algae species C. vulgaris or S. obliquus in vitro (EC50s = 47.46 and 44.87 μg/ml, respectively). It inhibits androgen receptor (AR) activity in a reporter assay in MDA-kb2 human breast cancer cells but not in a yeast antiandrogen screen (IC20s = 0.263 and 38.5 μM, respectively). It is not toxic to rats (LD50 = 3,900 mg/kg) or goldfish (C. auratus; LC50 = >32 μg/ml).

Chemical Properties

Off-White Solid

Uses

Agricultural fungicide.

Uses

Dimethomorph is a systemic fungicide which exhibits protectant, curative and antisporulant activities. It is active against fungal diseases such as leaf blight, downy mildew, damping off and foot-rot caused by Phytophthora spp. in/on grapes, potatoes and tomatoes.

Definition

ChEBI: A mixture of (E)- and (Z)-dimethomorph in an unspecified ratio. It is used as a systemic fungicide used on vines, potatoes, and greenhouse crops; only the Z isomer has fungicidal activity.

Agricultural Uses

Fungicide: A systemic fungicide that protects crops from mold. It also kills mold and prevents their spread; controls late blight on tomatoes; and is used as a wood preservative to control downey mildew.

Trade name

ACROBAT® WP; FORUM DC®, [manco- zeb + dimethomorph]; CME 151®; STATURE®

Metabolic pathway

Limited data are available in the open literature. Information presented in this summary is abstracted from the data evaluation published by the Pesticide Safety Directorate (PSD, 1994). Dimethomorph is a (1:l) mixture of the E- and Z-isomers. The Z-isomer has been shown to have all the intrinsic biological activities. The isomerisation of the E- and Z-isomers was observed when resolved isomers were exposed to UV light. Dimethomorph undergoes extensive degradation and metabolism in soil, plants and animals. The major metabolic pathway is the O-demethylation of one of the phenolic methoxy moieties to the corresponding phenols and conjugates. Other metabolic reactions include the oxidation of one of the CH2 moieties of the morpholine ring and the cleavage/opening of the morpholine ring (Scheme 1).

Degradation

Dimethomorph (1) is hydrolytically stable with no observable degradation in pH 4-9 buffered solutions at 70-90 °C for up to 10 weeks.
Degradation occurred when dimethomorph in pH 5 buffer solution was irradiated under Hanau Suntest apparatus (<290 nm) at 25 °C. The calculated aqueous photolytic degradation half-life (DT50) was ca. 25-28 days of continuous irradiation, No sigruficant degradation product (>7% of the applied radioactivity) was identified.

Dimethomorph Preparation Products And Raw materials

Raw materials

Preparation Products

Mancozeb+Dimethomorph,W.P.

Dimethomorph Suppliers

Global( 254)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12453 58
Henan Bao Enluo International TradeCo.，LTD 		+86-17331933971 +86-17331933971 deasea125996@gmail.com China 2503 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei Jusheng Technology Co.,Ltd. 		18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd. 		+86-19930503282 alice@crovellbio.com China 8822 58
Hubei xin bonus chemical co. LTD 		86-13657291602 linda@hubeijusheng.com CHINA 22968 58
BOC Sciences 		+1-631-485-4226 inquiry@bocsci.com United States 19553 58
Chongqing Chemdad Co., Ltd 		+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED 		+8618523575427 sales@conier.com China 47465 58
Supplier Advantage
Hebei Mojin Biotechnology Co., Ltd 		58
Henan Bao Enluo International TradeCo.，LTD 		58
Henan Tianfu Chemical Co.,Ltd. 		55
career henan chemical co 		58
Hubei Jusheng Technology Co.,Ltd. 		58
Hebei Guanlang Biotechnology Co., Ltd. 		58
Hubei xin bonus chemical co. LTD 		58
BOC Sciences 		58
Chongqing Chemdad Co., Ltd 		58
CONIER CHEM AND PHARMA LIMITED 		58

Related articles

View Lastest Price from Dimethomorph manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Dimethomorph pictures 2024-04-23 Dimethomorph
110488-70-5
 US $10900.00-10000.00 / Tons 1Tons 99.99% 200Tons Hebei Dangtong Import and export Co LTD
Dimethomorph pictures 2023-08-08 Dimethomorph
110488-70-5
 US $20.00 / kg 1kg 99.99% 50000tons Henan Bao Enluo International TradeCo.，LTD
Dimethomorph pictures 2023-08-02 Dimethomorph
110488-70-5
 US $20.00 / kg 1kg 99.99% 50000tons Henan Bao Enluo International TradeCo.，LTD
  • Dimethomorph pictures
  • Dimethomorph
    110488-70-5
  • US $10900.00-10000.00 / Tons
  • 99.99%
  • Hebei Dangtong Import and export Co LTD
  • Dimethomorph pictures
  • Dimethomorph
    110488-70-5
  • US $20.00 / kg
  • 99.99%
  • Henan Bao Enluo International TradeCo.，LTD
  • Dimethomorph pictures
  • Dimethomorph
    110488-70-5
  • US $20.00 / kg
  • 99.99%
  • Henan Bao Enluo International TradeCo.，LTD

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Dimethomorph W.P.(50%) Festival C Dimethomorph 100mg [110488-70-5] Dimethomorph 0 (e,z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl]morpholine (e,z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)acryloyl]morpholine 4-(3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl)-morpholin AcrobatWP ACROBAT Morpholine, 4-3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl- dimethomorph (bsi, draft-iso) 4-[3-(4-CHLOROPHENYL)-3-(3,4-DIMETHOXYPHENYL)-1-OXO-2-PROPENYL]-MORPHOLINE 4-[3-(4-Chlorophenyl)-3-(3,4-dimethoxyphenyl)acryloyl]morpholine CME 151 DIMETHOMORPH FORUM Dimethomorph{(E,Z)-4-[3-(4-Chlorophenyl)-3-(3,4-Dimethoxphenyl)Acryloy]Morpholine Dimethoroph DIMETHOMORPH MIXTURE OF E + Z ISOMERS, P Factory hot sell Dimethomorph CAS:110488-70-5 with best price Dimethomorph（mixture of E + Z isomers） Acrobat(TM) Dimethomorph +Ametoctradin Dimethomorph in Methanol Dimethomorph Solution in Acetonitrile (E)-3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-morpholinoprop-2-en-1-one Dimethomorph Solution, 1000ppm DimethomorphSolution,1000mg/L,1ml DimethomorphSolution,100mg/L,5x1ml DimethomorphSolution,100mg/L,1ml Dimethomorph (E, Z)@1000 μg/mL in Acetonitrile Dimethomorph @100 μg/mL in MeOH Dimethomorph 50%WP Chemical Fungicides Products 110488-70-5 White powder Chemical Pesticide Dimethomorph Fungicide 50%WP 110488-70-5 imethomorph Dimethomorph (0.1 mg/mL in Acetonitrile) Acroyl]-Dimethomorph 13C 3-(4-Chlorophenyl)-3-(3,4-diMethoxyphenyl)-1-(4-Morpholinyl)-2-propen-1-one 3-(4-Chlorophenyl)-3-(3,4-diMethoxyphenyl)-1-Morpholinoprop-2-en-1-one dimethomoph 4-(3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl)-morpholin (e,z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl]morpholine (e,z)-4-[3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)acryloyl]morpholine 4-(3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-oxo-2-propenyl)morpholine Z-DIMETHOMORPH 2-Propen-1-one, 3-(4-chlorophenyl)-3-(3,4-dimethoxyphenyl)-1-(4-morpholinyl)- Enoylmorpholine technical 110488-70-5 C21H22ClNO4 Alpha sort D DAlphabetic DID - DINPesticides Fungicides Morpholines Pesticides&Metabolites Agro-Products Aromatics Heterocycles INSECTICIDE