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L-tert-Leucine

CAS No.
20859-02-3
Chemical Name:
L-tert-Leucine
Synonyms
LEUCINE;LEU;H-LEU-OH;Tle;L-tertiary leucine;H-L-LEU-OH;L-Tle-OH;L-tert-Leu-OH;L-A-AMINOISOCAPROIC ACID;(S)-2-Amino-3,3-dimethylbutanoicacid
CBNumber:
CB9853319
Molecular Formula:
C6H13NO2
Molecular Weight:
131.17
MDL Number:
MFCD00064218
MOL File:
20859-02-3.mol
MSDS File:
SDS
Last updated:2024-04-12 23:00:59

L-tert-Leucine Properties

Melting point ≥300 °C (lit.)
alpha 6.3 º (c=4, 6 N HCl 200 ºC)
Boiling point 217.7±23.0 °C(Predicted)
Density 1.1720 (estimate)
refractive index -9 ° (C=3, H2O)
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility 1 M HCl: 50 mg/mL
form powder
pka 2.39±0.12(Predicted)
color White to almost white
optical activity [α]20/D 9.5°, c = 3 in H2O
Water Solubility 125.5 g/L (20 ºC)
BRN 1721824
InChIKey NPDBDJFLKKQMCM-SCSAIBSYSA-N
CAS DataBase Reference 20859-02-3(CAS DataBase Reference)
FDA 21 CFR 310.545
EWG's Food Scores 1
FDA UNII 1E6RFC9IVP

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319
Precautionary statements  P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313-P362
Hazard Codes  Xi
Safety Statements  22-24/25
WGK Germany  3
RTECS  OH2850000
Hazard Note  Irritant
HS Code  29224999
NFPA 704
1
0 0

L-tert-Leucine price More Price(40)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 269107 L-tert-Leucine 99% 20859-02-3 5g $114 2024-03-01 Buy
Sigma-Aldrich 269107 L-tert-Leucine 99% 20859-02-3 25g $183 2024-03-01 Buy
TCI Chemical L0147 L-tert-Leucine >98.0%(T) 20859-02-3 1g $26 2024-03-01 Buy
TCI Chemical L0147 L-tert-Leucine >98.0%(T) 20859-02-3 5g $48 2024-03-01 Buy
Alfa Aesar L13707 L-tert-Leucine, 99% 20859-02-3 1g $46.65 2024-03-01 Buy
Product number Packaging Price Buy
269107 5g $114 Buy
269107 25g $183 Buy
L0147 1g $26 Buy
L0147 5g $48 Buy
L13707 1g $46.65 Buy

L-tert-Leucine Chemical Properties,Uses,Production

Description

L-tert-Leucine is an essential amino acid making up one third of our muscle protein. L-tert-leucine is important in developing chiral pharmaceutically active chemicals. It can be used as a food additive. It is used in the formation of sterols. It can also be used as the catalyst in the production of cobalt oxazoline palladacycles complex. It can also be used for the production of Chiral tridentate Schiff base ligands.

References

Korkmaz, Neslihan, D. Astley, and S. T. Astley. "Tridentate ligands derived from L-tert-Leucine for the Cu(II) mediated asymmetric Henry reaction." Turkish Journal of Chemistry 35.3(2011):1-17.
https://www.alfa.com/en/catalog/L13707/
http://igem.org/abstract_pdf_file.cgi?id=1719

Chemical Properties

White to almost white powder

Uses

L-tert-Leucine is an essential amino acid and makes up one third of our muscle protein. It can be used as a food additive. It is used in the formation of sterols. It is used in the production of cobalt oxazoline palladacycles complex, which acts as a catalyst in the rearrangement of prochiral N-aryl trifluoroacetimidates to allylic amides yielded in significantly higher enantioselectivities with the (S)-(pR)-diasteroisomer.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 3, p. 523, 1955
Tetrahedron Letters, 19, p. 4625, 1978 DOI: 10.1016/S0040-4039(01)85688-4

815-17-8
20859-02-3
Synthesis of L-tert-Leucine from 3,3-Dimethyl-2-oxobutyric acid
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View Lastest Price from L-tert-Leucine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
L-tert-Leucine pictures 2024-04-16 L-tert-Leucine
20859-02-3
US $30.00 / kg 1kg 99.7% 200000kg Ouhuang Engineering Materials (Hubei) Co., Ltd
L-Tle pictures 2024-04-16 L-Tle
20859-02-3
US $0.00-0.00 / kg 1kg 99% 1T+ Sichuan HongRi Pharma-Tech Co.,Ltd
L-tert-Leucine pictures 2024-04-09 L-tert-Leucine
20859-02-3
US $0.00 / KG 1KG ≥98% HPLC 1000KG Changsha Staherb Natural Ingredients Co., Ltd.
  • L-tert-Leucine pictures
  • L-tert-Leucine
    20859-02-3
  • US $30.00 / kg
  • 99.7%
  • Ouhuang Engineering Materials (Hubei) Co., Ltd
  • L-Tle pictures
  • L-Tle
    20859-02-3
  • US $0.00-0.00 / kg
  • 99%
  • Sichuan HongRi Pharma-Tech Co.,Ltd
  • L-tert-Leucine pictures
  • L-tert-Leucine
    20859-02-3
  • US $0.00 / KG
  • ≥98% HPLC
  • Changsha Staherb Natural Ingredients Co., Ltd.
(S)-(+)-LEUCINE RARECHEM AB PP 3754 L-A-AMINO-G-METHYL VALERIC ACID L-2-AMINO-4-METHYLVALERIC ACID LEUCINE, L- FEMA 3297 L-TERT-LEUCINE, 99% (99% EE/GLC) L-2-(T-BUTYL)GLYCINE l-2-tert-butylglycine LEUCINE, L-(P) α-aminoisocaproic acid L-tert-Leucine 99% L-tert-Leucine, 95+% L-α-tert-Butyl-Gly-OH L-α-tert-Butyl-Gly-OH≥ 99% (Titration) L-tert-Leucine,99%e.e. T-LEUCINE, T-BUTYLGLYCINE L-2-Amino-3,3-dimethylbutanoic acid L-tert-Leucine t-Leucine, t-Butylglycine, (S)-2-Amino-3,3-dimethyl-butyric acid (S)-2-Amino-3,3-dimethylbutyric acid L-α-tert-Butylglycine L-tert-Leucine, 99+% L-tert-B-leucine, 99% (-)-L-Pseudoleucine L-Pseudoleucine (2S)-2-AMino-3,3-diMethylbutanoic acid/l-t-leucine by express 2-L-aMino-3,3-diMethylbutyric acid L-(+)-TERT-LEUCINE FOR SYNTHESIS L-tert-Leucine 3 L-tert-Leucine, (2S)-2-Amino-3,3-dimethylbutanoic acid 3-Methyl-L-valine 97% L-2-Amino-3,3-dimethylbutanoic acid CAS -tert-L L-tert-Leucine> L-tert-Leucine USP/EP/BP L-A-AMINOISOCAPROIC ACID LEU LEUCINE H-L-LEU-OH H-LEU-OH (2S)-2-Amino-3,3-dimethylbutanoicacid L-tert-Leu-OH (S)-2-Amino-3,3-dimethylbutanoicacid L-tertiary leucine Tle L-Tle-OH L-α-tert-Butyl-Gly-OH L-α-tert-Butylglycine NSC203785 Enzymatic Hydrolysis Amino Acid Powder 80% (OMRI Listed ) L-tert-Leucine,97% 20859-02-3 RCHNH2COOH CH33CCHNH2CO2H CH32CHCH2CHNH2COOH AMINE BioChemika Ultra Biochemicals and Reagents