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Ethylthiocyanate

CAS No.
542-90-5
Chemical Name:
Ethylthiocyanate
Synonyms
ai3-18429;Aethylrhodanid;ethyl rhodonate;Ethylthiokyanat;ETHYL RHODANATE;ETHYL RHODANIDE;thiocyanato-ethan;ETHYL THIOCYANATE;ethyl thiocyanide;Thiocyanato-ethane
CBNumber:
CB9853793
Molecular Formula:
C3H5NS
Molecular Weight:
87.14
MDL Number:
MFCD00001834
MOL File:
542-90-5.mol
MSDS File:
SDS
Last updated:2023-11-28 16:31:43

Ethylthiocyanate Properties

Melting point -85.5°C
Boiling point 145 °C(lit.)
Density 1.012 g/mL at 25 °C(lit.)
refractive index n20/D 1.462(lit.)
Flash point 109 °F
storage temp. Flammables area
form liquid
color Colorless to Almost colorless
BRN 1737620
Dielectric constant 29.6(20℃)
LogP 1.011 (est)
CAS DataBase Reference 542-90-5(CAS DataBase Reference)
FDA UNII PF9AD5G86Z
NIST Chemistry Reference Thiocyanic acid, ethyl ester(542-90-5)
EPA Substance Registry System Ethyl thiocyanate (542-90-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H226-H302+H312+H332
Precautionary statements  P210-P280-P301+P312+P330-P302+P352+P312-P304+P340+P312
Hazard Codes  Xn
Risk Statements  10-20/21/22-36/37/38
Safety Statements  26-36/37-24/25-16
RIDADR  UN 2929 6.1/PG 2
WGK Germany  3
RTECS  XK9900000
13-19-21
HazardClass  3.2
PackingGroup  III
HS Code  29309070
NFPA 704
2
3 0

Ethylthiocyanate price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 308951 Ethyl thiocyanate 97% 542-90-5 25g $170 2023-06-20 Buy
TCI Chemical T0200 Ethyl Thiocyanate >98.0%(GC) 542-90-5 25mL $253 2024-03-01 Buy
TCI Chemical T0200 Ethyl Thiocyanate >98.0%(GC) 542-90-5 500mL $3693 2024-03-01 Buy
American Custom Chemicals Corporation CHM0079010 ETHYL THIOCYANATE 95.00% 542-90-5 25G $1206.57 2021-12-16 Buy
AHH MT-12779 Ethyl thiocyanate 98% 542-90-5 250ml $298 2021-12-16 Buy
Product number Packaging Price Buy
308951 25g $170 Buy
T0200 25mL $253 Buy
T0200 500mL $3693 Buy
CHM0079010 25G $1206.57 Buy
MT-12779 250ml $298 Buy

Ethylthiocyanate Chemical Properties,Uses,Production

Chemical Properties

Ethyl thiocyanate is a liquid. Onion odor

Chemical Properties

clear colorless liquid

Uses

Ethyl thiocyanate was used in the synthesis of hydrogen cyanide by undergoing in situ reduction with dithiothreitol.

General Description

Liquid. Used as an agricultural insecticide.

Reactivity Profile

Nitric acid violently oxidized a thiocyanate solution [Bretherick, 1979 p. 121]. Caution should be exercised in treating a thiocyanate with an oxidizing agent such as a peroxide or chlorate as such mixtures have been known to explode.

Health Hazard

Ethylthiocyanate is highly toxic if ingested.

Fire Hazard

When heated to decomposition, Ethylthiocyanate emits very toxic fumes of oxides of nitrogen and sulfur.

Safety Profile

Poison by ingestion, subcutaneous, intraperitoneal, and intravenous routes. When heated to decomposition it emits very toxic fumes of NO, and SOx. See also THIOCYANATES.

Potential Exposure

This thiocyanate material is used as an agricultural insecticide

Shipping

UN2929 Toxic liquids, flammable, organic, n.o.s., Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard, 3-Flammable liquid, Technical Name Required

Purification Methods

Fractionally distil the ester at atmospheric pressure. [Beilstein 2 IV 1218.] (CARE LACHRYMATOR.)

Incompatibilities

Incompatible with oxidizers (chlorates, nitrates, peroxides, permanganates, perchlorates, chlorine, bromine, fluorine, etc.); contact may cause fires or explosions. Keep away from alkaline materials, strong bases, strong acids, oxoacids, and epoxides. Esters are generally incompatible with nitrates. Moisture may cause hydrolysis or other forms of decomposition. Caution should be exercised in treating a thiocyanate with an oxidizing agent such as a peroxide or chlorate as such mixtures have been known to explode

Waste Disposal

In accordance with 40CFR 165 recommendations for the disposal of pesticides and pesticide containers. Must be disposed properly by following package label directions or by contacting your local or federal environmental control agency, or by contacting your regional EPA office

540-72-7
121-44-8
542-90-5
Synthesis of Ethylthiocyanate from Sodium thiocyanate and Triethylamine
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View Lastest Price from Ethylthiocyanate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Ethylthiocyanate pictures 2023-06-27 Ethylthiocyanate
542-90-5
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Ethylthiocyanate pictures 2021-08-26 Ethylthiocyanate
542-90-5
US $10.00 / KG 1KG 99% 100 mt Hebei Guanlang Biotechnology Co., Ltd.
Ethylthiocyanate pictures 2020-01-08 Ethylthiocyanate
542-90-5
US $1.00 / KG 1KG 99% 100KG Career Henan Chemical Co
  • Ethylthiocyanate pictures
  • Ethylthiocyanate
    542-90-5
  • US $10.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
Ethane, thiocyanato- Ethylthiokyanat ethylthiokyanat(czech) thiocyanato-ethan Thiocyanato-ethane ethyl rhodonate Ethyl thiocyanate,99% Ethyl thiocyanate,Ethyl rhodanide Ethyl Rhodanide Thiocyanic Acid Ethyl Ester Ethyl thiocyanate 97% THIOCYANIC ACID ETHYL ESTER Ethyl sulfocyanate ETHYL THIOCYANATE ETHYL RHODANATE ETHYL RHODANIDE ethyl sulfocyanide ethyl thiocyanide Aethylrhodanid ai3-18429 Ethyl Thiocyanate > 542-90-5 C2H5SCN CH3CH2SCN Building Blocks Sulfur Compounds Thiocyanates/Isothiocyanates Organic Building Blocks Sulphur Derivatives Pharmaceutical Intermediates