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4-Chloro-2-methylaniline

CAS No.
95-69-2
Chemical Name:
4-Chloro-2-methylaniline
Synonyms
4-CHLORO-O-TOLUIDINE;P-CHLORO-O-TOLUIDINE;FAST RED TR BASE;Ipsilon;fastredtr;devalredk;redbasentr;devalredtr;RED TR BASE;fastredtr11
CBNumber:
CB9854705
Molecular Formula:
C7H8ClN
Molecular Weight:
141.6
MDL Number:
MFCD00007842
MOL File:
95-69-2.mol
Last updated:2024-01-01 23:31:51

4-Chloro-2-methylaniline Properties

Melting point 24-27 °C (lit.)
Boiling point 241 °C (lit.)
Density 1.19 g/mL at 25 °C (lit.)
refractive index n20/D 1.583(lit.)
Flash point 211 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
Water Solubility Practically insoluble in water
solubility Chloroform (Slightly), Methanol (Slightly)
pka pK1:3.385(+1) (25°C)
color White or colorless to Brown
BRN 878505
Stability Air Sensitive
CAS DataBase Reference 95-69-2(CAS DataBase Reference)
EWG's Food Scores 3
FDA UNII 95NB978426
Proposition 65 List p-Chloro-o-toluidine
IARC 2A (Vol. 77, 99) 2010
NIST Chemistry Reference Benzenamine, 4-chloro-2-methyl-(95-69-2)
EPA Substance Registry System 4-Chloro-2-methylaniline (95-69-2)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301+H311+H331-H341-H350-H410
Precautionary statements  P202-P273-P280-P301+P310-P302+P352+P312-P304+P340+P311
Hazard Codes  T,N
Risk Statements  45-23/24/25-50/53-68
Safety Statements  53-45-60-61
RIDADR  UN 2239 6.1/PG 3
WGK Germany  3
RTECS  XU5000000
8-10
HazardClass  6.1(b)
PackingGroup  III
HS Code  29214300
NFPA 704
0
1 0

4-Chloro-2-methylaniline price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 590711 4-Chloro-2-methylaniline 98% 95-69-2 10g $69.2 2024-03-01 Buy
Sigma-Aldrich 46282 4-Chloro-2-methylaniline analytical standard 95-69-2 250mg $53.6 2022-05-15 Buy
TCI Chemical A0704 4-Chloro-2-methylaniline >98.0%(GC)(T) 95-69-2 25g $28 2024-03-01 Buy
TCI Chemical A0704 4-Chloro-2-methylaniline >98.0%(GC)(T) 95-69-2 100g $63 2024-03-01 Buy
TCI Chemical A0704 4-Chloro-2-methylaniline >98.0%(GC)(T) 95-69-2 500g $186 2024-03-01 Buy
Product number Packaging Price Buy
590711 10g $69.2 Buy
46282 250mg $53.6 Buy
A0704 25g $28 Buy
A0704 100g $63 Buy
A0704 500g $186 Buy

4-Chloro-2-methylaniline Chemical Properties,Uses,Production

Chemical Properties

The chloromethylanilines are colorless or white crystalline solids or liquids, some have a mild fishy odor.

Chemical Properties

clear brown liquid

Uses

Intermediate.

Uses

4-Chloro-2-methylaniline may be used in the synthesis of the following:

  • 2,8-dichloro-4,10-dimethyl-6H,12H-5,11-methanodibenzo[b,f]-diazocine via reaction with paraformaldehyde in toluene
  • N-allylated derivative via palladium-catalyzed selective monoallylation with allyl alcohol
  • N-(4-chloro-2-methylphenyl)benzamide via reaction with benzoyl chloride

Definition

ChEBI: 4-Chloro-ortho-toluidine is a member of monochlorobenzenes.

General Description

Gray to white solid with a weak fishy odor. Sinks in water. Freezing point is 77°F.

Air & Water Reactions

May be sensitive to prolonged exposure to air and light. Insoluble in water.

Reactivity Profile

4-Chloro-2-methylaniline is incompatible with acids, acid chlorides, acid anhydrides, chloroformates and strong oxidizing agents. . A halogenated amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides.

Hazard

Toxic by ingestion and inhalation. Probable carcinogen.

Health Hazard

Inhalation, ingestion, or skin contact causes bluish tint in fingernails, lips, and ears. Headache, drowsiness, and nausea also occur. Contact with eyes causes irritation.

Fire Hazard

Special Hazards of Combustion Products: Toxic oxides of nitrogen and hydrochloric acid fumes may form.

Safety Profile

Confirmed carcinogen. Poison by ingestion and subcutaneous routes. Human mutation data reported. In the presence of copperpI) chloride catalyst decomposition occurs above 239'C. When heated to decomposition it emits toxic fumes of Cland NOx. See also other chloro toluidme entries.

Potential Exposure

Most of the isomers are used in dyestuff manufacture. The 3-chloro-para isomer is used to kill birds. It is marketed as pelleted bait for control of bird populations.

Carcinogenicity

p-Chloro-o-toluidine and its hydrochloride salt are reasonably anticipated to be human carcinogens based on limited evidence of carcinogenicity from studies in humans and evidence of carcinogenicity from studies in experimental animals.

Shipping

UN2239 Chlorotoluidines, solid, Hazard Class: 6.1; Labels: 6.1-Poisonous materials. UN3429 Chlorotoluidines, liquid, Hazard Class: 6.1; Labels: 6.1- Poisonous materials

Incompatibilities

Incompatible with oxidizers, strong acids; chloroformates, and acid anhydrides, isocyanates, aldehydes forming fire and explosive hazards.

95-53-4
95-69-2
Synthesis of 4-Chloro-2-methylaniline from o-Toluidine
Global( 303)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Fengda Chemical Co., Ltd
+8613613820652 info@fdachem.com China 5085 58
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Shanghai Worldyang Chemical Co.,Ltd.
,+86-21-56795779; +8613651600618 sales@worldyachem.com China 879 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Richest Group Ltd
18017061086 oled@richest-group.com CHINA 5601 58

View Lastest Price from 4-Chloro-2-methylaniline manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Chloro-2-Methylaniline pictures 2024-01-02 4-Chloro-2-Methylaniline
95-69-2
US $200.00-1.00 / KG 1KG 99%, 99.5% Sublimated g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
4-Chloro-2-methylaniline pictures 2023-04-20 4-Chloro-2-methylaniline
95-69-2
US $30.00-10.00 / kg 10kg 99% 100000kg Hebei Guanlang Biotechnology Co,.LTD
4-Chloro-2-methylaniline pictures 2022-02-19 4-Chloro-2-methylaniline
95-69-2
US $0.00 / KG 1KG 97.6% 100 tons Honest Joy Holdings Limited
fastredtrobase Ipsilon Kako Red TR Base kakoredtrbase Kambamine Red TR kambamineredtr Mitsui Red TR Base mitsuiredtrbase o-Toluidine, 4-chloro- para-chloro-ortho-toluidine Red Base Ciba IX Red Base Irga IX Red Base NTR redbasecibaix redbaseirgaix 3-Chloro-6-aminotoluene 2-Methyl-4-chloro aniline 4-chloro-2-Methylaniline 4-Chloro-2-Met 4-Chloro-2-methylaniline Solution, 100ppm 4-chloro-2-methyl-benzenamin 4-Chloro-2-methylbenzeneamine 4-Chloro-6-methylanilinen 4-chloro-o-toluidin 4-CHLORO-2-METHYLANILINE, STANDARD FOR GC 4-CHLORO-2-METHYLANILINE OEKANAL, 250 AZOIC DIAZO COMPONENT 11 99%- CARC. 2-amino-5-chlortoluol Amarthol Fast Red TR Base amartholfastredtrbase amino-2chloro-5toluene asymmetricmeta-chloro-ortho-toluidine Benzenamine,4-chloro-2-methyl- redbasentr Sanyo Fast Red TR Base sanyofastredtrbase Tulabase Fast Red TR tulabasefastredtr RED TR BASE 4-CHLORO-ORTHO-TOLUIDINE BENZENEAMINE,4-CHLORO-2-METHYL- PARA-CHLORO-ORTHO-TOLUDINE ORTHO-TOLUIDINE,4-CHLORO- 4-Chloro-o-toluidine (NH2=1) 3-CHLORO-6-METHYLANILINE 97% 4-CHLORO-2-METHYLANILINE 98% O-CHLOROTOLUIDINE 4-Chloro-2-methylaniline,98% 4-Chloro-2-methylaniline 1g [95-69-2] 4-Chloro-2-methylani 4-Chloro-2-Methylaniline, 98% 5GR 2-Amino-5-chlorotoluene 4-Chloro-o-toluidine Fast Red TR Base Fast Red Tr11 Fast Red TRO Base Fast Red TR-T Base fastred5ctbase fastredbasetr fastredtr fastredtr11