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N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-)

N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-) 化学構造式
2503-13-1
CAS番号.
2503-13-1
化学名:
N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-)
别名:
エンニアチンA;N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-)
英語名:
enniatin A
英語别名:
enniatin A;Lateritin I;N-Methylcyclo(L-Ile-D-Hmb-N-methyl-L-Ile-D-Hmb-N-methyl-L-Ile-D-Hmb-);(3S,6R,9S,12R,15S,18R)-3,9,15-tris[(2S)-butan-2-yl]-4,10,16-trimethyl-6,12,18-tri(propan-2-yl)-1,7,13-trioxa-4,10,16-triazacyclooctadecane-2,5,8,11,14,17-hexone;Cyclo[(2R)- 2-hydroxy-3-methylbutanoyl-N-methyl-L-isoleucyl-(2R)-2-hydroxy-3-methylbutanoyl-N-methyl-L-isoleucyl-(2R)-2-hydroxy-3-methylbutanoyl- N-methyl-L- isoleucyl]
CBNumber:
CB02079105
化学式:
C36H63N3O9
分子量:
681.906
MOL File:
2503-13-1.mol

N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-) 物理性質

融点 :
122-124 °C
沸点 :
847.4±65.0 °C(Predicted)
比重(密度) :
1.022±0.06 g/cm3(Predicted)
貯蔵温度 :
-20°C
溶解性:
DMSO：可溶10mg/mL
外見 :
白色からオフホワイトの結晶性固体。
酸解離定数(Pka):
-0.96±0.70(Predicted)

安全性情報

主な危険性  T
Rフレーズ  23/24/25
Sフレーズ  45
RIDADR  2811
WGK Germany  3
国連危険物分類  6.1(a)
容器等級  I
HSコード  2934999090

N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-) 価格 もっと(1)

メーカー 製品番号 製品説明 CAS番号 包装 価格 更新時間 購入
Sigma-Aldrich Japan E9661 from Gnomonia errabunda, ≥95% (HPLC)
Enniatin A from Gnomonia errabunda, ≥95% (HPLC)		 2503-13-1 1mg ￥42200 2024-03-01 購入

N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-) 化学特性,用途語,生産方法

説明

Enniatins are cyclohexadepsipeptides commonly isolated from fungi that are known to have antibiotic properties and to induce apoptosis in several cancer lines. Many function as ionophores, forming pores in cellular membranes to allow selective ion transport. Enniatin A is one of four major analogs in the enniatin complex . It has been shown to moderately inhibit acyl-CoA:cholesterol acyltranferase activity in rat liver microsomes with an IC50 value of 22 μM. Enniatin A also demonstrates anthelmintic properties against N. brasiliensis, T. spiralis, and H. spumosa.

使用

Enniatins are a family of depsipeptide ionophores, produced by several Fusarium species. More recently, the effects of the enniatins on acyl-CoA cholesterol transferase, transporters and the selectivity of their antitumour action have received more focus. Enniatin A is one of four major analogues of the enniatin complex and has not previously been available for investigation.

定義

ChEBI: An enniatin obtained from formal cyclocondensation of three N-[(2R)-2-hydroxy-3-methylbutanoyl]-N-methyl-L-isoleucine units.

N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-) 上流と下流の製品情報

原材料

準備製品

N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-) 生産企業

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2503-13-1(N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-))キーワード:

グラミシジン A N-メチルシクロ(L-Phe-D-Hmb-N-メチル-L-Phe-D-Hmb-N-メチル-L-Phe-D-Hmb-) (3S,6R,9S,12R,15S,18R)-3,6,9,12,15,18-ヘキサイソプロピル-4,10,16-トリメチル-1,7,13-トリオキサ-4,10,16-トリアザシクロオクタデカン-2,5,8,11,14,17-ヘキサオン エンニアチンB1
  • 2503-13-1
  • enniatin A
  • N-Methylcyclo(L-Ile-D-Hmb-N-methyl-L-Ile-D-Hmb-N-methyl-L-Ile-D-Hmb-)
  • Lateritin I
  • Cyclo[(2R)- 2-hydroxy-3-methylbutanoyl-N-methyl-L-isoleucyl-(2R)-2-hydroxy-3-methylbutanoyl-N-methyl-L-isoleucyl-(2R)-2-hydroxy-3-methylbutanoyl- N-methyl-L- isoleucyl]
  • (3S,6R,9S,12R,15S,18R)-3,9,15-tris[(2S)-butan-2-yl]-4,10,16-trimethyl-6,12,18-tri(propan-2-yl)-1,7,13-trioxa-4,10,16-triazacyclooctadecane-2,5,8,11,14,17-hexone
  • エンニアチンA
  • N-メチルシクロ(L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-N-メチル-L-Ile-D-Hmb-)
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