1,1-ジメチルヒドラジン 化学特性,用途語,生産方法
外観
無色～ほとんど無色, 澄明の液体
溶解性
水に易溶, エタノール, エーテルに混和。水及びエタノールに極めて溶けやすい。
解説
化学式 CH3NHNHCH3 。ジメチルヒドラジン, ジメチルアミンからつくられる可燃性液体。沸点 64℃。アンモニア臭をもつ吸湿性の液体。水と混合し塩基性を示す。エチルアルコール，エーテルに易溶。硝酸を酸化剤としてロケット燃料に用いられる。ブリタニカ国際大百科事典 小項目事典 ブリタニカ
用途
主たる用途: ロケット燃料組成物(MERCK(14TH,2006))
使用上の注意
不活性ガス封入
化学的特性
1,1-Dimethylhydrazine is a colorless, flammable, hygroscopic liquid that gradually turns
yellow on contact with air and is miscible with water. 1,1-Dimethylhydrazine is primar-
ily used as a high-energy fuel in military applications, as a rocket propellant and fuel for
thrusters, and small electrical power-generating units. 1,1-Dimethylhydrazine is also used
in the manufacture of a plant growth regulator, in chemical synthesis, in photographic
chemicals, as a stabilizer for fuel additives, and as an absorbent for acid gases. Exposure
to 1,1-dimethylhydrazine usually occurs at the workplace during use and handling of the
chemical substance.
No information is available on the carcinogenic effects of 1,1-dimethylhydrazine in humans.
Carcinogenic effects were observed in mice and rats exposed to 1,1-dimethylhydrazine
by inhalation, but the carcinogenicity could not be defi nitively attributed to
1,1-dimethylhydrazine because of the presence of contaminants in the study. The US EPA
has not classifi ed 1,1-dimethylhydrazine for potential carcinogenicity, while the IARC has
classifi ed 1,1-dimethylhydrazine as Group 2B, meaning a possible human carcinogen.
物理的性質
Clear, colorless fuming liquid with an amine-like odor. Turns yellow on exposure to air. Odor
detection threshold concentrations ranged from 6.1 to 14 ppm
v (Jacobson et al., 1955).
使用
1,1-Dimethylhydrazine is used in rocket fuel.
定義
ChEBI: A member of the class of hydrazines that is hydrazine substituted by two methyl groups at position 1.
一般的な説明
A clear colorless liquid with an ammonia-like odor. Flash point 0°F. Corrosive to the skin. Less dense than water and soluble in water. Vapors are heavier than air and very toxic by inhalation, attacking the eyes and respiratory system. Prolonged exposure of containers to heat may result in their violent rupturing and rocketing due to decomposition. Generates toxic oxides of nitrogen when burned. Vapors may travel to a source of ignition and a flame can flashback to the source of vapors. Used as a rocket propellant and to make other chemicals.
空気と水の反応
Highly flammable over a wide range of vapor concentrations. May ignite spontaneously when spread on a large surface exposed to the air. [Def. Res. and Eng., pp 299-300(1963)]. Dissolves and slowly decomposes in water.
反応プロフィール
1,1-Dimethylhydrazine is a powerful reducing agent. Ignition can occur on contact with oxidizing agents such hydrogen peroxide and fuming nitric acid, [Haz. Chem. Data(1966)]. Also reacts as a base to neutralize acids in exothermic reactions.
健康ハザード
1,1-Dimethylhydrazine exhibits high acute toxicity as a result of exposure by all routes. Death or permanent injury may result after very short exposure to small quantities. Chronic exposure may cause pneumonia, liver damage, and kidney damage.
火災危険
Vapor may explode if ignited in an enclosed area. Vapors may travel to a source of ignition and flashback. Runoff to sewer may create fire or explosion hazard. When 1,1-Dimethylhydrazine decomposes, 1,1-Dimethylhydrazine gives off toxic nitrogen compound fumes. Dissolves, swells, and disintegrates many plastics. Dangerous when exposed to heat, flame, or oxidizers. Hazardous polymerization may not occur.
安全性プロファイル
Confirmed carcinogen
with experimental carcinogenic,
tumorigenic, and teratogenic data. Other
experimental reproductive effects. Poison byingestion, intraperitoneal, intravenous, and
intracerebral routes. Moderately toxic by
inhalation and skin contact. Human
mutation data reported. A plant growth
control agent. Corrosive. A powerful
reducing agent. A dangerous fire hazard. It
is hypergolic with many oxidants (e.g.,
dinitrogen tetroxide, hydrogen peroxide, and
nitric acid). Dangerous when exposed to
heat, flame, or oxidizers; can react
vigorously with oxidning materials such as
air, fuming HNO3, (HNO3 + N2O4), NO. A
high-energy propellant for liquid-fueled
rockets. To fight fire, use alcohol foam,
CO2, dry chemical. When heated to
decomposition it emits highly toxic fumes of
NOx. See also HYDRAZINE.
発がん性
1,1-Dimethylhydrazine is reasonably anticipated to be a human carcinogen based on sufficient evidence of carcinogenicity from studies in experimental animals.
環境運命予測
Chemical/Physical. Releases toxic nitrogen oxides when heated to decomposition (Sax and
Lewis, 1987). Ignites spontaneously in air or in contact with hydrogen peroxide, nitric acid, or
other oxidizers (Patnaik, 1992).
N-Nitrosodimethylamine was the major product of ozonation of 1,1-dimethylhydrazine in the
dark. Hydrogen peroxide, methyl hydroperoxide, and methyl diazene were also identified (HSDB,
1989).
純化方法
Fractionally distil the hydrazine through a 4-ft column packed with glass helices. Precipitate it as its oxalate from diethyl ether solution. After crystallising from 95% EtOH, the salt is decomposed with aqueous saturated NaOH, and the free base is distilled, dried over BaO and redistilled [McBride & Kruse J Am Chem Soc 79 572 1957]. Distillation and storage should be under nitrogen. [Beilstein 4 IV 3322.]
1,1-ジメチルヒドラジン 上流と下流の製品情報
原材料
準備製品