トリフルオロ酢酸銀(I)
安全性情報
- リスクと安全性に関する声明
- 危険有害性情報のコード(GHS)
| 主な危険性 |
Xi,T,N |
|
|
| Rフレーズ |
36/38-50-36/37/38 |
|
|
| Sフレーズ |
26-61-36/39 |
|
|
| WGK Germany |
3 |
|
|
| F |
3-8 |
|
|
| Hazard Note |
Toxic/Hygroscopic |
|
|
| TSCA |
T |
|
|
| 国連危険物分類 |
HYGROSCOPIC, TOXIC |
|
|
| 国連危険物分類 |
9 |
|
|
| HSコード |
28432900 |
|
|
| 安衛法 |
57,57-2 |
|
|
| PRTR法 |
1-82 |
|
|
| 絵表示（GHS） |
 
|
| 注意喚起語 |
危険 |
| 危険有害性情報 |
| コード |
危険有害性情報 |
危険有害性クラス |
区分 |
注意喚起語 |
シンボル |
P コード |
| H300 |
飲み込むと生命に危険 |
急性毒性、経口 |
1, 2 |
危険 |
|
P264, P270, P301+P310, P321, P330,P405, P501 |
| H400 |
水生生物に強い毒性 |
水生環境有害性、急性毒性 |
1 |
警告 |
|
P273, P391, P501 |
|
| 注意書き |
|
トリフルオロ酢酸銀(I) 価格
もっと(11)
| メーカー |
製品番号 |
製品説明 |
CAS番号 |
包装 |
価格 |
更新時間 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01SRM93-4736 |
トリフルオロ酢酸銀, min. 98%
Silver trifluoroacetate, min. 98% |
2966-50-9 |
5g |
￥21500 |
2024-03-01 |
購入 |
|
富士フイルム和光純薬株式会社(wako)
|
W01SRM93-4736 |
トリフルオロ酢酸銀, min. 98%
Silver trifluoroacetate, min. 98% |
2966-50-9 |
25g |
￥74800 |
2024-03-01 |
購入 |
|
関東化学株式会社(KANTO)
|
13973-2A |
トリフルオロ酢酸銀 98%
Trifluoroacetic acid silver salt 98% |
2966-50-9 |
5g |
￥17800 |
2024-03-01 |
購入 |
|
関東化学株式会社(KANTO)
|
13973-1A |
トリフルオロ酢酸銀 98%
Trifluoroacetic acid silver salt 98% |
2966-50-9 |
25g |
￥41100 |
2024-03-01 |
購入 |
|
Sigma-Aldrich Japan
|
482307 |
トリフルオロ酢酸銀 ≥99.99% trace metals basis
Silver trifluoroacetate ≥99.99% trace metals basis |
2966-50-9 |
1g |
￥14600 |
2024-03-01 |
購入 |
トリフルオロ酢酸銀(I) 化学特性,用途語,生産方法
溶解性
水、エタノール及びアセトンに溶ける。
用途
有機合成用試薬。
化学的特性
light beige to grey crystalline powder
使用
Silver Trifluoroacetate functions as a catalyst in the synthesis of cyclobutene-fused azepines/dihydropyridines.
主な応用
Silver trifluoroacetate is the silver salt of trifluoroacetic acid and is used as a Lewis acid catalyst. It is used as an important raw material for the preparation of triethylsilyl trifloroacetate and triphenylmethyl trifluoroacetate. Further, it is used as a catalyst in the preparation of 4-iodoveratrole from veratrole by reacting with iodine.
合成
Silver trifluoroacetate is prepared by the reaction of silver oxide and trifluoroacetic acid.
Reaction equation: Ag2O+2CF3COOH→2CF3COOAg+H2O
Reaction: 187g (0.81mol) of silver oxide was weighed and suspended in 200mL of water, and 177g (1.55mol) of trifluoroacetic acid was added. After filtration, the filtrate was evaporated to dryness under reduced pressure. The residue was extracted with ether in a Soxhlet extractor. Alternatively, dissolve the residue in 1.2L of ether and filter through a thin layer of activated carbon. After distilling off the ether, 300g of the product was obtained with a yield of 83%.
純化方法
The extract is filtered and evaporated to dryness, then the powdered residue is completely dried in a vacuum desiccator over silica gel. Its solubility in Et2O is 33.5g in 750mL. It can be recrystallised from *C6H6 (solubility is: 1.9g in 30mL of *C6H6, and 33.5g will dissolve in 750mL of anhydrous Et2O). [Traynham & Dehn J Org Chem 23 1545 1958, Haszeldine J Chem Soc 584 1951.] Store it in the dark. It is also soluble in trifluoroacetic acid (15.2% at 30o), toluene, o-xylene and dioxane [Hara & Cady J Am Chem Soc 76 4285 1954]. [Beilstein 2 IV 461.]
トリフルオロ酢酸銀(I) 上流と下流の製品情報
原材料
準備製品
トリフルオロ酢酸銀(I) 生産企業
Global( 239)Suppliers
トリフルオロ酢酸銀(I) スペクトルデータ(13CNMR、IR1、IR2、Raman)
2966-50-9(トリフルオロ酢酸銀(I))キーワード:
- 2966-50-9
- trifluoro-aceticacisilver(1++)salt
- SILVER TRIFLUOROACETATE
- SILVER(I) TRIFLUOROACETATE
- SILVER TRIFLUOROACETATE, 99.99+%
- Silvertrifluoroacetate,min.98%
- Trifluoroacetic acid silver(I) salt
- Acetic acid, trifluoro-, silver(1+) salt
- Silver trifluoroacetate 98%
- Silvertrifluoroacetate98%
- Silver trifluoroacetate, min. 98%
- Trifluoroacetoxysilver(I)
- Trifluoroacetic acid, silver salt,98%
- Trifluoroacetic acid, silver saltSilver trifluoroacetate
- Trifluoroacetic acid, silver salt, 98% 25GR
- Silver trifluoroacetate,98% AgOOCCF3
- 5,6-DIHYDRO-2-ISOPROPENYL-4,4,6-TRIMETHY
- SILVER TRIFLUOROACETATE FOR SYNTHESIS
- Silver trifluoroacetate ,97.5%
- Silver(I) 2,2,2-trifluoroethanoate, 2,2,2-Trifluoroethanoic acid, silver(I) salt
- Silver(I) trifluoroacetate 98%
- Silver(I) 2,2,2-trifluoroacetate
- (2,2,2-trifluoroacetoxy)silver
- Silver trifluoroacetate >=99.99% trace Metals basis
- SILVER TRIFLUOROACETATE, 98%SILVER TRIFLUOROACETATE, 98%SILVER TRIFLUOROACETATE, 98%SILVER TRIFLUOROACETATE, 98%
- Acetic acid, 2,2,2-trifluoro-, silver(1+) salt (1:1)
- Silver trifluoroacetate ISO 9001：2015 REACH
- 2966-50-9 Silver trifluoroacetate
- TRIFLUOROACETIC ACID SILVER SALT
- Silver 2,2,2-trifluoroacetate
- SILVER TRIFLUOROACETIC ACID
- トリフルオロアセトキシ銀(I)
- トリフルオロ酢酸銀(I)
- トリフルオロ酢酸銀
- トリフルオロ酢酸銀, min. 98%